Interaction of [(VO)-O-IV(acac)(2)] with Human Serum Transferrin and Albumin
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![Figure 4. Absorption spectra of solutions of [V IV O(acac) 2 ] added to solutions of (A) imidazole (Im), and (B) pyrazole (Pz) containing a 40 mm carbonate buffer.](https://thumb-eu.123doks.com/thumbv2/123dok_br/18725211.919135/4.892.104.797.842.1063/figure-absorption-solutions-solutions-imidazole-pyrazole-containing-carbonate.webp)
![Table 1. Summary of assignments in ESI-MS experiments with solutions of [V IV O(acac) 2 ] upon addition to solutions of several potential monodentate ligands](https://thumb-eu.123doks.com/thumbv2/123dok_br/18725211.919135/5.892.410.822.637.1050/summary-assignments-experiments-solutions-addition-solutions-potential-monodentate.webp)
![Figure 6. Superposition of pair distance distribution function for both ana- ana-lyzed samples—native apoHTF (black) and apoHTF-[V IV O(acac) 2 ] (reddish)—](https://thumb-eu.123doks.com/thumbv2/123dok_br/18725211.919135/7.892.470.809.231.585/figure-superposition-distance-distribution-function-samples-native-reddish.webp)
![Figure 8. High field range of the 1 st derivative EPR spectra of solutions of [V IV O(acac) 2 ] (black), or [V IV O(acac) 2 ] and apoHTF with 2:1 molar ratio (blue) and 4:1 molar ratio (red), recorded at 77 K](https://thumb-eu.123doks.com/thumbv2/123dok_br/18725211.919135/10.892.100.412.101.447/figure-high-field-derivative-spectra-solutions-apohtf-recorded.webp)
![Table 4. Stern–Volmer constant (K SV ), R 2 (from SV plot), binding constant (K BC ), number of binding sites on the protein (n) and R 2 (from K BC fitting) for the interaction of [V IV O(acac) 2 ] with HTF and HSA (see below).](https://thumb-eu.123doks.com/thumbv2/123dok_br/18725211.919135/14.892.77.431.738.1016/volmer-constant-binding-constant-binding-protein-fitting-interaction.webp)
![Figure 17. Fluorescence emission spectra measured for a solution of HSA and upon adding [V IV O(acac) 2 ]](https://thumb-eu.123doks.com/thumbv2/123dok_br/18725211.919135/16.892.91.421.90.353/figure-fluorescence-emission-spectra-measured-solution-hsa-adding.webp)
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