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[PENDING] Van der Waals interactions between two-hydrogen atoms : the Slater-Kirkwood method revisited

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Academic year: 2024

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Fig. 3.1. Interaction energy (van der Waals energy) between two hydrogen atoms. The unit for the vertical scale is the Hartree, and the unit for the horizontal scale is the Bohr
Fig. 3.2. Plots of (a) −T (r 1 , r 2 ) and (b) −T (r 1 , r 2 )/(r 1 r 2 ) = −ψ 0 (r 1 s 1 , r 2 s 2 )/b(s 1 , s 2 ), where T is the unique solution in H 0 1 (Ω) of the equation (3.24), b is defined in (3.16), and ψ 0 is defined in (3.28)
Fig. 3.3. Comparison of perturbation ψ 0 (rs 1 , rs 2 )/b(s 1 ,s 2 ) (lower curve) with ground-state wave function ψ 0 (rs 1 , rs 2 ) (upper curve)
Fig. 3.4. Spherical coordinates for visualizing the function b defined in (3.16).
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