Detecção fotoeletroanalítica de adrenalina baseada em DNA e nanopartículas de TiO2 sensibilizadas com Bis (Etilenoditio) tetratiofulvaleno explorando luz de led

Texto

(1) . . . 234567849 96 6967

(2) 9 7 3 637 96434 86 8663

(3) 4 7 7 9687 92 624 687 9 6244 . 4 228 94 88 3 8 . !"#$""%&"'('%)*'##'&('%*('#+',''# -#('##('(".'&)/%',##0"1#,(,*+*%*2'',#"-# +*,3*%("**"4&'*"$/%5'%("#6.%"&'("#%/2## %#. . . 789:;<=>7?7>@A97A BCD8>8<:;>E9<F>E . 8G>

(4) HIEJ KLMN.

(5) 1234564858916 34994 169

(6)

(7)

(8)

(9)

(10)

(11)

(12).

(13)

(14)

(15)

(16)

(17)

(18)

(19)

(20)

(21)

(22) !

(23) "

(24)

(25) # $%

(26) &

(27) "

(28)

(29)

(30).

(31)

(32)

(33).

(34)

(35) ''()*+,-.

(36) +/)('(0*+1+

(37) +.

(38) ).2)+3+

(39) 1(

(40) 4'56)+17+,-.

(41) (3

(42) 8793 :+

(43) #6873$

(44) 1+

(45) 0;()'1+1(

(46) (1()+<

(47) 1.

(48) +)+0=-.

(49) :.3.

(50) )(>7'*.

(51) /+)+

(52) +

(53) .?*(0,-.

(54) 1.

(55) *9*7<.

(56) 1(

(57) ('*)(

(58) (3

(59) 8793 :+@

(60)

(61)

(62) A)(+

(63) 1(

(64) .0:(0*)+,-.B

(65) 8793 :+

(66) 0+<9*:+

(67) )(0*+1.)B

(68) ).C@

(69) )@

(70) <D;.

(71) +0*.'

(72) +3.'

(73)

(74)

(75)

(76)

(77)

(78). -.

(79) 79'

(80) E

(81)

(82) !FGH

(83).

(84) 123426728932

(85) 2. !. " "2 1#2$%982!. " "2&'2#()82!.

(86) 12314567859

(87) . !"# !$#%& '())*"+,%""-%.!# %#%(!"/## #%!(& 0'()1)123+,"45""6% %#7%$".#%%%(#"8 %%5%#"%(#"''9:& ;8$,",%<%=%>"% ,%#.#%#%"%$?@%%/ #.(!8(%%"6%# %.%(#"$8 %-A& $!8(#"B %/<%# %/.4"%C%#"8D# ##%("%%//7& ( "(%!8 #%!-##%." %#%+" %/& $E$7%,83%",. 4-FC4"6%%%%F'"" (#(& $4!A,%C8 %"-#G4!,H"#%/7"% #%(%5.#"%"%.#%(5(% $& $,IJK"#L%#%% !"/#%4!A%%!8 !#.7%$& 0M%*"C%/." %( #%#"5.&.

(88) 12352678973 2

(89) 2

(90) 7 3

(91) 276 73 368327

(92) 76 3776289

(93)

(94) 9892

(95) 27 737827892 8977696229!

(96) 2 737827892 2

(97) 7378979

(98) "2# 123

(99) 23 727892$1 %&'$( )*)+,+-,*./0#1,..)0-,*./.# )*+/2*-,*.+)#1,/))3-,*.//'41 %51 67(%5**.++-./#8(9:%6&1; **0,3-./729839992(628 7$<867=76822 7>2896 1/+)20-,*.13'72?28867

(100) 272362867 2372

(101) 8 7893

(102) 2 737827892 73979

(103) "2@ .

(104) 123456. 9

(105)

(106)

(107)

(108)

(109)

(110)

(111)

(112)

(113) !"

(114) #

(115) $

(116) %

(117) &'("

(118) )

(119)

(120) "

(121)

(122) *+&,&&-"#

(123)

(124) ./

(125)

(126) 0

(127)

(128) #

(129) 1'

(130) #$

(131)

(132)

(133) *+&,&&-2 !2&'(23&'

(134)

(135)

(136)

(137)

(138)

(139) #

(140) ./

(141)

(142) )4+"

(143) #./ #

(144)

(145)

(146) #$ 15 .6

(147) )

(148) *+&,&&-2 !2&'(23&'

(149)

(150)

(151)

(152) #

(153)

(154) 78 4,79:;:<=>><?@AB<C,7DA@<E@:<FGHFIJIBIK:KG<KG<LM=<HN<C<?@AB,7

(155)

(156)

(157)

(158)

(159) ./

(160) 7 4,7#

(161) 1'

(162)

(163)

(164) O

(165)

(166)

(167)

(168) #

(169)

(170) #./

(171) #

(172)

(173)

(174) # $

(175) P1'

(176) *+&, &&-2 !2&'(23&'#

(177)

(178)

(179)

(180)

(181)

(182) #

(183) ./

(184)

(185) QR

(186) 78RS1 TUVUWXUYZ[\UW]^

(187)

(188)

(189)

(190) O

(191)

(192) )4+"

(193)

(194)

(195) 1 .

(196) 12345164. 9

(197)

(198)

(199)

(200)

(201)

(202)

(203)

(204) 9! "

(205) #$%!

(206) &

(207) !

(208) '()#*##+!'

(209) "

(210)

(211) '

(212)

(213) " ,#

(214)

(215)

(216)

(217) "

(218)

(219)

(220) " ()#*##+- 9-#$%-.#$

(221) /

(222)

(223) '

(224) / " /

(225) 0)!

(226)

(227) "

(228)

(229)

(230) "

(231)

(232) '

(233) "

(234) " ,1

(235) "&

(236)

(237) ()#* ##+- 9-#$%-.#$

(238)

(239)

(240) /'

(241) "23"

(242) 0*2

(243) 233 456789*2:;<=8>8?@A?;<;B;<C86D8EFG8AH8984567*2"

(244) '

(245)

(246) '2"

(247) 0*2'

(248) ,#

(249)

(250)

(251) "

(252)

(253) /

(254)

(255)

(256)

(257) "

(258)

(259)

(260)

(261)

(262)

(263)

(264) , # ()#*##+- 9-#$%-.#$

(265)

(266)

(267) "

(268) '.

(269) "

(270) IJ23JK, LMNOPQRST

(271)

(272)

(273) "

(274) / " /

(275) 0)!

(276)

(277) , .

(278) 123457859 8 254

(279) 53832 153 5 57 5 545546 594 9874944 9 69 68 6 7O5 7 7V Z[97O5 7336[. e9695fg 9. 861 873 8mn. . !"#$%&'()*+,'-*.+/)*-'0*'123 7""8"" :" ;$""3"""<=> ?@;"":AB ;C=!@$D'EFG*&)'E+HIEF3 C":7"$D'GE&.-+JK.*&-'F.3 L""CM$D2*K)*+N'K&I((.&-23 PQRB=$S.'T2-)U'EG*K.)*+%*)F3 Q"< L""W=Q<$S)XX.-.E&)IK+YGK0.+ N'K&I((.&-23 Q\=]^$F'GUK.+0&-IEF.F_S`%3 C^=aaBbC"$S2.+ c.E0)&)d.F+c'KI-+D.KK03 W^":= 7"h==i 7"7jQ>$JE.-k2+S)01.-0)l.+ c1.*&-'0*'123 W"B.

(280) 123 ./ .34556 61431M V4W Y1Z13 YdMd 2m 25d s4tdZu s1t s{5W|} sdt s3/. . sMd |t Z1W Z|M5 t. . . 56789

(281) 69

(282) 7 8 789 58

(283) 9 !"#$%&"'($)%*'+',- 50

(284) 12

(285) 789:;9<=>?@A;@8B=CDE8DF=BG?H;IJ=DK18L 8 N 9

(286) 69

(287) 7 58 O 98P 8 9

(288) 5 66Q

(289) 8 R7

(290) S#(%"#++#)%*$))#)T%)%U#+',- X 19

(291) 6 [9

(292) \1]^1\1_

(293) L 8 -7 78 ` 1a1 b8

(294) 6cO 9

(295) e f N

(296) 89 e97

(297) 8 6g 58 h i#T!+% jk'#(%U k$%jl#$- c 28 8_

(298) &)n$(- oL

(299) 856 _

(300) 8p

(301) &)(#k"%q#)%jr#(- v82

(302) h

(303) wx _

(304) L c8 x

(305)

(306) 5 66

(307) 8v`y#T!%"##)T%z#(- ~8 9

(308) 8 88

(309) 68v

(310) v 88x8 89Q

(311) y#"#%n%z#)- P

(312) 8 8 P 8 v 8 y#)$% *'% $"",- e f N

(313) 89 x86

(314) 97

(315) 8 6 L58 h y +%) k'#(%U k$%jl#$- 8

(316) 87

(317)

(318) 8689 h

(319)

(320) 88

(321) 9! !"#+,- 8

(322) 18 1 6c8 68

(323)

(324) 6 9

(325) 6k$)k"%z +-.

(326) 123. 56789

(327) 86

(328) 89 !"# $%&'(#)&*+ ,- .

(329) 899/081 76 2*3**)&*4#*&'5*+ 678 /9 9:98;6 9 <-3 5678979:6 .

(330) 8= 67 > 888 ?&))%)@4#*&') $%&'"&'A!+ <-23 5678979:6 .

(331) 89BC;67 > 888 ?&))%)@ 4#*&'&D*E%&#$%&'"&'A!+ <F, /9 G 76 H

(332) ;9 I:80C76?3&*J#"E') 2*"'))&*+ KKLMNO PQR06 6;:

(333) "%)@#*")5*5STUV+ <WX >9

(334) ;86 Y 8 ?Z* [\* ]'#EE*!+ ^2N- _8 76 96

(335) 9 ^2N1 _8 76 9B6 96; 9 _;:9b6 9

(336) c89 `a ^-3 5678979:6 .

(337) 8= 67 _8 ;6d9e)"E%""%') 4#*&')$%&'"&'A!+ ^^f _8 690

(338) b

(339) 9 gX h

(340) 8 b69

(341) Xi j >

(342) 1 76 ]#*)&*k)5+ W- .

(343) 899_8

(344) l9['m%)@4#*&'5*+ nF< .:78979:6 o99

(345) c89 .p76 9:98/ 69qrsS !JD''*#*&')?A*&'"&'A!+ n,M P608 d9/ 69qrsS!T%33&%')+ .

(346) 123457889 5

(347) 83 83 . 7345677478 9. 4A6B5CD73 E . O464C5376773C53 P. 15A57j . . % 01 !" #$&'()*)+,-$,./- (2. :; #$()%*)+<><= !?"@2 F(#$GN>HIJKLM@ QRSTSUSVVWXTW Y Z[\ ] ^_ ` Zabc ] dbc_ efghi klmnonpnqrs t uvwsuvxyz{.

(348) 123457892

(349) 53. 9 !"#$% & !" %'(!( )( !*"$%+++++++++,-./0 9/ !"#$% & 1 & )%+++++++++++++++++,-./2 934!" $(!$5 & 1 & )% %6&$%+++++++++++++++++,-./7 98 !"#$% & *5$ &$% & #" $(& " 9& & 1$ ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++,-.3 9:; *5( & <"$ " "$= "$%&! $(+++++++++++++++++,-.3/ 904!" $(!$5 & "1" & %'(!( )( !*"$% ($> & "&$& ""'$% +++++++++++++++++++++++++++++++++++++++++++++++++++++++++,-.87 92?$1" & @A!$ 9$& B4?CDCC<E?@FEC$;GEHC; " (! ! I=J "( KDJ & @GL;M 9 %&$N & %$( & %$%!$ 9 O%*%!( P !Q%$ O%*%!( " 5"(RP & $(!"$ 5$ & (!> K4? +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++,-.:8 9ST#)$% & UDL%RVA OWDG XY 4P 9$& C$;GEHC; O%*%!( " 5"(RP B4?CDCC<E?@FEC$;GEHC; O%*%!( P !" ) !Q%$ & JI VZ> +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++,-.:: 97[1!( & ) " )! & ) !Q%$ 9$& C$;GEHC; O%*%!( P B4?CDCC<E?@FEC$;GEHC; O%*%!( 5"(RP " \W] I=J "( KDJ #%$& %69$% I=IG "( KDJ +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++,-.:S .

(350) 12345689

(351) !"#$" %&'( !"#$" %#'( !"#$" %)' $" %*'+ , !- .!/ - .012 -2 %3 4(5' & --. 6& .! !. .! 5(#7 8 9+ ::;<%0' ++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++=>3?@A 12345688 B0 - !. 12 . .C! .! +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++=>3?D8 1234568E $.0F! .012 -2 .! &55 G-. 6&+ - ! - .!/ - .012 -2 ( 3HI !

(352) J 5(& -. 6& 0- !. .! 5(#7 8 9+ ::;<%0' +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++=>3?DE 1234568K $.0F! 3 .012 J &55 G-. 6& .!+ - ! - .!/ - .012 -2 12 5(& -. 6& !. .! 5(#7 8 9+ ::;<%0' +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++=>3?DK 1234568L $.0F! !. .! &55 G-. 6& .!+ - ! - .!/ - .012 -2 5(& -. 6& 3 4(5 +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++=>3?D@ 1234568@ . B0C-! J! J !1M !-!/ .! - ! 9. 12 5(5& &55 G-. 6& %09 .C! ! !' +++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++=>3?DD 1234568D J! . B0C-! - .12 N 9O! 0JP! ! - -12 - J! .! J !1M !-!/ !. .! 5(* 8 9+ ::;<%0'+ 12 Q! ! !, &55 G-. 6& ++++++++++++++++++++++++++=>3?R9 .

(353) 12345784598153. 4

(354) ! "!#$ %! !. !# # %! ! !&$#$ !'"#$. ((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((()*+,-.. 4

(355) /0 $ 123 4!# ! #. 5 6 7 89 ((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((((()*+,:.

(356) 1234567 9

(357)

(358) 9 2 !"3# $7% #&56'7%. ()*)*)+,-./0/123+-+45677/./86123+9-+:-073;-7+<=>?/837 ()*)()+:-073;-7+@3A3-5-A;3B=>?/837C ()*)D)+E+F39-53+967+G60967+9-+H0-;I/6J ()*)K)+E+H.-/A3+96+@3A3-L8/A6123+06+M;607.-;N08/6+9-+H5OA;307 #P6%Q7R6ST67U54V6'"W X RY Z1CW X 9 S[#$6P7\#5"TCW X S[#$6P7%%]#'^V6'7%CW _ ` 1`a 1C _ 9 b26]"3# $7%##"U# $#%C _ c57'#!63# $7%d]#563# $"6%Ce K)()*)+f/?g-h6+93+H5-A;393+iMECe K)()()+4307A;=123+93+7-073;+GH,MjMM@k,lmkM/E(kiMEnJ _ X c5#]"57!#17T2op#%n K)D)*)+:35=1q-7+M6?g23n K)D)()+m9;-065/06+-+H7gO8/-7+i0A-;.-;-0A-7n _ _ c5#]"57#" 4T6%#!"%"37%$5"%!#256"n r 1 1 111nC. r 9 "5"'$#56s"oQ7 !" ]T"$"V753" V7$7#T#$57b2^36'" ]75 %]#'$57%'7]6"!# 3]#!t '6"T#$57b2^36'"u 1vnC.

(359) 1232567689 7

(360) 9 86

(361) 9 97 86

(362)

(363) 7 3. !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!"#. 12$2 9 %6&'6(

(364) )

(365) 96

(366) 79 9766 9 8 3* !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!+, 12-2

(367) ) .6 9 8

(368) 7 3* !!!!!!!!!!!!!!++ 1212) 86&'

(369)

(370) 79 9766 9 8 3* . 6

(371) 976

(372) 7 6.66!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!/0. 125 5234 !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!/5 62((75**2* 8(9*5!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!//. : :. :.

(373) . . 3456789 7 . .

(374) . 01. 346789

(375) !"#$ $%$!$&' ($)$#$ $!$$$&$*#$+, !-./$$0$"12!!$ $0$$+$$%-3$!!$+ $$$$4$15!!!' ' $,6$&/$/&7+&3 $$+&$$8$!9$%! !$#!:&$$;%9$ % 0$-.$!:<1 2$ !&!$$3$ !-3*$ $+&3$$$ $ &7&$$4$$$$4$ !!+&$$/!$ $!"$!9$4$ $* :/3$7$4$ /$9$4$=$* :1 !$! $/&7+$$%$ $=/3>!!?1 @ $$-37%!$,$-3 &7+$$3$7!%$ $&$!+!$3 $/ $$$/& $&7/ !/ $1$$& . !3ABC@;2+ $+$$!$$!$+ $*$D1 @$$$!$/+$!$+, $# $%$+ $$&,!$-3 !-3$/)$/)$#*+ $$-3,6$ $%,!-37+ -3 !$=C7E1.

(376) . 01. 3567895 95

(377) 79 5

(378) 898 7759 7 878568 5 96 5 7577895 8896 8 58 898 6 987 979 5

(379) 6887 8988997568 6 !"#8 9$8 97585 5

(380) 7 868586 85987 %78&5787 5 78' (9 5576$55 8785 98885 68 (9 )"3567895 95685

(381) 87 65557 76897567895 958 5 5&6589* 589 5 95+,8 ,7598758-.+/012" 3 59868 58 57 65688 79 55' 59 5&68567895 958 575 5

(382) 6875968 98788955 5 65688965 7 95 565 5755 5 898 65898' 898898 5655 898 8785659559 8 $9 568567895 95 5966 59 "3875875 9$8 68567895 959 6 5 7 9568896865 65688 96 865 8984".575855 68 788 598975& 568567895 958997565857568 7 95889$8 959 57 -5567899 :,71;" 385598 756 87586 5595 $ 5( 675575 6887 95&68898 7759 7689785' 5 68,889 957

(383) 6 7

(384) 7 9887

(385) 7 78756 9895 89* 77 7575 555757575 5 $' 65685 58 (9 5728 87788 5 577<8

(386) 68 87' $ 7!,7;" 3857688759689=8768

(387) 6595 $ ' 8( 67 57556887 95&68567895 9555 7 568 878685 56859589 8 856 986859 8988 6568687

(388) ,75589 889 68575687 5 *5& 8 57875&8 7 5&85 8 (9 568 7 5 589878 956 ' 5 56">895 7

(389) 7 8756 ,89* &5 5 8985 *56956887 95&68 567895 958 55 7 9588 6896' 8895 756 ,89*

(390) 9 5 58985 89$8 888$ 8575&5

(391) 6 7

(392) 7 7

(393)

(394) 89 5898 898 575968 ' 59 6568688575785786887 95&655755

(395) 6 8 8567!" +8889 6

(396) 68 87' $ 578895,85 8795 5 5 8 5755' 59 5&68567895 95 58*' 888

(397) 6&68 5 58$8 68 875&87857 658575&5.

(398) . 01. 3456768.

(399) 568 3 6 768 6 5 56 . 753 6 788 65 83886 3 6 768 8 868

(400) 56 368 8 5 3 6 5

(401) 6 7 8685

(402) 6 8 5 3

(403) 68 7

(404) 35 7 756 8 8

(405) 7 7 6 7 7 6 5 6 88 8 . 753 6 7. 7

(406) 3 3685 8 6

(407) 8!"#!$ % 76 3 85 68 7868568 656

(408) 56 368 5&3 376. 5

(409) 3 5 636 8853 8 65

(410) 3 5 8 8 8 63

(411) 7 7 7 7 666

(412) 568 5

(413) 68 7 8685

(414) 8.

(415) 6 5 6 7. 7

(416) 8 8 5 636 3.

(417) 5 5 63886 !'#(! )3 5368 8. 756 656

(418) 56 3 4 8 7 6 7 6566 5 6 5 7. 5 6 7 3 3 5

(419) 656 56 5 7 7& 7

(420) * 6

(421) 3 65. 63 7 7 6

(422) 563 45 +

(423) 43 7886 5 76 3 85 6 5 7 5 6 6 8853 7 756 86 7 5* 785 5 8 68 7868568 656

(424) 56 5

(425) 568 8 5 3 3

(426) 7

(427) 6 8

(428) , 76(!(( - 5 8 656 568 3 768 3 656

(429) 56 3 5 8 636 68 768 836 7568 5&3 5 76 7 588 56 6 78 6

(430) 3 56 7 8853 8 656 5

(431) 568 656

(432) 56 368 . 5 858 6 776 7 55/ 6. 5 8 0%1(2 4 3 768 3 8 3 768 3 8853 8 656

(433) 56 368 3 57 7

(434) 3 8 5 8 6363 567 7 476

(435) 7 7 6 856 85

(436) 7 7 5 6566686(( +

(437) 43 7886 6 %1(. 5 8 8 5 7 8 7

(438) & 63

(439) 68

(440) 768 568 6 35 8

(441) 8 7 8 5 7 3 8

(442) 6

(443) * 8 7 5

(444) 56 76# 53 3 5 5 . 5

(445) 456 8

(446) 8 7 36

(447) 4

(448) 8 76 76 8(( )3 6 5 57 6 %1( 8 5.

(449) 3 8 78 5 8 .

(450) 68 636 3 5

(451) 656 5

(452) 56

(453) 76 63 6 768 65 768 7 . 656 768

(454) 6 7 789:;<8=

(455) 76 3 56 6 7 >(( ? 7 63.

(456) 35 88 836 756 5 866 5 7 7 6

(457) 3 5 6 76

(458) 5 6

(459) 5 (> .85 63 88

(460) 56

(461) 6 7 789:;<8= 76 %1(

(462) 35 8 65

(463) .

(464) 6 6 36 656

(465) 56.

(466) 56 6 5 753 6 7 848 6

(467) 8 5 76 3 85 7 6 6 76 @? 67 7 88 8 848(A 88 8 576

(468) 3 8 85 54 8 5&3 876 6685 8 63 6 6B56 7 3

(469) 46 6 783 46 656

(470) 56 36 76 %1( 56 5 8 7 7 7. 866 6 76 8

(471) . 5 8 85 54 8 3 7 8 76 3 63.

(472) . 01. 345689 9

(473) 689

(474) 56 4

(475) 6

(476) 5 94

(477) 8

(478) 5 48489899 465

(479) 98984 9 4 46

(480) 6956

(481) 44 4

(482) 5 96 8 6644 9 6 846956

(483) 844 464 !46 4689

(484) 59

(485)

(486) 6

(487)

(488) 4

(489)

(490) 8

(491) 89"6 !4! 98

(492) 8968966969 458 454#98 96!9 4

(493) 4896954 95 489 8 6!46 464 499 4#3 46 5 584

(494) 5 48489

(495) 4

(496) 5 5

(497) 6$!43 946 458 496%!4 5

(498) 6& 9

(499)

(500) 549 959 46893 4'( )*+,-!45 46#.5 46 '/01230456738595/68,:;95 94 46 <95 48

(501) !96!9

(502) 8464894

(503) 5 96!

(504)

(505) 6956

(506) 484 4 9

(507) 4

(508) 954'=, 4 984

(509) 84899 456>?@ABC@DCE@FDGFHIJ@CKLCMNFO@

(510) 95454896954 95 4896956496#3 46:P

(511) 9

(512) 66!9458 496: 94

(513) Q5 46::8 6!46 46R! 4654> 59

(514) 96:S

(515) 6" 44 6 39:$9.

(516) 6995 9 95 954896954 95 489

(517) 664

(518) 966956

(519) 8

(520) 64 4

(521) 5 96'6TU5VU28W3WXUY5V7Z1[5\UZZ85956VV\8,:(4Q4

(522) 96694 !46 44 4

(523) Q95 9896956

(524) 49

(525) 9

(526) 64 4

(527) 469 !4966464 499 4#3 46 45

(528) >69

(529)

(530)

(531) 95849 6

(532)

(533) 6

(534) ]9684 #

(535) 5 4"6

(536)

(537) !

(538) 8

(539) 8989

(540) 644 5

(541) 9Q 484 63994649 !4 95

(542) 8464 !46 4689=54 9^4

(543) 95 4 8

(544) !94

(545) 59898 9646

(546) 9

(547) 64!9695 9

(548)

(549) ^4 9 4 4!4!R6 44 896954 95 489 544695644 499 4#3 4"

(550) 6989R_ 848996

(551) 5^49 358 4'`, 48

(552) 844 5

(553) 54!

(554) 3

(555) 689

(556) 5

(557)

(558) 696956

(559) 8

(560) 64 ab<>=!

(561)

(562)

(563) 89 9489

(564) 895

(565) 5

(566) 6

(567) 584 8 4849 66489 639 '(b<,8 45

(568) 95 94 848964_ 459 489

(569) 6 !96'66><*,4 9 !9Q

(570) 84

(571) 894 9 9 44 !

(572) 39996 9"6!93 98499 484. 48

(573) 844 4 5 489!4!4 45

(574) 9^496

(575) 8

(576) 8996956 8

(577) 89" !

(578)

(579) 4

(580) 4 499 4#3

(581) *96 9695 844!9695 9

(582)

(583) ^4!4!]9

(584) 89

(585) ! 459

(586) !

(587)

(588)

(589) 89 9 5

(590) 489

(591) 895

(592) 5

(593) 9_!4

(594) 584

(595) 5 9

(596) 495 9ab<>=9

(597) 6 5

(598) 54!

(599) 3

(600) 689 9 4 4

(601) !46639 5 9

(602) 489669594

(603) 56 664 4 466><*5

(604) !94

(605) 594 499 4#3

(606) 84

(607) 9

(608) 4 !R6 49_!4

(609) 584 !495 95 989. !

(610) 8

(611) 89(b<4 9

(612) .

(613) . 23432356789. 3 276

(614) .

(615) . 01. 346787679

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`RBCI89>?:9F<E:A98:=9 I;INB8IEI89F<=9:88:89EB8F<8BGBH<898:9E:H:9Z9>?I;GBEIE:9C<;8BE:=OH:N9E:98:;8<=:89 EB8F<;@H:B89TI8:IE<89:A9EBH:=8<89GBF<89E:9G=I;8E?LD<M9E:;G=:9<89>?IB89S9F<88@H:N9 A:;CB<;I=9INR?AI89CNI88:8M9C<A<V9 abbcdefg9hD<9TI8:IE<89;I9G=I;8K<=AILD<9EI9HI=BILD<9E:9 AI88I9<?9=:I==I;i<9IGjABC<kA<N:C?NI=9E:9?AI9E:G:=AB;IEI98?F:=K@CB:9:A98B;IB89 I;IN@GBC<89A:;8?=OH:B8P9lSC;BCI89I;IN@GBCI89C<A<9I9mBC=<TINI;LI9E:9n=B8GIN9E:9 o?I=GJ<9WonmY9:9mBC=<8C<FBI9E:9p<=LI9_GjABCI9W_pmY9B;G:R=IA9:88I9A<EINBEIE:9 E:98:;8<=9C?i<9K?;CB<;IA:;G<9C<;8B8G:M9E:9K<=AI9R:=INM9;<9:K:BG<9FB:J<:NSG=BC<9 B;H:=8<9:9EB=:G<M9=:8F:CGBHIA:;G:\qP9 rabsg9t8GI9CNI88:9E:98:;8<=:898:9TI8:BI9;I9A:EBEI9E:9 F=<F=B:EIE:89`FGBCI89:98?I9C<;H:=8D<9:A98B;IB89I;IN@GBC<8P9uA9:v:AFN<9E:88:9GBF<9 E:9EB8F<8BGBH<9S9I9GSC;BCI9E:9w:88<;x;CBI9E:9yNI8A<;9E:9h?F:=K@CB:9WhywY9C?i<9 K?;CB<;IA:;G<9C<;8B8G:9TI8BCIA:;G:9;<9K:;jA:;<9E:9=:KN:vD<9B;G:=;I9G<GIN9 IG:;?IEIz{MzXP9 ab7|}g9hD<9EB8F<8BGBH<89TI8:IE<89;I9C<;H:=8D<9EI89ING:=IL~:89EI89 F=<F=B:EIE:89:NSG=BCI89>?:9<C<==:A9;<98:B<9EI98<N?LD<9:A98B;IB89I;IN@GBC<89 A:;8?=OH:B8M9I9:v:AFN<9E<9>?:9<C<==:9:A98:;8<=:89C<;E?GBASG=BC<8z[P9.

(617) . 01. 346789 79

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

(619) . 01. 345467879 94

(620) 436 7579 94

(621) 36

(622) 8 7 9

(623) 94

(624) 7

(625)

(626) 94 9

(627) 4

(628) 4336

(629) 79

(630) 977 5464

(631) 3

(632) 34343

(633) 6454673

(634) 444

(635)

(636)

(637) 647 5

(638) 6 6 567

(639)

(640) 7

(641) 94

(642) 337 7576

(643)

(644) 433

(645) 94

(646) 6 347

(647) 94

(648)

(649)

(650) 3

(651) 4334

(652) 77

(653) 94

(654) 7 46

(655) 64

(656)

(657) 34

(658)

(659) 4476

(660) 645!67

(661) 4

(662) 6 6

(663) !

(664) 44337

(665) 4

(666) " #

(667) 447

(668) 377464

(669)

(670) 84

(671) 3

(672) 45!63

(673) 9

(674) 647 5

(675) 6 678

(676) 94

(677) 47

(678) 477464

(679)

(680) 4

(681)

(682) 6 347

(683) 94

(684)

(685)

(686)

(687) 764 4

(688) 45469$35%&

(689) 337

(690)

(691) 4

(692) 4736

(693) 6 347

(694) 94

(695)

(696)

(697) 67

(698) 9

(699) 5'

(700) 3

(701) 37364 3

(702) 6454673

(703)

(704) 447

(705) 9

(706) 97 %&

(707) 47679

(708) 9484

(709) 34

(710) 377464

(711)

(712) 84

(713) 3

(714) 45!63

(715)

(716) 8473

(717) 94

(718) 447 3

(719) 73

(720) 563

(721) 94

(722)

(723) 3775

(724) (3

(725) 477 3

(726) 6

(727)

(728) 4476

(729) 645!67

(730) 94

(731)

(732) 4#4%&

(733) 94

(734) 45!63

(735)

(736) 67

(737) 9

(738) 4733&

(739) 94

(740) )63

(741) 44

(742)

(743) 679 94

(744) 7

(745) 94

(746) 447

(747) *

(748) " 9

(749) %&

(750) 6. 5"+,

(751) -464

(752) 3

(753) 5776 %.43

(754) 93

(755) 34343

(756) 6454673

(757) 757$34

(758)

(759) 3%&

(760) 9

(761) 97 %&

(762)

(763) 47&

(764) 9

(765) 56 87546

(766)

(767) 64

(768) 9

(769) 647 5

(770) 6 678

(771)

(772) 445

(773) 9

(774) /701

(775) 24334

(776) 3

(777)

(778) 9464%&

(779) 94

(780) 43!743

(781) 75)7 3

(782) &

(783) !

(784) 87845

(785)

(786) 84'

(787) 4

(788) 433

(789) 47&

(790) 9

(791) 4346

(792) 37

(793) 4846 5464

(794)

(795) 94 9 %&

(796) 94

(797) 75!5 313 14

(798) 977 5464

(799) 944949

(800) 9

(801) 67

(802) 94

(803) 647 5

(804) 63343845

(805) 44 9

(806) 94

(807) " 84

(808) 4 7 %&

(809) 9

(810)

(811) 45!6$5

(812) *4$567"896+

(813) 4 9

(814) 45

(815) 3%&

(816) 94

(817) 5'

(818)

(819) 4

(820) !

(821) 943 8845

(822) 6

(823) (

(824) 34 %&

(825) 94

(826)

(827) 4

(828) 34464464

(829) 4 %&