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J. Braz. Chem. Soc. vol.23 número3

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Academic year: 2018

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Figure 1. First scans of cyclic voltammograms of aluminium polarized  in 0.1 mol L -1  H 3 PO 4  (- - -) and in {0.1 mol L -1  H 3 PO 4  + 0.5 mol L -1  Py}
Figure 4 shows the open circuit potential against  time for four samples of aluminium coated with PPy in  3% NaCl aqueous medium: PPy-coated Al with a thickness  of 14, 28, 43 and 57 µm, signed as PPy 14µm , PPy 28µm ,  PPy 43µm  and PPy 57µm  /Al, respect
Figure 5. Scheme of the proposed protective mechanism of PPy coating  on aluminium in 3% NaCl solution.
Table 3. Evolution of the Al 3+  concentration in solution with the applied  current density between 0.1 and 10 mA cm -2  during 5 min in 3% NaCl  solution
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