Fluidization and gas-solid systems - introduction
MSc. Leszek Stepien Faculty of Energy & Fuels
Winter 2014/2015
prof. Marek Sciazko
Monday 9.45-11.15
OBLIGATORY attendance
LECTURE (30h)
Expected achievements
Student is aware of advanced knowledge in the field of the implementation of typical fluidization and
other gas-solid systems, and principles of their design.
Has advanced knowledge of fluidization process arrangement and specific component’s function, particularly in a high velocity fluidization.
Is able to use the acquired knowledge to solve
specific engineering problems of fluid bed systems.
MS-AGH-2014 3
Contents
1. Introduction
Phenomenon of fluidization
Advantages and disadvantages
Applications for physical and chemical operations
Particle size distribution
Mean particle size
MS-AGH-2014 4
2. Mapping of fluidization regimes
Fixed bed, pressure drop
Minimum fluidizing velocity
Bubbling fluidization
Terminal transport velocity
Choking
Circulating fluid bed
3. The dense fluid bed
Distributors
Rising bubbles in fluid bed
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4. Bubbles in dense bed
Model of gas flow
Solids within bubbles
Bubble size – growth
5. Entrainment and elutriation
Freeboard
Entrainment from tall vessels
6. High velocity fluidization
Characteristic gas velocities
Two-phase model of circulating bed
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7. Heat transfer
Heat transfer between fluid bed and surfaces
8. The RTD and size distribution
Particles of unchanging size
Particles of changing size
9. Design of fluid bed reactors
For physical operations
For chemical operations
MS-AGH-2014 7
Computing tools:
Excel
MathCad
Personal calculator
Literature:
Daizo Kunii, Octave Levenspiel. Fluidization Engineering, Butterworth-Heinemann, 2nd Edition
Marek Ściążko. Studium aerodynamiki cyrkulacyjnego reaktora fluidalnego, Chemia Z.143, Politechnika Śląska, Gliwice 2001.
MS-AGH-2014 8
Student’s grading
Evaluation is a shared responsibility between the teacher and the student. The purpose of the evaluation is to demonstrate how well the student has learned specific course materials, the principles, concepts and terms relevant to the fluidization field, and to determine the students’ ability to apply that knowledge to specific engineering problems.
Final grade (OK) is calculated as weighted mean of lecture test (T), seminar delivered work (P):
OK = 0,4·w·T + 0,6·P
w – student’s activity; w=1; attending at least 80% of lectures, w
= 0,7 more than 50% and less than 80%, w = 0,3 for more than 50% unjustified absences.
MS-AGH-2014 9
Msc. Leszek Stępień
Friday 10-11.30
OBLIGATORY attendance
Grade: class test + activity/homework (problem solving)
CLASSES (15h)
1. Fludization velocities
a) Calculating mean diameter of particles b) Minimum fludization velocity
c) Terminal velocity 2. Gas distributors
3. Bubbling fluidization a) Size of bubbles
b) Kuni-Levenspiel bubbling bed model 4. Entrainment & elutriation
5. Fluid bed aerodynamics
6. Application example – drying process
Topics
Fluidization
The idea of fludization
Set of solid particles with of different size
(diameter/mass/density) is lifted by the counter current flow of gas to form the uniformly spread bed
Advantages:
Uniform temperature distribution
Large contact area between solid and gas phase
Good mixing => uniform
concentration of substrates and products in the system
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The idea of fludization
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Flow regimes
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Pros & Cons
Smooth flow = easier control
Isothermal conditions
Good resistance to rapid temperature changes
Heat and mass transfer
Suitable for large scale operations
Difficult to describe flow of gas
Nonuniform residence time
Entrainment of friable solids
Erosion of pipes
Possible agglomeration
and sintering
Fluidization significance
Energy generation
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Based on the steam parameters:
subcritical pulverized coal (SubCPC) plants,
supercritical pulverized coal (SCPC) plants,
ultra-supercritical pulverized coal (USCPC) plants
Based on parameters inside the furnace:
Atmospheric
Pressurized
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The heart of powert plant - BOILER
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Circulating fluid bed
Around 2 million tons of coal will be required each year to produce the continuous power.
Around 1.6 million cubic meter of air in an hour is delivered by air fans into the furnace.
The ash produced from this combustion is around 200,000 tons per year.
The boiler for typical 500 MW units produces around 1600 tons per hour of steam at a temperature of 540 to 600 degrees C. The steam pressures is in the range of 200 bar.
The steam leaving the turbine is condensed and the water is pumped back for reuse in the boiler. To condense all the steam it will require around 50,000 cubic meter per hour of cooling water to be circulated from lakes, rivers or the sea.
The water is returned to the source with only an increase of 3 to 4 degrees centigrade to prevent any effect to the environment.
Apart from the cooling water the power plant also requires around 400 cubic meter per day of fresh water for making up the losses in the water steam cycle
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500MW power plant - overview
Polands newest & most efficient power plant (44%)
the world's largest CFB boiler
High efficiency => lower fuel requirements, and lower levels of ash and emissions, including carbon dioxide (CO2).
CFB technology has excellent fuel flexibility and
offers the option of co-firing of biofuels with different grades of coals, which can further reduce CO2
emissions.
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Łagisza power plant
40-50 kg of coal/sec !!
Fluid bed approx 300 000kg
The fuel and limestone particles are recycled over and over back to the process, which results in high
efficiency for burning the fuel, capturing pollutants, and for transferring the fuel's heat energy into high- quality steam to produce power.
Steam: 27,5 MPa, 560C
No chimney
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Łagisza power plant
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Load flexibility and high heat transfer rates
Fuel flexibility, can gasify a wide range of feedstocks
Moderate oxidant and steam requirements
Has a uniform, moderately high temperature throughout the gasifier
Higher cold gas efficiency than entrained-bed gasifiers, but lower carbon conversion
Extensive char recycling is required
Fluid bed gasifier
The HTW gasifier is a circulating fluidized-bed reactor which operates in either air or oxygen blown modes.
Dry-feed, pressurized, dry ash gasifier.
A key advantage of the technology is the capability to
gasify a variety of different feedstocks, including all grades of more reactive low-rank coals with a higher ash softening temperature (i.e., brown coal), and also various forms of biomass.
Due to the high outlet temperature, the syngas does not contain any higher molecular weight hydrocarbons, such as tars, phenols, and other heavy aromatics.
High Temperature Winkler
The bottom part of the gasifier comprises a fluidized-bed (the fluidizing medium air/oxygen +steam)
The bed is formed by particles of ash, semi-coke and coal, and is
maintained in the fluidized state via upward flow of the gasification
agent
Gas plus the fluidized solids flow up the reactor, with further air/O2 and steam being added in this
region to complete the gasification process.
Fine ash particulate and char entrained in the raw syngas are removed in a cyclone and cooled.
The solids removed in the cyclone are returned to the gasifier base to maximize carbon conversion
EU energy in figures 2012
http://www.pke.pl/
http://www.elko.com.pl/elkoweb/site2/site.php
http://www.brighthubengineering.com
http://www.freund-vector.com/lab/equipment.asp
R. Szafran et al., New spout-fluid bed apparatus for electrostatic coating of fine particles
and encapsulation, Powder technology(2012), 225
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