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INEGJ-lnstituto de Engcnharia Mct:anic.:a c Gcstfio Industrial Rua Dr. Robcno Frins, 4200-465 Porto. Portugal Tcl:+351 2::?. 957 87 10; Email: [email protected]

www.incgi.up.pl

J11/y, 2009

ISBN: 978-972-8826-22-2 Legal D.N: 295639/09

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~

2009

INTEGR~TY, REL~ABILITY

ANID

FA! lURE

(CHALLENGES AND OPPORTUN

I

TIES)

Editors

}.F. Sill'a Games and Shaker A. Meguid

Edi~oes

I

NEGI

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ORGANIZATION ·

Faculty of Engineering, University of Porto

LOCAL ORGANIZING COMMITTEE J.F. Silva Gomc.s :mu Shaker A. Mcguid. (Co-Ciwirs)

Carlos C. Antonio. Jose M. Cimc, Rui M. Gucdcs. Paulo G. Piloto

M. Tcrcsa Rcstivo, Aarash Snna. Mario A.P. Vaz

INTERNATIONAL SCIENTIFIC COMMITTEE

Clito F. Afunso. Porwgnl: Anabcla C. Alves, Porlltgal; C.C. Antt'mio, Pomt,~nl; Rui C. Barros. Portugal; K.J. Batht:. USA: R. de Borst.Nether/amls; Pcdro Camanhn. Portugal; Curios Cardeir..t, Portugal; Cmarina Castro.

Porwgal: J.L. Chcnot. Frtmc<•: Luistt Cosw. Ponugal: Alvaro Cunha. Porwgal: S. Datta. USA: J. Rodrigucs Dias, Portu.~al; Josl! L. Estevcs. Porlllgal: A.J.M. Fcrrcira. Porwgal; Elza Fonsec:J. Portugal; Hossam A. Gabbar, Cwwda; S.V. Hnu. Camula; I. Hutchings.Uii: N. Joncs. Uli: Rcnuto N. Jorgc. Porwga/; David

Kcnncdy. lrl!land: H.W. Klcin. Gl'nmmy: M. Langscth. Nonmy; T. Laurscn.USA; Cclina P. Lcao. Portugal; R.

Lcwis. Uli: D.G. Lee. lior<•a: Nuno M:1ia, Portugal: A. Mal. USA: A.T. Marques. Portugal; J. Couto Marques. Portugal; Alhcno Mt:da. lmly; S. A. Mcguid. Ct11wda: R.E. Miller, Cmuula; G. Mimmi. Italy: Rosa M. Miranda, l'ortugttl: Y. Miyano. Japmr; Amiram Moshaiov. !.l'ral'l; Marcclo F. Mouru. Porlllgal: Curios N:Jv:trro. Spain; C. P;~palcllcre. Italy: Puulo Piloto. Portugal; J.N. f>ircs. l'orwgal: J.N. Rcddy. USA; M.T. Rcstivo. Portugal; Nuno

f'. Rilo. Portugal; J. Dias Rodrigucs. Portugal; C.Q. Ru. Camula: Arlimlo J. Silva. Portugal; Lucas F. M. Silva.

Pnrtugttl; J.F. Sitva Gomcs, Portugal: C.A. Sciummarclla, lwly: Jorgc H.O. Se:Jbra. Portufla/; M. Gamciru Sil\'a

Portugttl: S. Carmo Silva Pm1ugal: C. M. Snares, Portugal; Afzal Sulcman. Portugal: Joliu M.R.S. Ta\'arcs.

Portllflttl: M.J . Tnorcn. Nt•tlterlmrds; K.T. Tan. Sirl,~llpore; Mario P. Vaz, Portugal; Gcorgc Wcng. USA: Y.C.

Yoon. Singapore; Z. Zlmng. Clti1111.

SYMPOSIA COORDINATORS

Clitn Afonso (U. l'orto, Portugal). Carlos C. Antonio (U. Porto, Prmugal). Tiago Darbosa (IPB, Portugal). Rui

C. Barros (U. Porto. Portugal). Pcdro C:1manho (U; l'rmo. Portugal). J. Rcis C:~mpus (U. Porto, Porlttgcr/J. M. Braz Ccsar (IP/J. Pmmga/1. J. Rodrigucs Dias (U. £1'1/rct, Portugal). Jose S. Est eves ( U. Parw. Portugal). Paulo Fcrnandcs (/ST. Portl'!!lll). Antonio Fcrrcira tU. Pono, Portugal). E17.a Fonscca (IPIJ, PonrrgaiJ. Mihail Fontul

(!ST. l'ortrtgal. Hossam Gahbar (UOIT. Cwuu/a). J.F. Silva Gomcs (U. Porto. Portuga/), Rcnatu N. Jorgc (U. Pnrto, Portugal), Jackk Li (CUNI. USt\J. F. Jorgc Lino (U. Porto, Portugal). Ramiro Martins (INEGI.

Portugal). Albcrto Mcda (U. Uomt•, lw/y), Shaker A. Mcguid ((!. 1immlrl. Ccmada). Rosa Miranda ( FCTIUNI ..

Porw~:al). Paulo Piloto {IP/1, Ponuga/J. M. Tcrcsa Rcstivo (U. l'orw. Portugal), Nur10 Rilo ( U. Coimbm). J. Dias Rodrigucs ( U. Porto, Portugal), C:Jrla Roquc ( U. Porto, Pnrltlga/), Jorgc Sc:J!Jra ( U. Porto. Portugal),

Arlindo Silva (IS1; Portugal). Lucas F. Sih·a (U. /'orto. PortugalJ. Aarash Son;~ ( U. Toromo. Cmuula), Joi:io M. Ta\'arc~ (U. Pono. PorJttga/). Ccsar Vasqucs (INEGI. Pm1uga/J. M:irio A.P. Vu7. (U. Porta. Portugal). Zhcng

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SYMPOSIUM

STRUCTURAL SAFETY

Coordinatt'd by

Paulo A.G. Piloto11•1 and Alberto Meda1'•1

1

/nl'lirwo Poliu!cnico de Bragilll{'a. Portugal l Unil'ersitY of Home, lw/y

In Association with

IRF'2009

3rd International Conference on Integrity, Reliability and Failure

Porta, Portugal

20-24 July 2009

Editors J.F. Silvu Gumes

Faculty of EIIMillt'erin~ U.Porto, Portugal

Shuker A. Meguid MADL

U. Toronw, Canada

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Porw!Portugal, 20-2-1 July 2009

Introduction to Symposium on

Structural Safety

Safe design is a design process that eliminates hazards, or minimizes potential risks, by

involving decision makers and considering the life cycle of structures and materials. Safe design approach will generate a well-infonncd design option that should eliminate these potential problems to those who makes the product and to those who use it.

Structural safety in design will cover the design aspects of safe structures and components,

using different materials. Advances in standards and regulations should permanently ensure

safety with the best practices and methods. Advanced analysis methods should be

permanently improved and used to prevent such potential risk in structures and materials.

Designers should guarantee structural integrity and reliability.

The following communications will present different aspects in Damage Analysis and

Assessment, Fire Safety Engineering, Life Cycle Analysis, Natural and Man-Made Hazards,

Performance-Based Design Methods, Prescribed Design Methods, Computational Methods

and Simplified Methods for Structural Safety. Ptmlo Piloto

lnstituto Pnlitecnicn de Bragan(:a Alberlo Meda

University of Rome "Tor Vergma"

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IRF'2009-lmegrity, Rdiabilily and Failure

REF: S2003_AO.t7 I

EFFICIENCY EVALUATION

OF INTUMESCENT COATINGS USED

FOR FIRE

PROTECTION: COMPARISON BETWEEN NUl\tiERICAL

METHOD AND

EXPERIMENTAL

RESULTS

Luis J\1.1{, Mcsqulln"'', l'aulo A.G. l'iloto1, anti Mario A.P. Vo1.! 1

Poly1cdmic lnslilutc of Bmgunt,:OI, Pnnugnl

~F;1culty of Engineering. Univcr.;ity of Ponu. Pnnugal

'''Email: [email protected]

SYNOPSIS

An experimental study to assess the perfonnance of water-based intumescent paints. used as a

passive fire protection material. is presenled. The specimens are steel plates coated with two

different paints, three dry film thicknesses and tested with two different radiant heat fluxes in a cone calorimeter. The efficiency of this protection is attained regarding the substrate temperature evolution. A comparison between these experimental results and the ones

obtained from a numerical model is presented. The numerical model considers the coating

decomposition, and models the protection by two layers. the reacted and the unreacted layer

(Mesquita et al. 2009). INTRODUCTION

Thin film intumescent coatings are mostly used in the civil construction industry to increase the fire resistance requirements prescribed by the structural fire design codes. They are

applied essentially to structural elements with inadequate fire behaviour, like the case of steel

and aluminium structures. An intumescent coating when submitted to fire starts to bubble and

swells to form a carbonaceous, porous, low-density char, reducing the heat trnnsfer to

underlying virgin material layer and therefore to the substrate.

This work presents an experimental study to assess the performance of water-based

intumescent paints used as a passive fire protection material. These tests were perfonned in a

cone calorimeter (ISO, 2002), in squared steel plates, with 4 and 6 [mm] thick, coated with

two different paints (A and B), three dry film thicknesses (0.5, 1.5 and 2.5 [mm]) and

considering two different radiant heat fluxes (35 and 75 [kWm'2]). Temperatures arc measured by means of four them10couples, type k, welded at the plate in the heating side and at the opposite side, at two different positions. Between the steel plate and the sample older

two silicate plates were used to put the specimen in place and also a thermocouple was

introduced inside to measure their temperature variation. During tests, among other quantities,

steel temperature, intumescence mass loss and thickness variation were measured.

A numerical model is also presented to study the intumescence behaviour. The paint thennal

decomposition numerical model is based on the Arrhenius equation, to simulate the chemical

reaction decomposition. The moving boundary and the free boundary locations, the depth of the carbonaceous and virgin coating layers (L(t), s(t)) are determined as part of the problem.

The energy equation for the overall conservation of energy within the intumescence zone can

be obtained by combining the energy equation for the gases with that of the solid char

material.

The solution method was implemented in a Matlab routine using the Method Of Lines (MOL)

(Wouwer. 2004), and the integrator ode 15s to solve the set of ordinary differential equations.

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Ponu/Pcmugul, 20-24 July 2009

The temperature field is determined by tlf steel and virgin energy equations. When the front reaches t11e pyrolysis temperature, equal ;o 250 [0

c], starts to decompose and to move. Then the moving front rate is determined ano the intumescence sturts. The position of the free boundary is set equal to the experimental results ami the intumescence temperature field is determined. In each time step the virgin and char layers are remeshed.

RESULTS

Measured values from the thermocouples welded on the bottom of the plate are very close to the temperatures at the top, as presented in Fig. I. The numerical results follow reasonably

well the experimental values, us presented in Fig. 2. The results show that both the determined

steel temperatures and the moving front are strongly dependent on the activation energy that defines the amount of mass loss of virgin paint.

Fig. I S1ecl ;md calcium silicmc 1cmpcrmures for 4

[mm) specimens coalcd wilh a DFf of coaling A

equal 10 1.5 [mm), ICSicd wilh heal fluxcs of 35 and

75fk\Vm'~l.

CONCLUSIONS

••• IJ~11

""'

,.

_,,,

Fig. 2 Comparison of measured and compUicd slccl

1cmpcrmures, £

0

=

1251\Jmot- 1.

This paper has presented a set of experimental tests conducted in a cone calorimeter to assess

the intumescent coating behaviour when used in fire protection. The intumescence depends on

the initial dry thickness and on the incident heat tlux. A numerical model is applied to

detem1ine the steel temperature considering the intumescence measured in the experimental

tests. The results show that temperature variation is strongly dependent on tlle activation

energy.

REFERENCES

[ 1) ISO 5660-1:2002, Reaction-to-fire tests - Heat release, smoke production and mass loss rate. Pan I: Heat release rate (cone calorimeter method), International Organization for

Standardization, 2002.

[2] Mesquita, L.M.R.; Piloto, P.A.G.; Vaz, M.A.P.; Pinto, T.; "Decomposition of intumescent coatings: comparison between numerical method and experimental results", Application of Structural Fire Design, ISBN: 978-80-01-04266-3, pp. 140-145, Prague, Czech Republic, 19-20 February 2009.

[3] Wouwer A.Y, Saucez P., and W. E. Schiesser, "Simulation of Distributed Parameter

Systems Using a Matlab- Based Method of Lines Toolbox: Chemical Engineering

Applications", lnd. Eng. Chem. Res. 2004, 43, 3469-3477.

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