ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ
5. əɜɨɪɨɜɫɶɤɢɣ Ɉ.ɉ. ɏɚɪɚɤɬɟɪɢɫɬɢɤɚ ɜɚɠɤɨɫɬɿ ɿ ɧɚɩɪɭɠɟɧɧɨɫɬɿ ɩɪɚɰɿ ɩɪɢ ɜɤɨɧɚɧɧɿ ɫɤɥɚɞɚɥɶɧɨ -ɤɥɟɩɚɥɶɧɢɯ ɪɨɛɿɬ ɧɚ ɚɜɿɚɰɿɣɧɢɯ ɩɿɞɩɪɢɽɦɫɬɜɚɯ / Ɉ.ɉ. əɜɨɪɨɜɫɶɤɢɣ,ȼ.Ɇ.ɒɟɜɰɨɜɚ,ɋ.Ƚ.ɋɨɜɚ // ɍɤɪ.ɠɭɪɧɚɥ ɡ ɩɪɨɛɥɟɦ ɦɟɞɢɰɢɧɢ ɩɪɚɰɿ. – 2013. – ʋ 3. – ɋ. 25-33.
6. Health and Safety Executive. [ɗɥɟɤɬɪɨɧɧɵɣ ɪɟɫɭɪɫ]. Ɋɟɠɢɦ ɞɨɫɬɭɩɭ: http://www.hse.gov.uk/vib-ration/hav/readyreckoner.htm
7. Giersiepen K. Carpal tunnel syndrome as an occupational disease / K. Giersiepen, M. Spallek // Dtsch. Arztebl. Int. – 2011. – Vol. 108, N 14. – P. 238-242.
8. Teollisuuden kunnossapitohenkilöstön riskipro-fiili (Risk profile of industrial maintenance staff) / P.I. Korhonen, A. Saalo, T/ Pensola, E. Priha // Helsinki: Ɍhe Finnish Institute of Occupational Health. – 2011. – 234 ɪ.
9. Tim South. Managing Noise and Vibration at Work. A practical guide to assessment, measurement and control (1st ed.). – Routledge: Elsevier Butterworth-Hei-nemann Linacre House, 2004. – 288 p.
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1. DSN 3.3.6.039-99. [State Sanitary norms of general and local vibration]. Ʉ.:ɆɈZ Ukrainy, 1999;45. Ukranian.
2. Kononova ȱG. [Modern problems of sanitary and hygienic supervision in machine industry enterprises]. Ukrainsky journal z problem mediciny praci. 2009;4:32-37. Ukranian.
3. Kundiev UI. [Occupational health in Ukraine. Epidemiological analysis]. Kiev. Avicena. Ukraine, 2007;396. Russian.
4. Kundiev UI, Nagornaya ȺM, Chernuk VI. [Ten-sion of labour as factor of profes[Ten-sional stress and risk to the health]. Ukrainsky journal z problem mediciny praci. 2007;4(12):10-17. Ukranian.
5. Yavorovsky OP, Shevtsova VM, Sova SG. [The characteristics of severity and intentensity of work when
performing assembly and riveting works in the air enterprises]. Ukrainsky journal z problem mediciny praci. 2013;3:25-33. Ukranian.
6. Health and Safety Executive. [Internet]. Available from: http://www.hse.gov.uk/vibration/hav/readyreckoner.htm
7. Giersiepen K, Spallek M. Carpal tunnel syndrome as an occupational disease. Dtsch Arztebl Int. 2011;108(14):238-42.
8. Korhonen PI, Saalo A, Pensola T, Priha E. [Risk profile of industrial maintenance staff]. Helsinki: Ɍhe Finnish Institute of Occupational Health; 2011;234. Finnish.
9. Tim South. Managing Noise and Vibration at Work. A practical guide to assessment, measurement and control (1st ed.). Routledge: Elsevier Butterworth-Heinemann Linacre House, 2004;288.
ɋɬɚɬɬɹ ɧɚɞɿɣɲɥɚ ɞɨ ɪɟɞɚɤɰɿʀ 29.08.2014
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Ʌɶɜɿɜɫɶɤɢɣ ɧɚɰɿɨɧɚɥɶɧɢɣ ɦɟɞɢɱɧɢɣ ɭɧɿɜɟɪɫɢɬɟɬ ɿɦ.Ⱦɚɧɢɥɚ Ƚɚɥɢɰɶɤɨɝɨ
ɜɭɥ.ɉɟɤɚɪɫɶɤɚ, 69, Ʌɶɜɿɜ, 79010, ɍɤɪɚʀɧɚ
Lviv National Medical University name of Danylo Galicky Pekarska str., 69, Lviv, 79010, Ukraine
e-mail: sknm@i.ua
Ʉɥɸɱɨɜɿ ɫɥɨɜɚ:ɞɿɬɢ,ɦɿɤɪɨɟɥɟɦɟɧɬɢ,ɝɟɨɯɿɦɿɱɧɿ ɩɪɨɜɿɧɰɿʀ,ɬɟɯɧɨɝɟɧɧɿ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɢ
Key words: children, microelements, geochemical territory, technogenic microelementosis
ɷɥɟɦɟɧɬɧɨɦɭ ɫɨɫɬɚɜɭ ɜɨɥɨɫ ɢ ɤɪɨɜɢ ɞɟɬɟɣ, ɢɧɬɟɧɫɢɜɧɨɫɬɢ ɩɪɨɰɟɫɫɨɜ ɩɟɪɟɤɢɫɧɨɝɨ ɨɤɢɫɥɟɧɢɹ ɥɢɩɢɞɨɜ ɢ
ɚɤɬɢɜɧɨɫɬɢ ɮɟɪɦɟɧɬɨɜ ɚɧɬɢɨɤɫɢɞɚɧɬɧɨɣ ɡɚɳɢɬɵ, ɩɨɤɚɡɚɬɟɥɹɦ ɮɢɡɢɱɟɫɤɨɝɨ ɪɚɡɜɢɬɢɹ ɢ ɫɨɫɬɨɹɧɢɹ ɢɯ
ɮɚɤɬɢɱɟɫɤɨɝɨ ɩɢɬɚɧɢɹ. ȼɵɹɜɥɟɧɧɚ ɤɨɪɪɟɥɹɰɢɨɧɧɚɹ ɡɚɜɢɫɢɦɨɫɬɶ ɦɟɠɞɭ ɜɥɢɹɧɢɟɦ ɬɨɤɫɢɤɚɧɬɨɜ ɫɪɟɞɵ ɢ
ɧɚɪɭɲɟɧɢɹɦɢ ɜ ɫɨɫɬɨɹɧɢɢ ɡɞɨɪɨɜɶɹ ɞɟɬɟɣ. Ɋɚɡɪɚɛɨɬɚɧɚ ɤɨɦɩɥɟɤɫɧɚɹ ɫɯɟɦɚ ɦɟɪɨɩɪɢɹɬɢɣ ɩɨ ɩɪɨɮɢɥɚɤɬɢɤɟ
ɪɚɡɜɢɬɢɹ ɬɟɯɧɨɝɟɧɧɵɯ ɦɢɤɪɨɷɥɟɦɟɧɬɨɡɨɜ ɭ ɞɟɬɟɣ.
Abstract. Hygienic assessment of microelementosis in primary school children living on geochemical territory. Kuzminov B.P., Skaletska N.M. In this work we consider methods of solving urgent issues of prevention of violations of children’s health those who live in technologically contaminated areas. Content of pollutants in environmental objects of Sosnivka town as geochemical province was conducted. We made a comparative analysis of pre-pathological health indicators of children living on this territory, as well as "conditionally clean territory" by the elemental composition of children’s hair and blood content, intensity of lipid peroxidation and activity of antioxidant enzymes, parameters of physical development and condition of their actual nutrition. Correlations between exposure to toxicants of the environment and changes in the health of children was revealed. There was developed integrated scheme of measures for the prevention of technogenic microelementosis among children.
ɇɚɜɚɧɬɚɠɟɧɧɹ ɬɟɯɧɨɝɟɧɧɨɝɨ ɜɩɥɢɜɭ ɧɚ ɨɪɝɚ
-ɧɿɡɦ ɥɸɞɢɧɢ ɫɬɚɽ ɧɟɜɿɞ’ɽɦɧɨɸ ɫɤɥɚɞɨɜɨɸ ɩɪɨ
-ɦɢɫɥɨɜɨ ɪɨɡɜɢɧɟɧɢɯ ɬɟɪɢɬɨɪɿɣ.Ɂɚɛɪɭɞɧɟɧɧɹ ɭɫɿɯ
ɫɮɟɪ ɞɨɜɤɿɥɥɹ ɩɪɢɡɜɨɞɢɬɶ ɞɨ ɡɚɤɨɧɨɦɿɪɧɨɝɨ ɡɛɿɥɶɲɟɧɧɹ ɧɚɞɯɨɞɠɟɧɧɹ ɜ ɨɪɝɚɧɿɡɦ ɞɿɬɟɣ ɬɨɤ
-ɫɢɱɧɢɯ ɟɥɟɦɟɧɬɿɜ ɬɚ ɪɨɡɜɢɬɤɭ ɭ ɧɢɯ ɬɟɯɧɨɝɟɧɧɢɯ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɿɜ, ɹɤɿ ɡɭɦɨɜɥɸɸɬɶ ɜɢɧɢɤɧɟɧɧɹ
ɡɧɚɱɧɢɯ ɡɦɿɧ ɜ ɨɪɝɚɧɚɯ ɬɚ ɫɢɫɬɟɦɚɯ ɨɪɝɚɧɿɡɦɭ
[17, 19]. Ɍɨɦɭ ɧɚ ɫɶɨɝɨɞɧɿ ɚɤɬɭɚɥɶɧɢɦ ɽ ɜɢɜɱɟɧɧɹ
ɮɚɤɬɨɪɿɜ ɪɢɡɢɤɭ ɜɢɧɢɤɧɟɧɧɹ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɿɜ ɭ ɞɿɬɟɣ, ɹɤɿ ɩɪɨɠɢɜɚɸɬɶ ɧɚ ɬɟɯɧɨɝɟɧɧɨ ɡɚɛɪɭɞ
-ɧɟɧɢɯ ɬɟɪɢɬɨɪɿɹɯ.
Ɇɟɬɨɸ ɧɚɲɨɝɨ ɞɨɫɥɿɞɠɟɧɧɹ ɛɭɥɚ ɩɨɪɿɜɧɹɥɶɧɚ ɝɿɝɿɽɧɿɱɧɚ ɨɰɿɧɤɚ ɫɬɚɧɭ ɡɞɨɪɨɜ’ɹ ɞɿɬɟɣ, ɳɨ
ɩɪɨɠɢɜɚɸɬɶ ɧɚ ɬɟɪɢɬɨɪɿʀ ɝɟɨɯɿɦɿɱɧɨʀ ɩɪɨɜɿɧɰɿʀ ɦ.ɋɨɫɧɿɜɤɚ ɬɚ ɧɚ ɭɦɨɜɧɨ «ɱɢɫɬɿɣ» ɬɟɪɢɬɨɪɿʀ ɞɥɹ
ɨɛʉɪɭɧɬɭɜɚɧɧɹ ɩɪɨɮɿɥɚɤɬɢɤɢ ɪɨɡɜɢɬɤɭ ɭ ɧɢɯ ɬɟɯɧɨɝɟɧɧɢɯ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɿɜ.
ɆȺɌȿɊȱȺɅɂ ɌȺ ɆȿɌɈȾɂ ȾɈɋɅȱȾɀȿɇɖ
Ⱦɨɫɥɿɞɠɟɧɧɹ ɫɬɚɧɭ ʉɪɭɧɬɭ ɩɪɨɜɨɞɢɥɢ ɡɚ ɡɚ
-ɝɚɥɶɧɨɩɪɢɣɧɹɬɨɸ ɦɟɬɨɞɢɤɨɸ ɬɚ ɚɧɚɥɿɡɨɦ ɜɿɞɩɨ
-ɜɿɞɧɨ ɞɨ [9]. Ƚɿɝɿɽɧɿɱɧɭ ɨɰɿɧɤɭ ɹɤɨɫɬɿ ɩɢɬɧɨʀ ɜɨɞɢ
ɡɞɿɣɫɧɸɜɚɥɢ ɡɝɿɞɧɨ ɡ [3]. Ⱦɥɹ ɨɰɿɧɤɢ ɜɦɿɫɬɭ ɭ
ɩɢɬɧɿɣ ɜɨɞɿ ɪɟɱɨɜɢɧ, ɧɟ ɡɚɡɧɚɱɟɧɢɯ ɭ [3], ɜɢɤɨ
-ɪɢɫɬɨɜɭɜɚɥɢ ʀɯ ȽȾɄ ɞɥɹ ɩɨɜɟɪɯɧɟɜɢɯ ɜɨɞɨɣɦ
[13] ɡɝɿɞɧɨ ɡ ɩ. 3.6 [3]. ȼɢɡɧɚɱɟɧɧɹ ɟɥɟɦɟɧɬɧɨɝɨ
ɫɤɥɚɞɭ ɜɨɞɢ ɩɪɨɜɨɞɢɥɢ ɧɚ ɛɚɡɿ ɇɌɐ «ȼȱɊȱȺ» (ɦ.Ʉɢʀɜ) ɡ ɜɢɤɨɪɢɫɬɚɧɧɹɦ ɦɟɬɨɞɭ ɪɟɧɬɝɟɧ-ɮɥɸ
-ɨɪɟɫɰɟɧɬɧɨɝɨ ɚɧɚɥɿɡɭ (ɊɎȺ) [7]. Ⱦɚɧɿ ɩɪɨ ɜɦɿɫɬ
ɮɬɨɪɭ ɭ ɜɨɞɿ ɜɨɞɨɡɚɛɨɪɿɜ ɬɚ ɜ ɪɨɡɜɿɞɧɿɣ ɦɟɪɟɠɿ ɦ.ɋɨɫɧɿɜɤɚ ɡɚ ɩɟɪɿɨɞ 1994-2012 ɪɪ. ɨɬɪɢɦɚɧɨ
ɲɥɹɯɨɦ ɤɨɩɿɸɜɚɧɧɹ ɡ ɠɭɪɧɚɥɭ ɨɛɥɿɤɭ ɪɟɡɭɥɶ
-ɬɚɬɿɜ ɞɨɫɥɿɞɠɟɧɶ ɩɢɬɧɨʀ ɜɨɞɢ ɰɟɧɬɪɚɥɿɡɨɜɚɧɨɝɨ ɬɚ ɞɟɰɟɧɬɪɚɥɿɡɨɜɚɧɨɝɨ ɜɨɞɨɩɨɫɬɚɱɚɧɧɹ ɑɟɪɜɨɧɨ
-ɝɪɚɞɫɶɤɨʀ ɫɚɧɿɬɚɪɧɨ-ɟɩɿɞɟɦɿɨɥɨɝɿɱɧɨʀ ɫɬɚɧɰɿʀ (ɋȿɋ).Ⱦɨɫɥɿɞɠɟɧɧɹ ɫɬɚɧɭ ɚɬɦɨɫɮɟɪɧɨɝɨ ɩɨɜɿɬɪɹ
ɭ ɦ.ɋɨɫɧɿɜɤɚ ɧɚ ɜɦɿɫɬ ɜɭɝɥɟɰɸ ɨɤɫɢɞɭ, ɚɡɨɬɭ
ɞɿɨɤɫɢɞɭ, ɫɿɪɤɢ ɞɿɨɤɫɢɞɭ, ɫɿɪɤɨɜɨɞɧɸ, ɮɨɪɦɚɥɶ
-ɞɟɝɿɞɭ, ɮɬɨɪɢɫɬɨɝɨ ɜɨɞɧɸ ɩɪɨɜɨɞɢɥɢ ɡɚ ɡɚɝɚɥɶ
-ɧɨɩɪɢɣɧɹɬɨɸ ɦɟɬɨɞɢɤɨɸ [10, 12] ɫɩɿɥɶɧɨ ɡ
ɩɪɚɰɿɜɧɢɤɚɦɢ ɤɨɦɭɧɚɥɶɧɨɝɨ ɜɿɞɞɿɥɭ ɑɟɪɜɨɧɨ
-ɝɪɚɞɫɶɤɨʀ ɋȿɋ. Ⱦɥɹ ɨɰɿɧɤɢ ɡɚɛɪɭɞɧɟɧɧɹ ɚɬɦɨ
-ɫɮɟɪɧɨɝɨ ɩɨɜɿɬɪɹ ɩɪɨɜɟɞɟɧɨ ɪɨɡɪɚɯɭɧɨɤ ɩɨ
-ɤɚɡɧɢɤɚ ɝɪɚɧɢɱɧɨ ɞɨɩɭɫɬɢɦɨɝɨ ɡɚɛɪɭɞɧɟɧɧɹ ɿ ɮɚɤɬɢɱɧɨɝɨ ɩɨɤɚɡɧɢɤɚ ɡɚɛɪɭɞɧɟɧɧɹ ɡɝɿɞɧɨ ɡ [4].
ȼɢɡɧɚɱɟɧɧɹ ɞɨɧɨɡɨɥɨɝɿɱɧɢɯ ɩɨɤɚɡɧɢɤɿɜ ɡɞɨ
-ɪɨɜ’ɹ ɩɪɨɜɨɞɢɥɢ ɲɥɹɯɨɦ ɤɨɦɩɥɟɤɫɧɨɝɨ ɨɛɫɬɟ
-ɠɟɧɧɹ ɞɿɬɟɣ 7-10-ɪɿɱɧɨɝɨ ɜɿɤɭ, ɹɤɿ ɧɚɪɨɞɢɥɢɫɶ ɿ
ɩɨɫɬɿɣɧɨ ɩɪɨɠɢɜɚɥɢ ɭ ɦ. ɋɨɫɧɿɜɤɚ ɿ ɦ. ɋɬɚɪɢɣ
ɋɚɦɛɿɪ. ȼɢɡɧɚɱɚɥɢ ɟɥɟɦɟɧɬɧɢɣ ɫɤɥɚɞ ɜɨɥɨɫɫɹ ɬɚ
ɤɪɨɜɿ ɦɟɬɨɞɨɦ ɊɎȺ [6, 7], ɿɧɬɟɧɫɢɜɧɿɫɬɶ ɩɪɨɰɟɫɿɜ
ɩɟɪɨɤɫɢɞɧɨɝɨ ɨɤɢɫɧɟɧɧɹ ɥɿɩɿɞɿɜ (ɉɈɅ) ɬɚ ɚɤɬɢɜ
-ɧɿɫɬɶ ɮɟɪɦɟɧɬɿɜ ɚɧɬɢɨɤɫɢɞɚɧɬɧɨɝɨ ɡɚɯɢɫɬɭ (ȺɈɁ) [16, 20]. Ⱦɨɫɥɿɞɠɟɧɧɹ ɮɿɡɢɱɧɨɝɨ ɪɨɡɜɢɬɤɭ ɞɿɬɟɣ
ɨɛɨɯ ɪɚɣɨɧɿɜ ɩɪɨɜɟɞɟɧɨ ɡɚ ɚɧɬɪɨɩɨɦɟɬɪɢɱɧɢɦɢ ɩɨɤɚɡɧɢɤɚɦɢ ɡɝɿɞɧɨ ɡ ɦɟɬɨɞɢɱɧɢɦɢ ɪɟɤɨɦɟɧ
-ɞɚɰɿɹɦɢ [14]. Ɉɰɿɧɤɭ ɫɬɭɩɟɧɹ ɝɚɪɦɨɧɿɣɧɨɫɬɿ
ɮɿɡɢɱɧɨɝɨ ɪɨɡɜɢɬɤɭ ɩɪɨɜɨɞɢɥɢ ɦɟɬɨɞɨɦ ɪɟɝɪɟ
-ɫɿɣɧɨɝɨ ɚɧɚɥɿɡɭ [2] ɩɨɪɿɜɧɹɧɨ ɡɿ ɫɬɚɧɞɚɪɬɚɦɢ
ɮɿɡɢɱɧɨɝɨ ɪɨɡɜɢɬɤɭ ɞɿɬɟɣ ɍɤɪɚʀɧɢ [15]. ȼɢɡɧɚ
-ɱɟɧɧɹ ɚɞɟɤɜɚɬɧɨɫɬɿ ɯɚɪɱɭɜɚɧɧɹ ɩɪɨɜɨɞɢɥɢ ɚɧ
-ɤɟɬɧɢɦ ɦɟɬɨɞɨɦ, ɩɨɪɿɜɧɸɸɱɢ ɿɡ ɜɿɞɩɨɜɿɞɧɢɦɢ
ɧɨɪɦɚɬɢɜɚɦɢ [11]. Ɋɨɡɪɚɯɭɧɨɤ ɧɭɬɪɿɽɧɬɧɨɝɨ
ɫɤɥɚɞɭ ɪɚɰɿɨɧɭ ɯɚɪɱɭɜɚɧɧɹ ɩɪɨɜɨɞɢɥɢ ɡɚ ɞɨɩɨ
-ɦɨɝɨɸ ɩɪɨɝɪɚɦɢ «ɌɊɏ» (ɇɌɐ «ȼȱɊȱȺ», ɦ. Ʉɢʀɜ) [18]. ɏɚɪɱɨɜɭ ɣ ɛɿɨɥɨɝɿɱɧɭ ɰɿɧɧɿɫɬɶ ɪɚɰɿɨɧɿɜ ɨɰɿ
-ɧɸɜɚɥɢ ɡɚ ɩɨɤɚɡɧɢɤɚɦɢ, ɪɟɝɥɚɦɟɧɬɨɜɚɧɢɦɢ ɧɨɪ
-ɦɚɦɢ ɮɿɡɿɨɥɨɝɿɱɧɨʀ ɩɨɬɪɟɛɢ [8]. ɐɢɮɪɨɜɿ ɪɟɡɭɥɶ
-ɬɚɬɢ ɛɭɥɢ ɨɩɪɚɰɶɨɜɚɧɿ ɡ ɜɢɤɨɪɢɫɬɚɧɧɹɦ ɩɪɨ
-ɝɪɚɦɢ Microsoft Exɫel ɬɚ ɩɪɨɝɪɚɦɧɨɝɨ ɡɚɛɟɡɩɟ
-ɱɟɧɧɹ ȺtteStat. ɍ ɞɨɫɥɿɞɠɟɧɧɿ ɛɭɥɢ ɜɢɤɨɧɚɧɿ
ɦɿɠɧɚɪɨɞɧɿ ɫɬɚɧɞɚɪɬɢ ɳɨɞɨ ɨɬɪɢɦɚɧɧɹ ɩɢɫɶ
ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ
ɞɿɬɟɣ ɭ ɤɨɦɩɥɟɤɫɧɨɦɭ ɨɛɫɬɟɠɟɧɧɿ,ɳɨ ɽ ɟɬɢɱɧɨɸ
ɫɤɥɚɞɨɜɨɸ ɜɢɤɨɧɚɧɧɹ ɞɨɫɥɿɞɠɟɧɶ ɬɚ ɜɡɹɬɬɹ ɛɿɨɦɚɬɟɪɿɚɥɭ.
ɊȿɁɍɅɖɌȺɌɂ ɌȺ Ȳɏ ɈȻȽɈȼɈɊȿɇɇə
ȼɫɬɚɧɨɜɥɟɧɨ, ɳɨ ɞɨɜɤɿɥɥɹ ɦ.ɋɨɫɧɿɜɤɚ ɯɚ
-ɪɚɤɬɟɪɢɡɭɽɬɶɫɹ ɬɟɯɧɨɝɟɧɧɢɦ ɡɚɛɪɭɞɧɟɧɧɹɦ ɭɫɿɯ ɫɟɪɟɞɨɜɢɳ ɬɚ ɡɧɚɱɭɳɢɦ ɞɢɫɛɚɥɚɧɫɨɦ ɟɥɟɦɟɧɬɿɜ:
ɭ ʉɪɭɧɬɚɯ ɜɦɿɫɬ ɯɥɨɪɢɞɿɜ ɩɟɪɟɜɢɳɭɽ ȽȾɄ ɭ 3-4
ɪɚɡɢ, Mn ɦɟɧɲɟ ɜɿɞ ȽȾɄ ɭ 120 ɪɚɡɿɜ, Co – ɦɟɧɲɟ
ɜ 3 ɪɚɡɢ; ɭ ɩɢɬɧɿɣ ɜɨɞɿ ɡɚɮɿɤɫɨɜɚɧɨ ɡɧɢɠɟɧɢɣ
ɜɦɿɫɬ Ca ɭ 12,6 ɪɚɡɭ, K ɭ 2,6 ɪɚɡɭ, ɩɿɞɜɢɳɟɧɢɣ
ɜɦɿɫɬ Cd, Fe ɬɚ Pb ɭ 5, 1,5 ɬɚ 2,3 ɪɚɡɭ ɜɿɞɩɨɜɿɞɧɨ;
ɪɿɜɟɧɶ ɡɚɛɪɭɞɧɟɧɧɹ ɚɬɦɨɫɮɟɪɧɨɝɨ ɩɨɜɿɬɪɹ ɭɩɪɨ
-ɞɨɜɠ 2005-2008 ɪɪ.ɜɢɡɧɚɱɟɧɨ ɹɤ – ɧɟɞɨɩɭɫɬɢɦɢɣ,
ɫɬɭɩɿɧɶ ɧɟɛɟɡɩɟɱɧɨɫɬɿ – ɧɟɛɟɡɩɟɱɧɢɣ, ɭɩɪɨɞɨɜɠ
2009-2012 ɪɪ. – ɧɟɞɨɩɭɫɬɢɦɢɣ, ɩɨɦɿɪɧɨ ɧɟ
-ɛɟɡɩɟɱɧɢɣ ɜɿɞɩɨɜɿɞɧɨ; ɤɿɥɶɤɿɫɬɶ ɧɟɧɨɪɦɚɬɢɜɧɢɯ
ɩɪɨɛ ɩɨɜɿɬɪɹ ɤɨɥɢɜɚɥɚɫɶ ɜɿɞ 23,0 ɞɨ 5,5%.
ȼɩɥɢɜ ɬɟɯɧɨɝɟɧɧɢɯ ɱɢɧɧɢɤɿɜ ɧɚ ɞɢɬɹɱɢɣ ɨɪɝɚɧɿɡɦ ɩɨɬɪɟɛɭɽ ɦɨɧɿɬɨɪɢɧɝɭ ɫɬɚɧɭ ɡɞɨɪɨɜ’ɹ
ɞɿɬɟɣ ɡ ɦɟɬɨɸ ɞɨɧɨɡɨɥɨɝɿɱɧɨʀ ɞɿɚɝɧɨɫɬɢɤɢ ɿ ɩɪɨɮɿɥɚɤɬɢɤɢ ɩɨɱɚɬɤɨɜɢɯ ɩɪɨɹɜɿɜ ɬɟɯɧɨɝɟɧɧɢɯ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɿɜ. Ɂ ɦɟɬɨɸ ɨɰɿɧɤɢ ɞɢɮɟɪɟɧ
-ɰɿɣɨɜɚɧɨɝɨ ɜɩɥɢɜɭ ɟɤɨɫɢɫɬɟɦɢ ɧɚ ɡɞɨɪɨɜ’ɹ ɞɿɬɟɣ
ɞɨɫɥɿɞɠɟɧɧɹ ɛɭɥɨ ɩɪɨɜɟɞɟɧɨ ɜ ɧɚɫɟɥɟɧɢɯ ɩɭɧɤɬɚɯ Ʌɶɜɿɜɫɶɤɨʀ ɨɛɥɚɫɬɿ, ɞɟɳɨ ɪɿɡɧɢɯ ɡɚ
ɩɪɢɪɨɞɧɨ-ɟɤɨɥɨɝɿɱɧɢɦɢ ɬɚ ɬɟɯɧɨɝɟɧɧɢɦɢ ɮɚɤɬɨ
-ɪɚɦɢ, ɚ ɫɚɦɟ ɭ ɦ.ɋɨɫɧɿɜɤɚ (ɬɟɯɧɨɝɟɧɧɨ ɡɚɛɪɭɞ
-ɧɟɧɢɣ ɪɚɣɨɧ) ɬɚ ɦ.ɋɬɚɪɢɣ ɋɚɦɛɿɪ (ɭɦɨɜɧɨ «ɱɢɫ
-ɬɢɣ»ɪɚɣɨɧ) [1, 5].
ɍ ɜɨɥɨɫɫɿ ɞɿɬɟɣ ɦ. ɋɨɫɧɿɜɤɚ ɜɢɹɜɥɟɧɨ ɞɟɮɿɰɢɬ Cu ɭ 96,8%, Ca – ɭ 87,1%, Zn – ɭ 66,1% ɨɛ
-ɫɬɟɠɟɧɢɯ ɞɿɬɟɣ, Se – ɭ 37,8% ɬɚ Fe – ɭ 27,4%
ɞɿɬɟɣ. ɇɚɬɨɦɿɫɬɶ ɭ ɜɨɥɨɫɫɿ ɞɿɬɟɣ ɦ. ɋɬɚɪɢɣ
ɋɚɦɛɿɪ ɞɟɮɿɰɢɬ ɬɚɤɢɯ Ɇȿ ɹɤ Zn, Se ɬɚ Fe ɛɭɥɨ
ɜɢɹɜɥɟɧɨ ɭ ɞɟɳɨ ɦɟɧɲɨʀ ɤɿɥɶɤɨɫɬɿ ɞɿɬɟɣ,ɚ ɫɚɦɟ ɜ 56,6%, 23,8% ɬɚ ɭ 22,6% ɜɿɞɩɨɜɿɞɧɨ. ȼɦɿɫɬ Pb ɭ
ɜɨɥɨɫɫɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɡɧɚɯɨɞɢɜɫɹ ɜ ɦɟɠɚɯ
ɪɟɮɟɪɟɧɬɧɢɯ ɡɧɚɱɟɧɶ, ɚ ɣɨɝɨ ɩɟɪɟɜɢɳɟɧɧɹ ɭ ɬɪɢ
ɪɚɡɢ ɛɭɥɨ ɜɢɹɜɥɟɧɨ ɭ ɜɨɥɨɫɫɿ 9,0% ɲɤɨɥɹɪɿɜ.
ɉɿɞɜɢɳɟɧɭ ɤɨɧɰɟɧɬɪɚɰɿɸ Sr ɜɢɹɜɥɟɧɨ ɭ 66,1 %
ɜɨɥɨɫɫɿ ɞɿɬɟɣ, ɡ ɧɢɯ ɭ 14,6% ɜɦɿɫɬ Sr ɩɟɪɟ
-ɜɢɳɭɜɚɜ ɪɟɮɟɪɟɧɬɧɿ ɡɧɚɱɟɧɧɹ ɭ ɬɪɢ ɪɚɡɢ. ɍ ɜɨ
-ɥɨɫɫɿ ɞɿɬɟɣ ɦ. ɋɬɚɪɢɣ ɋɚɦɛɿɪ ɩɿɞɜɢɳɟɧɢɣ ɜɦɿɫɬ Pb ɿ Sr ɜɢɹɜɢɥɢ ɥɢɲɟ ɜ 4,4%. ɉɨɪɿɜɧɹɥɶɧɢɣ
ɚɧɚɥɿɡ ɟɥɟɦɟɧɬɿɜ ɭ ɜɨɥɨɫɫɿ ɞɿɬɟɣ ɦɿɫɬ ɋɨɫɧɿɜɤɚ ɬɚ ɋɬɚɪɢɣ ɋɚɦɛɿɪ ɜɢɹɜɢɜ ɡɧɚɱɭɳɭ ɪɿɡɧɢɰɸ ɡɚ ɤɿɥɶɤɿɫɬɸ Ca, Cu, Mn, Sr ɬɚ Pb (ɪ<0,001).
Ɂɚ ɪɟɡɭɥɶɬɚɬɚɦɢ ɚɧɚɥɿɡɭ ɟɥɟɦɟɧɬɨɝɪɚɦ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɜɢɹɜɥɟɧɨ ɡɦɟɧɲɟɧɧɹ ɜɦɿɫɬɭ Ca
ɬɚ Cu ɞɨ ɪɿɜɧɹ 37,7±3,1 ɦɤɝ/ɦɥ ɬɚ 0,3±0,03 ɦɤɝ/ɦɥ
ɜɿɞɩɨɜɿɞɧɨ.ɍ 97,2% ɨɛɫɬɟɠɟɧɢɯ ɞɿɬɟɣ ɜɦɿɫɬ Zn ɭ 2,9 ɪɚɡɢ ɦɟɧɲɟ ɧɢɠɧɶɨɝɨ ɩɨɤɚɡɧɢɤɚ ɿɧɬɟɪɜɚɥɭ
ɪɟɮɟɪɟɧɬɧɢɯ ɡɧɚɱɟɧɶ ɿ ɧɚ 58,35% ɦɟɧɲɢɣ, ɧɿɠ ɭ
ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ ɋɚɦɛɿɪ. Ʉɿɥɶɤɿɫɬɶ Se ɽ
ɦɟɧɲɨɸ ɡɚ ɧɢɠɧɸ ɦɟɠɭ ɿɧɬɟɪɜɚɥɭ ɜ 1,5 ɪɚɡɢ, ɬɚ
ɧɚ 44,6% ɦɟɧɲɟ, ɧɿɠ ɭ ɤɪɨɜɿ ɞɿɬɟɣ ɋɬɚɪɨɝɨ
ɋɚɦɛɨɪɚ. ȼɦɿɫɬ K ɭ ɦɟɠɚɯ ɪɟɮɟɪɟɧɬɧɢɯ ɡɧɚɱɟɧɶ
ɡɚɮɿɤɫɨɜɚɧɨ ɥɢɲɟ ɭ 19,4% ɟɥɟɦɟɧɬɨɝɪɚɦ. ȼɦɿɫɬ
Fe ɧɚ 18,4% ɩɟɪɟɜɢɳɭɜɚɜ ɜɟɪɯɧɸ ɦɟɠɭ ɪɟɮɟ
-ɪɟɧɬɧɢɯ ɡɧɚɱɟɧɶ. Ɂɚ ɞɚɧɢɦɢ ɦɿɤɪɨɟɥɟɦɟɧɬɨɝɪɚɦ
ɜɦɿɫɬ Pb, Cd, Hg ɬɚ Sr ɜɢɹɜɥɟɧɨ ɭ ɜɫɿɯ ɡɪɚɡɤɚɯ
ɩɥɚɡɦɢ ɤɪɨɜɿ ɞɿɬɟɣ ɨɛɨɯ ɪɚɣɨɧɿɜ.ɍ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.
ɋɨɫɧɿɜɤɚ ɫɩɨɫɬɟɪɿɝɚɜɫɹ ɡɧɚɱɧɨ ɜɢɳɢɣ ɜɦɿɫɬ Sr ɭ 11,1% ɦɿɤɪɨɟɥɟɦɟɧɬɨɝɪɚɦ, Pb – ɭ 2,8%. ɍ ɤɪɨɜɿ
2,8% ɨɛɫɬɟɠɟɧɢɯ ɞɿɬɟɣ ɜɦɿɫɬ Sr ɩɟɪɟɜɢɳɭɜɚɜ
ɭɦɨɜɧɭ ɧɨɪɦɭ ɭ 2,3 ɪɚɡɢ, ɳɨ, ɣɦɨɜɿɪɧɨ, ɩɨ
-ɜ’ɹɡɚɧɨ ɿɡ ɩɪɨɩɨɪɰɿɣɧɨ ɡɧɢɠɟɧɧɹɦ ɪɿɜɧɹ Ca ɭ
ɤɪɨɜɿ. ɉɪɢ ɩɨɪɿɜɧɹɥɶɧɨɦɭ ɚɧɚɥɿɡɿ ɜɦɿɫɬɭ ɟɥɟ
-ɦɟɧɬɿɜ ɭ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɢ ɬɚ ɦ.ɋɬɚɪɨɝɨ
ɋɚɦɛɨɪɚ ɞɨɫɬɨɜɿɪɧɿ ɜɿɞɦɿɧɧɨɫɬɿ ɜɢɹɜɥɟɧɨ ɡɚ ɜɦɿɫɬɨɦ S, Ca, Cu, Zn, Se (ɪ<0,001), ɚ ɬɚɤɨɠ Cl, K
ɿ Sr (ɪ<0,05).
ɉɪɨɜɟɞɟɧɟ ɜɢɡɧɚɱɟɧɧɹ ɤɨɪɟɥɹɰɿɣɧɢɯ ɡɜ’ɹɡɤɿɜ
ɦɿɠ ɜɦɿɫɬɨɦ Ɇɚȿ-ɬɚ Ɇȿ ɭ ɨɛ’ɽɤɬɚɯ ɞɨɜɤɿɥɥɹ ɬɚ ɭ
ɜɨɥɨɫɫɿ ɞɿɬɟɣ ɦ. ɋɨɫɧɿɜɤɚ. ȼɢɹɜɥɟɧɨ ɜɿɪɨɝɿɞɧɢɣ
ɫɟɪɟɞɧɿɣ ɡɜ’ɹɡɨɤ (r=0,633) ɦɿɠ ɜɦɿɫɬɨɦ F ɭ ɜɨɞɿ ɬɚ
ɜɦɿɫɬɨɦ Mn ɭ ɜɨɥɨɫɫɿ, ɚ ɬɚɤɨɠ ɨɛɟɪɧɟɧɢɣ ɫɟ
-ɪɟɞɧɿɣ ɡɜ’ɹɡɨɤ ɦɿɠ ɜɦɿɫɬɨɦ Cu, Sr (r= - 0,417; r= - 0,507 ɜɿɞɩɨɜɿɞɧɨ) ɬɚ ɜɦɿɫɬɨɦ Mn ɭ ɜɨɥɨɫɫɿ ɞɿɬɟɣ
ɦ.ɋɨɫɧɿɜɤɚ. Ɂɚɮɿɤɫɨɜɚɧɨ ɩɪɹɦɭ ɡɚɥɟɠɧɿɫɬɶ
ɡɪɨɫɬɚɧɧɹ ɜɦɿɫɬɭ Cu ɿ Pb ɭ ɜɨɥɨɫɫɿ ɞɿɬɟɣ ɜɿɞ
ɡɛɿɥɶɲɟɧɧɹ ɤɿɥɶɤɨɫɬɿ Cd ɭ ɩɢɬɧɿɣ ɜɨɞɿ ɦ.ɋɨɫ
-ɧɿɜɤɚ (r=0,767 ɬɚ r=0,483 ɜɿɞɩɨɜɿɞɧɨ). ȼɫɬɚɧɨɜ
-ɥɟɧɨ ɜɿɪɨɝɿɞɧɢɣ ɡɜ’ɹɡɨɤ ɫɟɪɟɞɧɶɨʀ ɫɢɥɢ ɦɿɠ
ɤɿɥɶɤɿɫɬɸ Cu ɭ ɜɨɞɿ ɬɚ ɭ ɜɨɥɨɫɫɿ (r=0,763).
ȼɿɪɨɝɿɞɧɢɣ ɡɜ'ɹɡɨɤ ɫɟɪɟɞɧɶɨʀ ɫɢɥɢ ɜɢɹɜɥɟɧɨ ɦɿɠ
ɜɦɿɫɬɨɦ Se ɭ ɜɨɥɨɫɫɿ ɬɚ Cd ɭ ɜɨɞɿ (r=0,845).
ɉɪɨɜɟɞɟɧɨ ɜɢɡɧɚɱɟɧɧɹ ɤɨɪɟɥɹɰɿɣɧɢɯ ɡɜ’ɹɡɤɿɜ
ɦɿɠ ɜɦɿɫɬɨɦ Ɇɚȿ-ɬɚ Ɇȿ ɜ ɨɛ’ɽɤɬɚɯ ɞɨɜɤɿɥɥɹ ɬɚ ɭ
ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ. ȼɫɬɚɧɨɜɥɟɧɨ ɫɢɥɶɧɢɣ
ɜɿɪɨɝɿɞɧɢɣ ɡɜ’ɹɡɨɤ ɦɿɠ ɤɿɥɶɤɿɫɬɸ Cd ɭ ɜɨɞɿ ɬɚ
ɜɦɿɫɬɨɦ S ɭ ɤɪɨɜɿ ɞɿɬɟɣ (r=0,833); ɫɢɥɶɧɢɣ ɜɿɪɨ
-ɝɿɞɧɢɣ ɡɜ’ɹɡɨɤ ɦɿɠ ɜɦɿɫɬɨɦ Pb ɭ ɜɨɞɿ ɬɚ Sr ɭ
ɜɨɥɨɫɫɿ (r=0,922); ɜɿɪɨɝɿɞɧɢɣ ɡɜ’ɹɡɨɤ ɫɟɪɟɞɧɶɨʀ
ɫɢɥɢ ɦɿɠ ɧɢɡɶɤɢɦ ɜɦɿɫɬɨɦ Zn (0,03±0,01,
ȽȾɄ=1,0 ɦɝ/ɞɦ3) ɭ ɩɢɬɧɿɣ ɜɨɞɿ ɦ.ɋɨɫɧɿɜɤɚ ɬɚ
ɧɢɡɶɤɢɦ ɣɨɝɨ ɜɦɿɫɬɨɦ ɭ ɤɪɨɜɿ ɞɿɬɟɣ (r=0,836), ɚ
ɬɚɤɨɠ ɧɢɡɶɤɢɦ ɜɦɿɫɬɨɦ Cu (r=0,431).
Ⱦɥɹ ɞɿɚɝɧɨɫɬɢɤɢ ɬɟɯɧɨɝɟɧɧɨɝɨ ɜɩɥɢɜɭ ɧɚ ɫɬɚɧ ɡɞɨɪɨɜ’ɹ ɞɿɬɟɣ ɜɢɡɧɚɱɚɥɢ ɿɧɬɟɧɫɢɜɧɿɫɬɶ ɩɪɨɰɟɫɿɜ
ɉɈɅ ɬɚ ȺɈɁ. ɍ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɜɦɿɫɬ
ɌȻɄ-ɚɤɬɢɜɧɢɯ ɩɪɨɞɭɤɬɿɜ ɽ ɜɢɳɢɦ ɩɨɪɿɜɧɹɧɨ ɡɿ
ɡɧɚɱɟɧɧɹɦɢ ɭ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ ɋɚɦɛɿɪ ɧɚ 24,67% (ɪ<0,05).ɍ ɤɪɨɜɿ ɞɿɬɟɣ ɦ. ɋɨɫɧɿɜɤɚ ɜɢɹɜɥɟɧɨ ɞɨ
-ɫɬɨɜɿɪɧɟ ɡɧɢɠɟɧɧɹ ɚɤɬɢɜɧɨɫɬɿ ɫɭɩɟɪɨɤɫɢɞɞɢɫ
-ɦɭɬɚɡɢ (ɋɈȾ) ɧɚ 24,87%, ɤɚɬɚɥɚɡɢ ɧɚ 10,0% (ɪ<0,05), ɝɥɭɬɚɬɿɨɧɩɟɪɨɤɫɢɞɚɡɢ (ȽɉɈ) ɧɚ 25,3%
ɪɚɣɨɧɭ.ȼɦɿɫɬ ɰɟɪɭɥɨɩɥɚɡɦɿɧɭ (ɐɉ)ɭ ɤɪɨɜɿ ɞɿɬɟɣ
ɦ.ɋɨɫɧɿɜɤɚ ɧɚ 19,8% (ɪ<0,05) ɽ ɜɢɳɢɦ, ɧɿɠ ɭ
ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ ɋɚɦɛɿɪ. ȼɢɹɜɥɟɧɨ ɞɨɫɬɨ
-ɜɿɪɧɟ ɡɦɟɧɲɟɧɧɹ ɭ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɤɿɥɶ
-ɤɨɫɬɿ ɟɪɢɬɪɨɰɢɬɿɜ ɧɚ 24,95% ɬɚ ɜɦɿɫɬɭ
ɝɟɦɨɝɥɨɛɿɧɭ ɧɚ 18,92% (ɪ<0,001), ɿ ɡɛɿɥɶɲɟɧɧɹ
ɤɨɥɶɨɪɨɜɨɝɨ ɩɨɤɚɡɧɢɤɚ ɧɚ 7,04%% (ɪ<0,05) ɜɿɞ
-ɩɨɜɿɞɧɨ ɳɨɞɨ ɩɨɤɚɡɧɢɤɿɜ ɭ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ
ɋɚɦɛɿɪ. ȼɦɿɫɬ ɌȻɄ-ɚɤɬɢɜɧɢɯ ɩɪɨɞɭɤɬɿɜ ɜ ɟɪɢ
-ɬɪɨɰɢɬɚɯ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɽ ɧɚ 53,17% ɜɢɳɢɦ
ɩɨɪɿɜɧɹɧɨ ɡɿ ɡɧɚɱɟɧɧɹɦɢ ɭ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ
ɋɚɦɛɿɪ. ɉɪɢ ɜɢɜɱɟɧɧɿ ɪɟɡɢɫɬɟɧɬɧɨɫɬɿ ɟɪɢɬɪɨ
-ɰɢɬɿɜ ɞɨ ɞɿʀ ɩɟɪɨɤɫɢɞɭ ɜɨɞɧɸ ɛɭɥɨ ɨɬɪɢɦɚɧɨ ɞɨɫɬɨɜɿɪɧɟ ɡɛɿɥɶɲɟɧɧɹ ɜɿɞɫɨɬɤɚ ɝɟɦɨɥɿɡɨɜɚɧɢɯ ɟɪɢɬɪɨɰɢɬɿɜ ɭ ɤɪɨɜɿ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ, ɚ ɬɚɤɨɠ
ɡɛɿɥɶɲɟɧɧɹ ɩɪɨɧɢɤɧɨɫɬɿ ɟɪɢɬɪɨɰɢɬɚɪɧɢɯ ɦɟɦ
-ɛɪɚɧ ɿ, ɜɿɞɩɨɜɿɞɧɨ, ɡɛɿɥɶɲɟɧɧɹ ɜɿɞɫɨɬɤɚ ʀɯ
ɝɟɦɨɥɿɡɭ ɩɨɪɿɜɧɹɧɨ ɿɡ ɩɨɤɚɡɧɢɤɚɦɢ ɨɫɦɨɬɢɱɧɨʀ ɪɟɡɢɫɬɟɧɬɧɨɫɬɿ ɟɪɢɬɪɨɰɢɬɿɜ ɤɪɨɜɿ ɞɿɬɟɣ ɤɨɧɬɪɨɥɶ
-ɧɨɝɨ ɪɚɣɨɧɭ.
ɍ ɞɿɬɟɣ ɦ. ɋɨɫɧɿɜɤɚ ɡɚɮɿɤɫɨɜɚɧɨ ɡɚɥɟɠɧɨɫɬɿ
ɦɿɠ ɨɫɧɨɜɧɢɦɢ ɞɨɫɥɿɞɠɭɜɚɧɢɦɢ ɩɨɤɚɡɧɢɤɚɦɢ, ɚ
ɫɚɦɟ: ɜɦɿɫɬɨɦ Hg ɭ ɜɨɥɨɫɫɿ ɿ ɩɟɪɨɤɫɢɞɧɨɸ
ɪɟɡɢɫɬɟɧɬɧɿɫɬɸ ɟɪɢɬɪɨɰɢɬɿɜ (r=0,41; ɪ<0,01) ɣ
ɪɿɜɧɟɦ ɦɚɥɨɧɨɜɨɝɨ ɞɢɚɥɶɞɟɝɿɞɭ (ɆȾ) (r=0,32;
ɪ<0,05); ɚɤɬɢɜɧɿɫɬɸ ȽɊ ɿ ɜɦɿɫɬɨɦ ɭ ɜɨɥɨɫɫɿ Fe ɿ Co (ɜɿɞɩɨɜɿɞɧɨ r=0,57 ɿ 0,43; ɪ<0,01 ɜ ɨɛɨɯ ɜɢ
-ɩɚɞɤɚɯ); ɩɟɪɨɤɫɢɞɧɨɸ ɪɟɡɢɫɬɟɧɬɧɿɫɬɸ ɟɪɢɬɪɨ
-ɰɢɬɿɜ ɿ ɪɿɜɧɟɦ ɰɢɧɤɭ (r=-0,49; ɪ<0,05); ɚɤɬɢɜ
-ɧɿɫɬɸ ɐɉ ɿ ɜɦɿɫɬɨɦ Mn (r=0,47; ɪ<0,05); ɚɤɬɢɜ
-ɧɿɫɬɸ ȽɉɈ ɿ ɤɿɥɶɤɿɫɬɸ Ca ɬɚ Cu (r=0,52; ɪ<0,05ɜ
ɨɛɨɯ ɜɢɩɚɞɤɚɯ). ɍ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ ɋɚɦɛɿɪ ɜɢɹɜ
-ɥɟɧɨ ɡɚɥɟɠɧɿɫɬɶ ɦɿɠ ɜɦɿɫɬɨɦ Se ɭ ɜɨɥɨɫɫɿ ɣ
ɚɤɬɢɜɧɿɫɬɸ ȽɉɈ (r=0,80) ɿ ɪɿɜɧɟɦ ɆȾ (r=-0,813) (ɪ<0,05 ɜ ɨɛɨɯ ɜɢɩɚɞɤɚɯ). Ɂ’ɹɫɨɜɚɧɨ, ɳɨ ɜ ɞɿɬɟɣ
ɦ.ɋɨɫɧɿɜɤɚ ɜɦɿɫɬ ɞɿɽɧɨɜɢɯ ɤɨɧ’ɸɝɚɬɿɜ ɡɚɥɟɠɢɬɶ
ɜɿɞ ɪɿɜɧɹ ɭ ɤɪɨɜɿ Se (r=-0,87) ɿ Pb (r=0,85),
ɚɤɬɢɜɧɿɫɬɶ ɐɉ – ɜɿɞ ɜɦɿɫɬɭ ɭ ɤɪɨɜɿ Ni (r=-0,62), Br (r=-0,85) ɿ Sr (r=0,69) (ɭ ɜɫɿɯ ɜɢɩɚɞɤɚɯ ɪ<0,05);
ɭ ɞɿɬɟɣ ɦ. ɋɬɚɪɢɣ ɋɚɦɛɿɪ ɩɟɪɨɤɫɢɞɧɚ ɪɟɡɢɫɬɟɧɬ
-ɧɿɫɬɶ ɟɪɢɬɪɨɰɢɬɿɜ – ɜɿɞ ɜɦɿɫɬɭ Hg (r=0,65;
ɪ<0,01).
Ⱥɧɬɪɨɩɨɦɟɬɪɢɱɧɿ ɩɨɤɚɡɧɢɤɢ ɞɿɬɟɣ ɦ. ɋɨɫɧɿɜ
-ɤɚ ɜɿɞɪɿɡɧɹɸɬɶɫɹ ɡɚ ɡɪɨɫɬɨɦ ɭ ɤɨɠɧɿɣ ɜɿɤɨɜɿɣ ɝɪɭɩɿ ɜɿɞ 7 ɞɨ 10 ɪɨɤɿɜ (ɪ<0,001);ɡɚ ɩɨɤɚɡɧɢɤɚɦɢ
ɦɚɫɢ ɬɿɥɚ ɬɚ ɨɛɜɨɞɭ ɝɪɭɞɧɨʀ ɤɥɿɬɤɢ ɞɿɬɟɣ ɨɛɨɯ ɪɚɣɨɧɿɜ ɡɚɮɿɤɫɨɜɚɧɨ ɡɧɚɱɭɳɭ ɪɿɡɧɢɰɸ (ɪ<0,001)
ɥɢɲɟ ɫɟɪɟɞ ɞɿɬɟɣ 7-ɢ, 8-ɢ ɬɚ 10-ɪɿɱɧɨɝɨ ɜɿɤɭ;ɭ
9-ɢ ɪɿɱɧ9-ɢɯ ɞɿɬɟɣ ɪɿɡɧ9-ɢɰɿ ɡɚ ɰ9-ɢɦ9-ɢ ɩɨɤɚɡɧ9-ɢɤɚɦ9-ɢ ɧɟɦɚɽ.Ƚɚɪɦɨɧɿɣɧɢɣ ɮɿɡɢɱɧɢɣ ɪɨɡɜɢɬɨɤ ɜɢɹɜɥɟɧɨ
ɭ 48,6% ɞɿɬɟɣ ɦ. ɋɨɫɧɿɜɤɚ, ɞɢɫɝɚɪɦɨɧɿɣɧɢɣ – ɭ 18,4%, ɪɿɡɤɨ ɞɢɫɝɚɪɦɨɧɿɣɧɢɣ – ɭ 34,8%, ɬɨɞɿ ɹɤ
ɉɪɨɞɭɤɬɨɜɿ ɧɚɛɨɪɢ ɪɚɰɿɨɧɿɜ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ
ɬɚ ɦ.ɋɬɚɪɢɣ ɋɚɦɛɿɪ ɧɟ ɜɿɞɩɨɜɿɞɚɥɢ ɪɟɤɨɦɟɧ
-ɞɨɜɚɧɢɦ ɧɨɪɦɚɦ ɫɩɨɠɢɜɚɧɧɹ ɨɫɧɨɜɧɢɯ ɯɚɪɱɨɜɢɯ ɩɪɨɞɭɤɬɿɜ. ȿɧɟɪɝɟɬɢɱɧɚ ɰɿɧɧɿɫɬɶ ɯɚɪɱɨɜɨɝɨ
ɪɚɰɿɨɧɭ ɞɿɬɟɣ ɨɛɨɯ ɦɿɫɬ ɽ ɧɢɠɱɨɸ ɮɿɡɿɨɥɨɝɿɱɧɨʀ ɩɨɬɪɟɛɢ ɧɚ 13,5% ɬɚ 5,2% ɜɿɞɩɨɜɿɞɧɨ. ɍ 60%
ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɜɢɹɜɥɟɧɨ ɡɧɚɱɧɟ ɡɧɢɠɟɧɧɹ ɫɩɨ
-ɠɢɜɚɧɧɹ ɛɿɥɤɚ ɜɿɞ ɜɿɤɨɜɨʀ ɩɨɬɪɟɛɢ. Ⱦɿɬɢ ɦ.ɋɬɚ
-ɪɢɣ ɋɚɦɛɿɪ ɫɩɨɠɢɜɚɸɬɶ ɛɿɥɤɚ ɧɚ 3,5% ɛɿɥɶɲɟ,
ɧɿɠ ɞɿɬɢ ɦ.ɋɨɫɧɿɜɤɚ. ɋɩɨɠɢɜɚɧɧɹ ɞɿɬɶɦɢ ɨɛɨɯ
ɦɿɫɬ ɠɢɪɿɜ ɫɬɚɧɨɜɢɬɶ ɜɿɞɩɨɜɿɞɧɨ 92,14% ɬɚ
93,4%. Ɂɚɛɟɡɩɟɱɟɧɧɹ ɜɭɝɥɟɜɨɞɚɦɢ ɲɤɨɥɹɪɿɜ
ɦ.ɋɨɫɧɿɜɤɢ ɫɬɚɧɨɜɢɥɨ 83,4% ɜɿɞ ɞɨɛɨɜɨʀ ɩɨɬɪɟɛɢ
ɬɚ ɧɚ 12,5% ɦɟɧɲɟ ɜɿɞ ɫɩɨɠɢɜɚɧɧɹ ɞɿɬɶɦɢ ɦ.
ɋɬɚɪɢɣ ɋɚɦɛɿɪ.ɍ ɪɚɰɿɨɧɚɯ ɲɤɨɥɹɪɿɜ ɦ.ɋɨɫɧɿɜɤɚ
ɜɦɿɫɬ ɜɿɬɚɦɿɧɭ Ⱥ ɫɬɚɧɨɜɢɬɶ 61,9% ɜɿɞ ɧɨɪɦɢ
ɮɿɡɿɨɥɨɝɿɱɧɨʀ ɩɨɬɪɟɛɢ; ɜɿɬɚɦɿɧɭ ɊɊ – ɧɚ 19,4%
ɦɟɧɲɟ ɧɨɪɦɢ ɮɿɡɿɨɥɨɝɿɱɧɨʀ ɩɨɬɪɟɛɢ; ɜɦɿɫɬ
ɜɿɬɚɦɿɧɭ ɋ – ɧɚ 16% ɩɟɪɟɜɢɳɭɜɚɜ ɞɨɛɨɜɭ
ɩɨɬɪɟɛɭ. ɇɚɬɨɦɿɫɬɶ ɭ ɪɚɰɿɨɧɚɯ ɞɿɬɟɣ ɦ.ɋɬɚɪɢɣ
ɋɚɦɛɿɪ ɜɢɹɜɥɟɧɨ ɥɢɲɟ ɞɟɮɿɰɢɬ ɜɿɬɚɦɿɧɭ ɊɊ ɧɚ
11,4%. ȼɫɬɚɧɨɜɥɟɧɨ, ɳɨ ɜ ɪɚɰɿɨɧɚɯ ɞɿɬɟɣ
ɦ.ɋɨɫɧɿɜɤɢ ɤɿɥɶɤɿɫɬɶ Ca ɧɢɠɱɚ ɡɚ ɧɟɨɛɯɿɞɧɭ ɭ
ɦɚɣɠɟ ɞɜɚ ɪɚɡɢ; ɽ ɧɟɞɨɫɬɚɬɧɿɫɬɶ Zn ɧɚ 16,6%;
ɜɢɹɜɥɟɧɨ ɧɚ 18,17% ɩɿɞɜɢɳɟɧɢɣ ɜɦɿɫɬ Fe, ɚ
ɫɩɿɜɜɿɞɧɨɲɟɧɧɹ Ca:P:Mn ɫɬɚɧɨɜɢɬɶ 1:1,8:0,5.
ɉɪɚɤɬɢɱɧɨ ɬɚɤɚ ɠ ɤɚɪɬɢɧɚ ɫɩɨɫɬɟɪɿɝɚɽɬɶɫɹ ɿ ɜ ɯɚɪɱɭɜɚɧɧɿ ɲɤɨɥɹɪɿɜ ɦɿɫɬɚ ɋɬɚɪɢɣ ɋɚɦɛɿɪ.
Ɉɞɧɚɤɨɜɢɣ ɞɟɮɿɰɢɬ ɧɭɬɪɿɽɧɬɿɜ ɭ ɯɚɪɱɨɜɢɯ ɪɚɰɿɨɧɚɯ ɞɿɬɟɣ ɨɛɨɯ ɦɿɫɬ ɩɪɢ ɪɿɡɧɨɦɭ ɫɬɭɩɟɧɿ ɜɢɪɚɠɟɧɨɫɬɿ ɞɢɫɝɨɦɟɨɫɬɚɡɭ Ɇɚȿ ɬɚ Ɇȿ ɭ ɛɿɨɫɭɛ
-ɫɬɪɚɬɚɯ ɜɤɚɡɭɸɬɶ ɧɚ ɜɩɥɢɜ ɟɤɡɨɝɟɧɧɢɯ ɱɢɧɧɢɤɿɜ,
ɚ ɫɚɦɟ ɬɟɯɧɨɝɟɧɧɨ ɡɚɛɪɭɞɧɟɧɨɝɨ ɞɨɜɤɿɥɥɹ.
Ɂ ɦɟɬɨɸ ɩɨɩɟɪɟɞɠɟɧɧɹ ɧɟɝɚɬɢɜɧɨɝɨ ɜɩɥɢɜɭ ɬɟɯɧɨɝɟɧɧɨ ɡɚɛɪɭɞɧɟɧɨɝɨ ɞɨɜɤɿɥɥɹ ɧɚ ɨɪɝɚɧɿɡɦ ɞɿɬɟɣ ɧɟɨɛɯɿɞɧɨ ɩɪɨɜɨɞɢɬɢ ɤɨɦɩɥɟɤɫ ɡɚɯɨɞɿɜ ɞɥɹ ɩɪɨɮɿɥɚɤɬɢɤɢ ɪɨɡɜɢɬɤɭ ɬɟɯɧɨɝɟɧɧɢɯ ɦɿɤɪɨɟɥɟ
-ɦɟɧɬɨɡɿɜ, ɹɤɿ ɭɡɚɝɚɥɶɧɟɧɿ ɧɚɦɢ ɭ ɜɢɝɥɹɞɿ
ɦɟɬɨɞɢɱɧɨʀ ɫɯɟɦɢ,ɳɨ ɜɤɥɸɱɚɽ:ɬɟɯɧɿɱɧɿ ɿ ɬɟɯɧɨ
-ɥɨɝɿɱɧɿ ɪɨɡɪɨɛɤɢ, ɛɿɨɥɨɝɿɱɧɿ ɿ ɦɟɞɢɤɨ-ɩɪɨ
-ɮɿɥɚɤɬɢɱɧɿ ɡɚɯɨɞɢ (ɪɢɫ.).
Ⱦɿɥɶɧɢɱɧɢɦ ɩɟɞɿɚɬɪɚɦ ɪɟɤɨɦɟɧɞɭɜɚɬɢ ɩɪɨɜɨ
-ɞɢɬɢ ɩɪɢɰɿɥɶɧɿ ɩɪɨɮɿɥɚɤɬɢɱɧɿ ɦɟɞɢɱɧɿ ɨɝɥɹɞɢ ɡ ɭɪɚɯɭɜɚɧɧɹɦ ɪɟɚɤɰɿɣ ɞɢɬɹɱɨɝɨ ɨɪɝɚɧɿɡɦɭ ɧɚ ɜɩɥɢɜ ɡɚɛɪɭɞɧɸɸɱɢɯ ɮɚɤɬɨɪɿɜ ɞɨɜɤɿɥɥɹ. Ⱦɨɫɥɿɞ
-ɠɭɜɚɬɢ ɫɬɚɧ ɟɥɟɦɟɧɬɧɨɝɨ ɝɨɦɟɨɫɬɚɡɭ ɤɨɠɧɨʀ ɞɢɬɢɧɢ ɲɥɹɯɨɦ ɜɢɡɧɚɱɟɧɧɹɦ Ɇɚȿ ɿ Ɇȿ ɫɤɥɚɞɭ ɜɨɥɨɫɫɹ ɹɤ ɧɚɣɛɿɥɶɲ ɜɢɫɨɤɨɿɧɮɨɪɦɚɬɢɜɧɨɝɨ ɦɚɥɨɿɧɜɚɡɢɜɧɨɝɨ ɤɪɢɬɟɪɿɸ ɞɿɚɝɧɨɫɬɢɤɢ ɩɟɪɜɢɧ
-ɧɢɯ ɩɪɨɹɜɿɜ ɞɢɫɟɥɟɦɟɧɬɧɨɝɨ ɫɬɚɧɭ ɬɚ ɞɨɧɨɡɨɥɨ
ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ
Ɇɟɬɨɞɢɱɧɚ ɫɯɟɦɚ ɤɨɪɟɤɰɿʀ ɜɩɥɢɜɭ ɬɟɯɧɨɝɟɧɧɨɝɨ ɡɚɛɪɭɞɧɟɧɧɹ ɧɚ ɨɪɝɚɧɿɡɦ ɞɿɬɟɣ ɉȱȾɋɍɆɈɄ
ɉɪɨɜɿɞɧɢɦ ɱɢɧɧɢɤɨɦ ɪɨɡɜɢɬɤɭ ɞɨɧɨɡɨɥɨ
-ɝɿɱɧɢɯ ɡɪɭɲɟɧɶ ɭ ɡɞɨɪɨɜ’ʀ ɞɿɬɟɣ ɦ.ɋɨɫɧɿɜɤɚ ɽ
ɧɚɞɯɨɞɠɟɧɧɹ ɬɨɤɫɢɤɚɧɬɿɜ ɡ ɭɫɿɯ ɫɮɟɪ ɞɨɜɤɿɥɥɹ,
ɳɨ ɡɚɫɜɿɞɱɢɥɨ ɜɢɹɜɥɟɧɧɹ ɤɫɟɧɨɛɿɨɬɢɤɿɜ ɭ ʉɪɭɧɬɿ,
ɜɨɞɿ ɬɚ ɚɬɦɨɫɮɟɪɧɨɦɭ ɩɨɜɿɬɪɿ ɣ ɫɩɪɨɜɨɤɭɜɚɥɨ ɞɢɫɛɚɥɚɧɫ ɦɿɠ ɩɪɨɰɟɫɚɦɢ ɧɚɞɯɨɞɠɟɧɧɹ, ɭɬɢɥɿ
-ɡɚɰɿʀ ɣ ɟɥɿɦɿɧɚɰɿʀ Ɇɚȿ ɬɚ Ɇȿ ɭ ɜɨɥɨɫɫɿ ɬɚ ɤɪɨɜɿ ɞɿɬɟɣ,ɡɦɿɧɢ ɪɿɜɧɨɜɚɝɢ ɦɿɠ ɨɤɫɢɞɚɰɿɣɧɢɦ ɫɬɪɟɫɨɦ
ɬɚ ȺɈɋ ɡɚɯɢɫɬɭ ɨɪɝɚɧɿɡɦɭ,ɩɨɪɭɲɟɧɧɹ ɮɿɡɢɱɧɨɝɨ
ɪɨɡɜɢɬɤɭ, ɳɨ ɧɚ ɮɨɧɿ ɮɿɡɿɨɥɨɝɿɱɧɨ ɧɟɩɨɜɧɨɰɿɧ
-ɧɨɝɨ ɿ ɧɟɡɛɚɥɚɧɫɨɜɚ-ɧɨɝɨ ɯɚɪɱɭɜɚɧɧɹ ɫɩɪɢɱɢɧɢɥɨ ɪɨɡɜɢɬɨɤ ɭ ɞɿɬɟɣ ɬɟɯɧɨɝɟɧɧɨɝɨ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɭ.
ɉɟɪɫɩɟɤɬɢɜɢ ɩɨɞɚɥɶɲɢɯ ɞɨɫɥɿɞɠɟɧɶ ɦɨɠɭɬɶ ɛɭɬɢ ɩɨɜ’ɹɡɚɧɿ ɡ ɩɨɲɭɤɨɦ ɧɨɜɢɯ ɲɥɹɯɿɜ ɬɚ
ɭɞɨɫɤɨɧɚɥɟɧɧɹɦ ɦɟɬɨɞɿɜ ɩɪɨɮɿɥɚɤɬɢɤɢ ɪɨɡɜɢɬɤɭ ɭ ɞɿɬɟɣ ɬɟɯɧɨɝɟɧɧɢɯ ɦɿɤɪɨɟɥɟɦɟɧɬɨɡɿɜ.
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ɋɈ
ɈɄ
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ȺɌ
Ɍɍ
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1. ȼɩɥɢɜ ɯɿɦɿɱɧɢɯ ɮɚɤɬɨɪɿɜ ɦɚɥɨʀ ɿɧɬɟɧɫɢɜɧɨɫɬɿ ɧɚ ɡɞɨɪɨɜ’ɹ ɧɚɫɟɥɟɧɧɹ Ʌɶɜɿɜɫɶɤɨʀ ɨɛɥɚɫɬɿ / ȼ.ȱ.Ɏɟɞɨ -ɪɟɧɤɨ,Ɉ.Ȼ.Ⱦɟɧɢɫɸɤ,ȱ.Ƚ.Ɇɭɞɪɚ,Ʌ.Ɇ.Ʉɿɰɭɥɚ // Ƚɿɝɿɽ -ɧɚ -ɧɚɫɟɥɟɧɢɯ ɦɿɫɰɶ. – 2007. – ȼɢɩ. 49. – ɋ. 177–183.
2. Ƚɢɝɢɟɧɚ ɞɟɬɟɣ ɢ ɩɨɞɪɨɫɬɤɨɜ : ɪɭɤɨɜɨɞɫɬɜɨ ɞɥɹ ɫɚɧɢɬɚɪɧɵɯ ɜɪɚɱɟɣ; ɩɨɞ. ɪɟɞ. Ƚ.ɇ. ɋɟɪɞɸɤɨɜɫɤɨɣ, Ⱥ.Ƚ.ɋɭɯɚɪɟɜɚ. – Ɇ.:Ɇɟɞɢɰɢɧɚ, 1986. – ɋ. 129–131.
3. Ⱦɟɪɠɚɜɧɿ ɫɚɧɿɬɚɪɧɿ ɩɪɚɜɢɥɚ ɿ ɧɨɪɦɢ “Ƚɿɝɿɽɧɿɱɧɿ ɜɢɦɨɝɢ ɞɨ ɜɨɞɢ ɩɢɬɧɨʀ,ɩɪɢɡɧɚɱɟɧɨʀ ɞɥɹ ɫɩɨɠɢɜɚɧɧɹ ɥɸɞɢɧɨɸ”. – Ⱦɋɚɧɉɿɇ 2.2.4-171-10. – Ɂɚɬɜ. ɇɚɤɚɡɨɦ ɆɈɁ ɍɤɪɚʀɧɢ ɜɿɞ 12.05.2010 ɪ.ʋ 400.
4. Ⱦɟɪɠɚɜɧɿ ɫɚɧɿɬɚɪɧɿ ɩɪɚɜɢɥɚ ɨɯɨɪɨɧɢ ɚɬɦɨ -ɫɮɟɪɧɨɝɨ ɩɨɜɿɬɪɹ ɧɚɫɟɥɟɧɢɯ ɦɿɫɰɶ (ɜɿɞ ɡɚɛɪɭɞɧɟɧɧɹ ɯɿɦɿɱɧɢɦɢ ɬɚ ɛɿɨɥɨɝɿɱɧɢɦɢ ɪɟɱɨɜɢɧɚɦɢ). – Ⱦɋɉ
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5. Ʉɥɢɦɱɭɤ Ɇ.Ⱥ.ɋɬɚɧ ɧɚɜɤɨɥɢɲɧɶɨɝɨ ɫɟɪɟɞɨɜɢ -ɳɚ ɬɚ ɣɨɝɨ ɜɩɥɢɜ ɧɚ ɡɞɨɪɨɜ’ɹ ɧɚɫɟɥɟɧɧɹ Ʌɶɜɿɜɫɶɤɨʀ ɨɛɥɚɫɬɿ / Ɇ.Ⱥ.Ʉɥɢɦɱɭɤ // Ⱦɨɜɤɿɥɥɹ ɬɚ ɡɞɨɪɨɜ’ɹ. – 2005. – ʋ 3 (34). – ɋ. 43–48.
6. Ɇɟɬɨɞɢɤɚ ɜɢɤɨɧɚɧɧɹ ɜɢɦɿɪɸɜɚɧɶ ɜɦɿɫɬɭ ɯɿɦɿɱ -ɧɢɯ ɟɥɟɦɟɧɬɿɜ ɜ ɩɥɚɡɦɿ ɤɪɨɜɿ ɪɟɧɬɝɟɧɨ-ɮɥɸɨɪɢɫɰɟɧɬ -ɧɢɦ ɦɟɬɨɞɨɦ. – Ɇȼȼ 081/12-0468-07 ɜɿɞ 12.10.2007 ɪ.
7. Ɇɭɥɶɬɢɷɥɟɦɟɧɬɧɵɣ ɚɧɚɥɢɡ ɜɨɥɨɫ: ɧɨɜɵɟ ɜɨɡɦɨ -ɠɧɨɫɬɢ ɞɢɚɝɧɨɫɬɢɤɢ / ȯ.Ʉɢɪɢɥɟɧɤɨ, Ⱥ. Ʉɢɪɢɥɟɧɤɨ, ɋ.Ʌɟɫɧɢɤ,ɋ.Ɏɭɫ // Ʌɿɤɢ ɍɤɪɚʀɧɢ.–2001.–ʋ12.–ɋ. 28–29. 8. ɇɨɪɦɢ ɮɿɡɿɨɥɨɝɿɱɧɢɯ ɩɨɬɪɟɛ ɧɚɫɟɥɟɧɧɹ ɍɤɪɚʀ -ɧɢ ɜ ɨɫɧɨɜ-ɧɢɯ ɯɚɪɱɨɜɢɯ ɪɟɱɨɜɢɧɚɯ ɬɚ ɟɧɟɪɝɿʀ;ɡɚɬɜɟɪɞ -ɠɟɧɿ ɧɚɤɚɡɨɦ ɆɈɁ ɍɤɪɚʀɧɢ ʋ 272 ɜɿɞ 18.11.1999 ɪ.
ɧɵɯ ɦɟɫɬ. – ȽɈɋɌ 17.2.3.01-86. – Ɇ.: ɂɡɞ-ɜɨ ɫɬɚɧ -ɞɚɪɬɨɜ, 1986. – 16 ɫ.
11. ɉɪɨ ɡɚɬɜɟɪɞɠɟɧɧɹ ɧɨɪɦ ɯɚɪɱɭɜɚɧɧɹ ɭ ɧɚɜɱɚɥɶ -ɧɢɯ ɬɚ ɨɡɞɨɪɨɜɱɢɯ ɡɚɤɥɚɞɚɯ: ɩɨɫɬɚɧɨɜɚ ɄɆ ɍɤɪɚʀɧɢ ɜɿɞ 22.11.2004 ɪ.ʋ 1591.
12. Ɋɭɤɨɜɨɞɹɳɢɣ ɞɨɤɭɦɟɧɬ. Ɋɭɤɨɜɨɞɫɬɜɨ ɩɨ ɤɨɧɬɪɨɥɸ ɡɚɝɪɹɡɧɟɧɢɹ ɚɬɦɨɫɮɟɪɵ. – ɊȾ 52.04.186-89.
13. ɋɚɧɢɬɚɪɧɵɟ ɩɪɚɜɢɥɚ ɢ ɧɨɪɦɵ ɨɯɪɚɧɵ ɩɨ -ɜɟɪɯɧɨɫɬɧɵɯ ɜɨɞ ɨɬ ɡɚɝɪɹɡɧɟɧɢɹ. – ɋɚɧɉɢɇ 4630-88. – Ɇ., 1988. – 50 ɫ.
14. ɋɬɚɜɢɰɶɤɚ Ⱥ.Ȼ.Ɇɟɬɨɞɢɤɚ ɢɫɫɥɟɞɨɜɚɧɢɹ ɮɢɡɢ -ɱɟɫɤɨɝɨ ɪɚɡɜɢɬɢɹ ɞɟɬɟɣ ɢ ɩɨɞɪɨɫɬɤɨɜ / Ⱥ.Ȼ.ɋɬɚɜɢɰɶ -ɤɚ,Ⱦ.ɂ.Ⱥɪɨɧ. – Ɇ., 1959. – 24 ɫ.
15. ɋɬɚɧɞɚɪɬɢ ɞɥɹ ɨɰɿɧɤɢ ɮɿɡɢɱɧɨɝɨ ɪɨɡɜɢɬɤɭ ɲɤɨɥɹ -ɪɿɜ.–ȼɢɩ. 3 / ɩɿɞ ɪɟɞ.Ⱥ.Ɇ.ɋɟɪɞɸɤɚ.–Ʉ.:Ʉɚɡɤɚ, 2010.–60 ɫ. 16. ɋɬɚɬɟɜɨ-ɜɿɤɨɜɿ ɨɫɨɛɥɢɜɨɫɬɿ ɦɿɤɪɨɟɥɟɦɟɧɬ -ɧɨɝɨ ɫɬɚɬɭɫɭ ɧɚɫɟɥɟɧɧɹ ɩɪɨɦɢɫɥɨɜɨɝɨ ɪɟɝɿɨɧɭ /
17. Ɍɹɠɟɥɵɟ ɦɟɬɚɥɥɵ ɜɧɟɲɧɟɣ ɫɪɟɞɵ ɢ ɢɯ ɜɥɢɹ -ɧɢɟ ɧɚ ɪɟɩɪɨɞɭɤɬɢɜɧɭɸ ɮɭɧɤɰɢɸ ɠɟɧɳɢɧ / Ⱥ.Ɇ.ɋɟɪ -ɞɸɤ,ɗ.ɇ.Ȼɟɥɢɰɤɚɹ,ɇ.Ɇ.ɉɚɪɚɧɶɤɨ, Ƚ.Ƚ.ɒɦɚɬɤɨɜ. – Ⱦɧɟɩɪɨɩɟɬɪɨɜɫɤ : ȺɊɌ-ɉɊȿɋɋ, 2004. – 148 ɫ.
18. Ɏɭɫ ɋ.ȼ.Ⱥɧɚɥɢɡ ɫɬɪɭɤɬɭɪɵ ɩɢɬɚɧɢɹ ɱɟɥɨɜɟɤɚ ɤɚɤ ɨɫɧɨɜɚ ɩɪɨɮɢɥɚɤɬɢɤɢ ɚɥɢɦɟɧɬɚɪɧɵɯ ɡɚɛɨɥɟɜɚɧɢɣ / ɋ.ȼ.Ɏɭɫ, ɋ.Ⱥ. Ʌɟɫɧɢɤ, ȿ.Ʉ. Ʉɢɪɢɥɟɧɤɨ // ɀɭɪɧɚɥ ɩɪɚɤɬɢɱɧɨɝɨ ɥɿɤɚɪɹ. – 2006. – ʋ 4. – ɋ. 16–20.
19. Hendryx M. Relations between health indicators and residential proximity to coal mining in West Virginia / M. Hendryx, M.M. Ahern // Am. J. Public. Health. – 2008. – Vol. 98. – P. 669–671.
20. Valko M. Metals, toxicity and oxidative stress / M. Valko, H. Morris, M. Cronin // Current Medicinal Chemistry. – 2005. – Vol. 12, N 10. – P. 1161–1208.
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