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Evolution of Proanthocyanidins During Grape Maturation, Winemaking, and Aging Process of Red Wines

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RED WINE TECHNOLOGY

Edited by

A

NTONIO

M

ORATA

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Academic Press is an imprint of Elsevier

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Cover Pictures: Courtesy of Rafael Cuerda Garcı´a-Junceda, Winemaker Typeset by MPS Limited, Chennai, India

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Contents

List of Contributors

ix

Prologue

xi

1. Grape Maturity and Selection: Automatic

Grape Selection

1

SUSANA RI´O SEGADE, SIMONE GIACOSA, VINCENZO GERBI AND LUCA ROLLE

1.1 Physicochemical Characteristics of Enological

Interest 1

1.2 Vineyard Approaches to Grape Selection and Harvest

Date Determination 3

1.3 Grape Selection in Winery 9

References 13

2. Acidification and pH Control in

Red Wines

17

PIERGIORGIO COMUZZO AND FRANCO BATTISTUTTA

2.1 Importance of Acidic Fraction and pH Control

in Red Wines 17

2.2 Main Organic Acids in Must and Wine 17 2.3 Total Acidity and Wine pH 19 2.4 AcidBase Equilibrium and Wine Buffer Capacity 22 2.5 Traditional Strategies for Chemical Acidification 23 2.6 Traditional Strategies for Chemical Deacidification 25 2.7 New Technologies for pH Control 27 2.8 Laboratory Techniques for Measuring pH and Acidic

Fraction 30

Acknowledgments 32

References 32

3. Maceration and Fermentation: New

Technologies to Increase Extraction

35

ANTONIO MORATA, CARMEN GONZA´ LEZ, WENDU TESFAYE, IRIS LOIRA AND JOSE A. SUA´ REZ-LEPE

3.1 Introduction 35

3.2 Tank Design for Red Winemaking 35 3.3 Vessel Materials in Red Winemaking 36 3.4 Kinetics of Extraction: The Effect of Temperature 38 3.5 Mechanical Processes During Maceration 40 3.6 New Extraction Technologies 44

3.7 Conclusions 47

References 48

4. Use of Non-Saccharomyces Yeasts in Red

Winemaking

51

MAURIZIO CIANI AND FRANCESCA COMITINI

4.1 Introduction 51

4.2 Yeast Ecology of Grape Berry 51 4.3 Controlled Fermentation: The Role of Saccharomyces

Cerevisiae 55

4.4 Non-Saccharomyces Yeasts Features in Red Wine 56

References 64

5. Yeast Biotechnology for Red Winemaking

69

KARINA MEDINA, VALENTINA MARTIN, EDUARDO BOIDO AND FRANCISCO CARRAU

5.1 Introduction 69

5.2 Yeast Diversity in Red Grapes and Musts 70 5.3 Influence of Red Wine Technology on Saccharomyces

Strains 71

5.4 Saccharomyces Cerevisiae and Flavor Compounds 74 5.5 Practical Red Winemaking and Yeast Performance 76

Acknowledgments 80

References 80

Further Reading 83

6. Malolactic Fermentation

85

IRENE GIL-SA´ NCHEZ, BEGON˜A BARTOLOME´ SUA´LDEA AND M. VICTORIA MORENO-ARRIBAS

6.1 Introduction 85

6.2 Lactic Acid Bacteria in Winemaking 85 6.3 Factors Impacting LAB at Winery 87 6.4 Technological Strategies for Managing the MLF

Performance 88

6.5 Impact of MLF on Wine Organoleptic Properties 89 6.6 Production of Off-Flavors by Lactic Acid Bacteria 91 6.7 Implications of LAB and MLF in Wine Safety 93

6.8 Conclusion 94

Acknowledgments 95

References 95

7. Yeast-Bacteria Coinoculation

99

ISABEL PARDO AND SERGI FERRER

7.1 Introduction 99

7.2 Objectives 101

7.3 Interactions Between Wine Microorganisms 107

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Acknowledgments 108

References 108

8. Molecular Tools to Analyze Microbial

Populations in Red Wines

115

KAROLA BO¨ HME, JORGE BARROS-VELA´ZQUEZ AND PILAR CALO-MATA

8.1 Introduction 115

8.2 Classical and Phenotypic Methods 116

8.3 DNA-Based Methods 116

8.4 Matrix-Assisted Laser Desorption/IonizationTime

of Flight Mass Spectrometry 119 8.5 Microbial Diversity Assessment Through Enzymes

Detection 119

8.6 Culture-Dependent Versus Culture-Independent

Methods 119

8.7 Conclusions 120

References 120

Further Reading 123

9. Barrel Aging; Types of Wood

125

FERNANDO ZAMORA

9.1 Brief Historical Introduction 125 9.2 The Main Tree Species Used in Cooperage 125 9.3 The Main Forests Providing Wood For Cooperage 126 9.4 The Concept of Wood Grain in Cooperage 126 9.5 Obtaining the Staves: Hand Splitting and Sawing 127 9.6 Drying Systems: Natural Seasoning and

Artificial Drying 129

9.7 Assembly and Toasting of the Barrel 129 9.8 Types of Barrels and Barrel Parts 130 9.9 What Happens to a Wine During Barrel Aging 131 9.10 Volatile Substances Released by Oak Wood During

Barrel Aging 132

9.11 Phenolic Compounds Released by Oak Wood During

Barrel Aging 134

9.12 Oxygen Permeability of Oak Wood 136 9.13 Influence of Wood Grain 136 9.14 Influence of Botanical and Geographic Origin 137 9.15 Influence of Natural Seasoning and Artificial Drying 138 9.16 Influence of Toasting Level 139 9.17 Influence of the Repeated Use of Barrels 141 9.18 Barrel Aging Process 143

Acknowledgments 144

References 144

Further Reading 147

10. Emerging Technologies for Aging Wines:

Use of Chips and Micro-Oxygenation

149

ENCARNA GO´ MEZ-PLAZA AND ANA B. BAUTISTA-ORTI´N

10.1 Why Aging Wines in Barrels? 149 10.2 The Micro-Oxygenation Technique 150 10.3 Positive Factors of Using Micro-Oxygenation 151 10.4 The Application of the MOX Technique 152 10.5 The Use of Oak Chips 153

10.6 When and How Use Them 153 10.7 Effect of Adding Oak Chips on Wine Characteristics 153 10.8 Comparing the Effect of Chips or MOX With Aging

Wine in Barrels 155

10.9 The Combined Used of MOX1 Chips 156 10.10 Innovations in MOX and Chips Application 157

References 159

Further Reading 162

11. New Trends in Aging on Lees

163

ANTONIO MORATA, FELIPE PALOMERO, IRIS LOIRA AND JOSE A. SUA´ REZ-LEPE

11.1 Introduction 163

11.2 Use of Non-Saccharomyces Yeasts 166 11.3 Accelerated Aging on Lees 167

11.4 Lees Aromatization 171

11.5 Conclusions 174

References 174

Further Reading 176

12. Evolution of Proanthocyanidins During

Grape Maturation, Winemaking, and Aging

Process of Red Wines

177

ANTO´ NIO M. JORDA˜O AND JORGE M. RICARDO-DA-SILVA

12.1 Proanthocyanidins: Composition, Content,

and Evolution During Grape Maturation 177 12.2 Evolution of Proanthocyanidins During Fermentative

Maceration of Red Wines 183 12.3 Changes on Proanthocyanidins During Red Wine

Aging in Contact with Wood 185

12.4 Final Remarks 189

References 189

13. Wine Color Evolution and Stability

195

MARI´A TERESA ESCRIBANO-BAILO´ N, JULIA´N C. RIVAS-GONZALO AND IGNACIO GARCI´A-ESTE´VEZ

13.1 Introduction 195

13.2 Anthocyanin Stability 195

13.3 Copigmentation 198

13.4 Red Wine Color Evolution 199 13.5 Winemaking Practices for Stabilizing Red Wine Color 201

Acknowledgments 202

References 203

Further Reading 205

14. Polymeric Pigments in Red Wines

207

JOANA OLIVEIRA, VICTOR DE FREITAS AND NUNO MATEUS

Abbreviations 207

14.1 Introduction 207

14.2 Polymeric Pigments in Red Wines 209 14.3 Analysis of Polymeric Pigments 212 14.4 Stability in Solution and Influence in Red Wine Color 213

14.5 Conclusion 215

References 215

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15. Spoilage Yeasts in Red Wines

219

MANUEL MALFEITO-FERREIRA

15.1 Introduction 219

15.2 Description of the Main Yeast Genera/Species

Involved in Wine Spoilage 224

15.3 Yeast Monitoring 227

15.4 Control of Yeast Populations in Wines 230

15.5 Future Trends 233

References 233

16. Red Wine Clarification and Stabilization

237

AUDE VERNHET

16.1 Colloids and Colloidal Instabilities in Red Wines 237

16.2 Wine Clarification 240

16.3 Stabilization With Regards to the Crystallization

of Tartaric Salts 245

16.4 Microbiological Stabilization 248

16.5 Conclusion 249

References 249

17. Sensory Analysis of Red Wines for

Winemaking Purposes

253

PABLO OSSORIO AND PEDRO BALLESTEROS TORRES

17.1 Tasting of Grapes 253

17.2 Tasting in the Production of Red Wine 255 17.3 Tasting During Malolactic Fermentation 256

17.4 Conclusions 256

18. Management of Astringency in Red Wines

257

ALVARO PEN˜ A-NEIRA

18.1 Introduction 257

18.2 Astringency in Wines 258

18.3 Influence of Winemaking Technology in Wine

Astringency 261

18.4 Future Outlook 267

References 267

Further Reading 272

19. Aromatic Compounds in Red Varieties

273

DORIS RAUHUT AND FLORIAN KIENE

19.1 Introduction 273

19.2 Selection of Aromatic Compounds With Distinct

Impact 273

19.3 Conclusion 279

References 279

20. The Instrumental Analysis of Aroma-Active

Compounds for Explaining the Flavor of Red

Wines

283

LAURA CULLERE´, RICARDO LO´ PEZ AND VICENTE FERREIRA

20.1 Introduction 283

20.2 Analytes and an Analytical Classification 284 20.3 The Analysis of “Easy” Aroma Compounds 285 20.4 The Specific Analysis of Volatile Phenols 290 20.5 The Analysis of “Difficult” Aroma Compounds

in Red Wine 291

20.6 Final Considerations 300

References 301

21. SO

2

in Wines: Rational Use and Possible

Alternatives

309

SIMONE GIACOSA, SUSANA RI´O SEGADE, ENZO CAGNASSO, ALBERTO CAUDANA, LUCA ROLLE AND VINCENZO GERBI

21.1 Sulfur Dioxide: Use in the Winemaking Process

and Legal Limits 309

21.2 Different Forms to Use SO2 311

21.3 SO2Action Mechanisms 314

21.4 SO2Replacement Products for Red Wine Production 318

References 320

22. Red Wine Bottling and Packaging

323

MARK STROBL

22.1 Glass Bottles 323

22.2 Targets Today 323

22.3 Bottling Lines 324

22.4 Hazards in Bottling Red Wine 325

22.5 Closures 333

22.6 Preparing the Wine for Market 334

22.7 Packaging 336

22.8 Economy 337

22.9 Ecology 338

References 338

Further Reading 339

23. Red Winemaking in Cool Climates

341

BELINDA KEMP, KARINE PEDNEAULT, GARY PICKERING, KEVIN USHER AND JAMES WILLWERTH

23.1 Introduction 341

23.2 Cool Climate Grape Varieties in the Northern

and Southern Hemisphere 342 23.3 Chemical Composition of Grapes in Cool and

Warm Climates 342

23.4 Innovations in Cool Climate Winemaking 347 23.5 Making Wine From Red Interspecific Hybrid

and Fungus-Resistant Varieties 349 23.6 Yeast Assimilable Nitrogen 350 23.7 Tannins and Anthocyanin 350

References 353

24. Red Winemaking in Cold Regions With

Short Maturity Periods

357

MA TENGZHEN, KAI CHEN, HAO YAN, HAN SHUNYU AND BI YANG

24.1 Introduction 357

vii

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24.2 Wintering Adaptability and Cold Resistance of

Grape Vine 363

24.3 Influence of Low Temperature on Different Tissues

of Grape Vine 364

24.4 Influence of Low Temperature on Grape Cells 364 24.5 The Reasons for Freeze Damage 365

24.6 Maturity Analysis 365

24.7 Anthocyanin Accumulation by Viticulture Process 366

24.8 Winemaking Technology 367 24.9 Final Comments 370 References 370 Further Reading 372

Author Index

373

Subject Index

383

viii

CONTENTS

Referências

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