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Azeotropic separation: playing with the ionicity of ionic liquids

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Academic year: 2019

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Figure 1 | Temperature - composition phase diagr ideal  behaviour,  b)  positive  deviation  from  the  Raoult
Figure  2  |  Deviations  from  the  “ideal”  Walden  behaviour  for  the  binary  systems  [C 2 MIM][C 2 SO 3 ]  +  [NH 4 ][SCN] and [C 2 MIM][C 2 SO 4 ] + [NH 4 ][SCN] 12  plotted against the inorganic salt molar concentration
Table  S1  in  SI  presents  the  experimental  data  for  the  viscosity  and  density  of  the  [ C 2 MIM ][ C 2 SO 3 ]  +  [ NH 4 ][ SCN ]  binary system
Figure  5  |  Trend  of  the  chemical  shift  difference  of  protons  in  1 H  NMR  of  [C 2 MIM][C 2 SO 3 ]  (red)  and  [C 2 MIM][C 2 SO 4 ] 12  (blue) with increasing [NH 4 ][SCN] concentration (∆δ = δ −δneat) (b is an enlarged image of  a)
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