11 20For C3 A7as 20intermoleculares 20e 20consequ C3 AAncias 20bb

(1)

! ! "# $%&

' &

' ( ( ) ( ( *

+ , - + &

, .( . / &

0 (

1 /+ &

2 1 3 4 5 3 ( &

67 - 3 3 % 8&

0 9 - ( ) 0&:& '

1 + ( + - 1 (

( & 8 3, + 1*

CH

₂

CH

C

H

₂

OH

; + < 1 /+ + &

= ( ( 3 3 4

0 % 7 > %?# 9? ?" 7 * @ A

" A "#! A& B 1 >

*

% C > &

(2)

03 8 + 3 C 1 :" C /+ *

:& 8 1 1 3 /+ &

::& 1 1 &

:::& D + < +7 :" /+ &

' / % ;;'E8 D 3

: & :: & ::: &

: :: & :: ::: &

0 - 9 ( + 3

< + 1 698

+ &

8 < + *

F /

+ +7

+ 1 1 -/ (

3 1 >

&

(3)

2 C 3 1 ( 3 + < +7

+7 /+ 1

?"D& %?#& 9? & =? & % "&

03 GH08 I': 8IJ:'9E' ' E'%9 B H:8

8 /+ + @! K 3) & =

+ 3 /+

3 C 1 &

8 /+ + C ( 1

3 &

E 1 /+ + /+

&

6 3 ) /+ + ( 1

3 ,+ +

< ( ) ,+ &

= /+ C < ( L 1 1

/ L &

,+ + + 3 & 8

( ) , + ,

3 + ( , + / 3

3 &

M ( /+ ( 1 3 )

&

8 / > /+ C

( + 3 + + 3 /+ &

8 3 *

: ?/ ( + 3 &

:: 8 C 3 +7 &

::: 8 +7 ( 7 < L +7

+7 & ' / :& ::& :::& : ::& :: :::&

0 9 %"? ? / 1 %? % ? L

:& ( + < 3 + < N

::& ( + < +7 / ( / N

:::& 3 1 ( +7 &

6 3 < : 1 & :: 1 & ::: 1 &

(4)

!

03 + /3 + I =&'&

( 1 , + / / &

8 3 ( /

C 3 +7 &

C + ?&

O <

P Q &

C O <

P Q &

F +

?&

I R L ; C > ? 9 3 L + 3 < &

S6 * ? T U N 9 8 @8 V

: = C 3 +> &

:: D ? 3 +7 &

::: ? 1 ( 9 1 > F &

:P 8 + &

D *

: :P& :: :::& :: :P& : ::& : :::&

0 9 3 *

.8 + 1 ( ) / ( /+ ( /+ 1

3 ( + & = )( 3

) &.

2 4

"

(5)

"

% + 8 ( 1 3, ( 3

+7 *

% + 8 + ( ) 3 > * %" ?:

?" 9 % (

3 *

% + 8 + ( (

*

% + *

?" W !! !

?"D !

?"D # ?"E " "

/+ 1 F 3 ) +7

( *

1 /+ &

+7 1 /+ &

P 6 Q 1 /+ &

1 /+ 1 &

> < &

% + 3) ( ) - 3

+ < F ( /

( 3 1 , 1 & 8 /+ <

1 )( 1

7 , & E +

+7 +7 &

% ( 3 F 3 ,+ + >

/ < &

8 > )( ( 9X L

(6)

# I &

' &

G , & E 3 &

&

% +

(

O /+ &

1 ( + &

+ 1 ( &

1 ( + &

( ( + &

= ? ?% 3 1

+ < +7 & &

+ < P Q ? + < +7 ?% &

+ < +7 ? ?% &

+ < / ? L ?% &

: D )( 3 3 < *

:& 8 3 + ( ) :9E;8 &

::& 8 3 + ( ) :9E'; &

:::& 8 )( &

:P& 8 ( , &

' % ;;'E8D* 8 : :: 8 : :P& 8 ::: :P&

8 :: ::: :P E

= + D ( + ( 1 + +

698 ( 3 + &

+ + < *

& + < +7 &

(7)

$

= + % > 3 "&

8 ( 7 % ;;'E8 1*

: ::: :P :: :: ::: : :P :P :: ::: : :P :: : :::

= + Y 1 ) ( /+ & D

( C /+ 1 ) *

& &

+ < 3 &

&

= ) - ( + 3

> - 3, + *

= / 3, 1 3 ( >

& O /+ &

3 3 < ( ) & F &

+ < &

= % % 3,

( + &

'

3, %@?@ & F &

+ 3 &

+ ,3 &

(8)

% =

= / ( (

1*

: Z :: Z ::: Z :P Z P :: Z : Z P Z ::: Z :P :: Z P Z : Z ::: Z :P ::: Z :P Z : Z :: Z P :P Z ::: Z P Z : Z ::

= 8 / 3, F (

& 9 /

) 1 3) &

6 + F 3 3 + &

= 3 ( F ( 1

* F > 3 ( 3, &

0 9 + 1 ,

+7 &

3 Q &

(9)

&

0 8 < + < +7

3 )( ( + 3) )( &

6 > 1 ) / , (

3 1*

M ) & ' &

G , & % & 8 &

0 ) .+ . J 1

+ ( / & 6 3

) * / ) +>

( ) - )L &

8 !! B + 3 /+ B&

= :" ( 3

@!! B !! B& C + ( 1

1 + [ ) &

' ( ( ( ) ( 1 +

1 1 &

0 8 + + ( &

8 + > L 3 <

) . , . 3 +

L & 8 + ) )

3 + 3 31 ) 3)

) ) & 6

(10)

'

0 - G+ )( ) ( ( < + <

* F

+7

L L

0 - - 3, / + 1 +

+ + &

6 ( ( L 1*

/+

03 ; ( 9 8 * "!!! &#! +&

( + ) 3)

1 < & 8 ( 1

( 3

( + *

) ) &

) &

L L &

L & &

03 8

=' 3 &

3 ( 3 1*

+ &

+ F &

+ +7 & 3 P Q &

(11)

8 3 ( < : :: ::: *

+ +7 /

+ +7 + +7 /

/ + +7

+ +7 /

03 + % > )( /+

< &

8 < 3 1

: :: ::: :P P

03 + 8 /+ 1 & % C /+ C < (

3 8BD8 1

3 + < +7 F + 9? +

/+ &

+ < +7 ( &

1 +7 + ?% + ( /+ + )

? W _{% &}

) ? W _? _/ ₁ _/+ _&

+7 "+ /+ <

&

03 + 8 ( > I8: ; 1

03 + ' E' $% 7

(12)

% , /

1 1 % ;;'E 3 ( <

(

+ %]\&

O 1 7 / \&

+ / \ + / &

> 1 1 7 / \ O &

03 + = - +

+ & + &

& /+ &

03 + ' ( 3 >

" "

% :% : *

! ! " # $ % ! ! " & '$ %

"

% !"

:% W"@ W^@

"

: W W #

% > 1 % ;;'E 3 (

:% < 3 ( :_"&

" $% % " 1 + :% 1 )( :" 1 , &

1 :% F / / &

:% < >

L &

03 + 8 ( ( / (

> *

% ( 1 % ;;'E 3 ( C (

F 3

+ < &

< > L &

+ < +7 &

< &

03 8 < 1 L

3) ( ) ,

( ,+ & 8 +

(13)

% 3 ( *

< 3 ( (

/+ &

< 3 ( (

&

7 )( 1 ( + < +7 3 &

+ < 1 7 )( &

< 3 ( (

/+ &

03 8 , L 3

+ < ( ) & 3 , + 1

+ <

Q / &

F / &

Q / &

Q F &

03 ( ( + &

8 /+ 1

" #& " # & " # & # "& # " &

03 8 =' +

+7 + # , &

+ # 3 1 ( (

+ 3 1 &

% 3 3

(14)

! ` ` ` !&

` ` Z !& Z Z ` !& Z Z Z !& Z ` ` !&

0 = 3 ( /+ , +

( )( & : L + <

/ +7 +7 + 1 /+ + L & 8

< 1 /+

3 P Q &

3 L &

3 &

+7 & + < &

0 % 1 ( +

> L ] % ? 1 O 4

0 ( ) D D E + , 3

+7 + , 3, ( ) ?" ?"D

?"D ?"E &

8 ?"D ?"D ?"E

&

8 /+ ( &

' < *

3 < &

3 + < +7 &

3 < &

3 +7 &

0 3 8 + 1

L 3 & 6 +7

, 3 F 3 +7 /+ ( (

D " ?"D& 9" ?" & 9? ?" &

(15)

"

0 0 > > & %

+ ( / , J " C

%% # /+ ?" &

? +7 &

? +7 %% #&

? +7 ?" &

? +7 %%#&

? +7 ?" &

0 . &&& % J 5 1 J 3/ #!R D 5 1 ; =

D = 3 3 / 3 + )3 I & 3

L F &. aaa&+ a &+ &

8 F 9? 1 +/ C & 9 1

+ + )( , & 8 (

1 )( &

+ +7

L

L L

) ]

0 ' < / )( 3

/+ & ' / ( (

/+ 1

% + 0 1 + # +[

F +7 " " K # K

+7 K +7 & = 3 ( 1

)( + *

F & &

& P Q &

+7 &

0 = 1 ( + 3 ) 1

1 3 & + , )

/ & 8 ) 1

( ) + ! R+ &

' + ) 1 -/ 1 7 C &

' 7 ( / 1

& / ( 1 +

(16)

#

8 ( ) ( 1 C

4 5 3 ( &

6 3 + 1 ) ( 7

3 ( 7 C

&

0 2 ( / /+

1 ) & 0 < ? W

+ ( 3 F 1*

luz

2 2 3

(H O) H O e OH

dímero íon elétron radical

(Números atômicos :H 1; O 8).

+ −

→ + + •

= =

; B a 3, F ) + &

2 3 < ( 1 ) ( - 3

7 4

E > ( 3 /+

, & ' 3

) + + 3 /+ 3)

1 + 3 , 3) &

0 L >

% "?"" 1 L

& D 3, 1 &

2 1 3, ( + L

4 8 ( 3 +> 4

9 3, 3)

3) & 5 3 ( 3 /+

, &

: D )( 1 3 3 *

8 3 + ( ) :9E'; & %';E ';;86 4

5 3 ( &

: % + 3) /+

(17)

$

8 8 D 3) +

/ , &

8 J D 3) + /

) + / &

P 3 + ( 3 (

3 3) /+ 'I %868 0I8 68D 8BE';98E:P8D 89E';: ;'D&

: 2 3 L 7 3 (

L /+ )( (

3 ( /+ , 4

03+ / 1 698 1 1 3 & '

O 3 3 ( & B + O

+ ( +7 & 0 ( 7

1 C * 8E%%H8H + E8HH%E% & 8

+ 3, *

; +7 ( 698&

03 - % + *

2 ( 3 - 3 3 3) +

4

03 I 3) >

1 & D ( .

. > F /+ *

( 1 4 5 3 ( + &

( > / O /+ 4 5 3 (

&

03 D 1 )( L + O > & I

O ( + L )

+ &

% ) + ( ( )( ?" % ? "

(18)

%

0 6 : :: ::: + *

2 : ::4

: :: 3 &

% ( 1 ) 3

:::4 5 3 ( &

(

2 F b 3) c

* ` ` ` &

H 1 (

+ , &

, L / &

' *

" "

,

9 ?% +?\→? +% +9 \

8 % 1 3 (

+ ? ( 3 L + < +7 +7 /+ &

8 % ( + ? ( 8

( 3 L ( + < +7 +7 (

+ < ( 3 a &

E *

C

H

₂

C

H

C

H

₂

O

H

O

H

O

H

(19)

&

8( +7 1

/+ + /+ 1 3

&

=' %?# U " AN =' 9? U "#! AN =' ?" U @ A&

%?#* P Q =' &

?" 9? @ * 1 3 L + < +7 *

, & = 1 /+ ?" 3 L + < +7 1 ( F 9? & = =' ?" ` =' 9? &

8 J&

6 % 6 ' % J

8 J& E 7 &

.8 + 1 ! " ( "! ! / ( /+ ( /+

1 3 ( + & = )( # ! " !

&) & " & ! " " " # ! *+ ) & ! ( "! ! $ & ! ,- $ ! &.

6 8 % J 6

8 6 6 J J %

' 6 J 6 J %

C + 1 / ) 3 1

3 ( + W 3 1 3

/+ W / ) &

P ) U !! B

P / ) U !! B ] @!! B U !! B !! B !!K

!! B

U " K / ) &

1 3 1 (

/+ ( 1 & 9 ) L /+ 3 &

8 J % % 6 % %

' 8 6 8 % J '

' J ' 6 8 ' J

(20)

'

) C 1 / 3 <

1 ( &

3 + + *

< 1 + <

+7 &

3 + + *

' 1 / + < +7 +7 &

% ? " / ) &

(21)

% & 2 3 + / + /

7 3 ( > + /

> &

8 + + , 3) /+ / 3 31

, 1 /+ 1 + /

, /+ &

8 3 L / 1 % ?@ −% ? / /+ 3

) ( , + / 1

% ? / ) /+ + % @? 1 / /

/+ - / &

8 + / + < +7 +7

/+ )( 1 ( , , 1

/+ > ( )( &

6 3 b 3 ( c + < +7 +7

& % ( + +

b + < c ( 3 b

+ < c &

+ *

9" % # < P Q

L )( , & ' < 3 (

3) ( % #

3 ( 9"&

?J 1 1 < ( 1

3 ( L &

8 /+ 1 + < +7 +7 ( 1

3 1 3)

&

8 F * H 1 1 3

L & 8 1 1 &

G+ * H + 1 1 3 L & 8

1 1 &

I * H 1 1 1 + L & 8

1 1 &

8 > O /+ / F 1

1 1 3 L C /+ &

G+ L ) - /+

1 L 1 &

% :* &

% ::* &

::: / ( : ::

1 + 3) 1 1 & 2 3

Q 1 / & 2 1

3 3) 1