Sugestões para trabalhos futuros

 Realizar ensaios com maiores pressões e temperaturas para verificar maiores alterações físicas e mineralógicas na estrutura da rocha submetida à exposição de CO2.

 Realizar ensaios com rochas carbonáticas sintéticas.

REFERENCIAS

1. ALLISON, J.D., D.S. BROWN, AND K.J. NOVO-GRADAC (1990) MINTEQA2/PRODEFA2, A Geochemical Assessment Model for Environmental Systems: Version 3.0 User’s Manual. United States Environmental Protection Agency, Office of Research and Development, Washington, DC, EPA/600/3-91/021, 106p.

2. ALLOWAY, B. J., Heavy metals in soils. Jonhn Wiley Sons: New York, 1995, 337p.

3. ANTHONSEN, K.M., AAGAARD P., BERGMO P.E.S., ERLSTRÖM M., FAREIDE J.I., GISLASON S.R., MORTENSEN, G.M. SNÆBJÖRNSDOTTIR S.Ó. - CO2 storage potential in the Nordic region Energy Procedia, 37 (2013) 4. APPELO CAJ, POSTMA D (2005). Geochemistry, groundwater, and pollution

(2nd ed.). Balkema, Amsterdam p. 635.

5. BACHU, S., 2000: Sequestration of carbon dioxide in geological media: Criteria and approach for site selection. Energy Conservation and Management, 41(9), 953–970.

6. BACHU, S., ADAMS, J. J. (2003). Sequestration of CO2 in geological media in response to climate change: Capacity of deep saline aquifers to sequester CO2 in solution. Energy Conversion and Management, v. 44, p. 3151-3175.

7. BACHU, S., W.D. GUNTER AND E.H. PERKINS, 1994: Aquifer disposal of CO2 : hydrodynamic and mineral trapping, Energy Conversion and Management, 35(4), 269–279.

8. BALL, J.W., NORDSTROM, D.K., 1991. User’s Manual for WATEQ4F, with Revised Thermodynamic Data Base and Test Cases for Calculating Speciation of Major, Trace and Redox Elements in Natural Waters. US Geol. Surv. Open- File Rep. 91- 183.

9. BARBOSA, J. A., PEREIRA, P. J. F., LIMA FILHO, M. Dente de um picnodontiforme (Actnopiterygii, Neopterygii) da Formação Estiva, Cenomaniano- Turoniano da Bacia de Pernambuco, NE do Brasil. GAEA, v. 4, n. 2, p. 43-48. 2008.

10. BARCELLOS R.G.S. 2006. Descarga de água subterrânea e fluxo de elementos em ambientes de manguezal. Baía de Sepetiba, RJ. Tese de doutorado. Niterói: Departamento de Geoquímica Ambiental, Universidade Federal Fluminense, 144 p.

11. BEGHINE, P.S.; ROSA, J.. SUBSTITUIÇÃO DE MISTURADOR DINAMICO POR MISTURADOR ESTÁTICO PARA HOMOGENEIZAÇÃO DE SOLUÇÕES. Centro de Pós-Graduação Osvaldo Cruz, 2011.

12. BODIPAT, K; DIRAJ D.; FRYE, E.; HUA, L.; MCCABE, T. (2010). Carbon Capture and Storage. Integrative Design of Energy & Mineral Engineering Systems. College of Earth and Mineral Sciences at Penn State

13. BODIPAT, K; DIRAJ D.; FRYE, E.; HUA, L.; MCCABE, T. Carbon Capture and Storage. Integrative Design of Energy & Mineral Engineering Systems. College of Earth and Mineral Sciences at Penn State, p. 39-48. 2010.

14. BRASIL. Lei nº 12.187. Institui a Política Nacional de Mudanças Climáticas. Diário Oficial da União, Brasília, p. 109, 29/12/2009.

15. BROWN, D.W. A Hot Dry Rock Geothermal Energy Concept Utilizing Supercritical CO2 Instead of Water, Proceedings, Twenty-Fifth Workshop on Geothermal Reservoir Engineering, pp. 233–238, Stanford University, January 2000.

16. CARRILHO, E. M. TAVARES, C. H. e LANÇAS, F. M. 2000. Experimental Studies of CO2 -Rock Interaction at Elevated Temperatures under Instituto de Química de São Carlos, Universidade de São Paulo, CP 780, 13560-970 São Carlos – SP.

17. CHOPPING C, KASZUBA JP (2012) Supercritical carbon dioxide-brine-rock reactions in the Madison Limestone of Southwest Wyoming: An experimental investigation of a sulfur-rich natural carbon dioxide reservoir. Chem Geol 322:223-236.

18. CHOW, J.C., J.G. WATSON, A. Herzog, S.M. Benson, G.M. Hidy, W.D. Gunter, S.J. Penkala and C.M. White, 2003: Separation and capture of CO2 from large stationary sources and sequestration in geological formations. Air and Waste Management Association (AWMA) Critical Review Papers, 53(10), October 2003.

19. CHRISTENSEN, T. H,; KJELDSEN, P.; ALBRECHTSEN, H. J.; HERON, G; NIELSEN, P. H.; BJERG, P. L.; HOLM, P. E. Attenuation of landfill leachate pollutants in aquifers. Critical Review in Environmental Science and Technology, no 24, p. 119-202, 1994.

20. CHRISTENSEN, T. H,; KJELDSEN, P.; BJERG, P. L.; JENSEN, D. L.; CHRISTENSEN, J. B.; BAUN, A.; ALBRECHTSEN, H. J.; HERON, G. Biogeochemistry of landfill leachate plumes. Applied Geochemistry, no 16, p. 659- 718, 2000.

21. CREDOZ, A. et al. Experimental and modeling study of geochemical reactivity between clayey caprocks and CO2 in geological storage conditions. Energy Procedia, Volume 1, Issue 1, Pages 3445–3452, 2009.

22. CZERNICHOWSKI-LAURIOL I, SANJUAN B, ROCHELLE C, BATEMAN K, PEARCE J, BLACKWELL P (1996) The underground disposal of carbon dioxide. Inorganic Geochemistry JOU2, 7: 183-276

23. DDY B.S., HIROSE Y., LUBET R., STEELE V., KELLOFF G., PAULSON S., SEIBERT K., RAO C.V. Chemoprevention of colon cancer by specific cyclooxygenase-2 inhibitor, celecoxib, administered during different stages of carcinogenesis. Cancer Res. 2000;60:293–297

24. DREVER, J. I. The Geochemistry of Natural Waters: surface and groundwater environments. 3rd ed., 1997, p. 436.

25. DUNHAM, R.J., 1962, Classification of carbonate rocks according to depositional texture: Ham, W.E., ed., Classification of carbonate rocks da: AAPG. Mem. 1. 108-121.

26. FERRAZ, R.L. 2006. Acoplamento dos processos do adensamento e do transporte de contaminantes em solos compressíveis. Pós-graduação em Engenharia Civil, COPPE, Universidade Federal do Rio de Janeiro, Rio de Janeiro, Tese de doutoramento, 346p.

27. FETTER, C.W. Contaminant hidrogeology. New York, Macmillan Publishing Company, 1993.

28. FOLK, R. L. 1962. Spectral subdivision of limestones types. In: W. E. Ham, ed., Classification of Carbonate Rocks: Tulsa, OK, American Association of Petroleum Geologists Memoir, 1, 62-84.

29. FOUILLAC, C., B. SANJUAN, S. GENTIER AND I. CZERNICHOWSKI- LAURIOL. Could Sequestration of CO2 be Combined with the Development of Enhanced Geothermal Systems?, paper presented at Third Annual Conference on Carbon Capture and Sequestration, Alexandria, VA, May 3-6, 2004.

30. FREEZE, R.A., and CHERRY, J.A. (1979). Groundwater. Pentice-Hall, Englewood Cliffs, N.J.

31. GRABAU, A. W. 1904. On the classification of sedimentary rocks: American Geologist, 33: 228-247.

32. GUIMARÃES L.J.N., GENS A, SANCHEZ M, OLIVELLA S. (2006). THM and reactive transport analysis of expansive clay barrier in radioactive waste isolation. Communications in Numerical Methods in Engineering; 22(8):849– 859. DOI: 10.1002/cnm.852.

33. GUIMARÃES L.J.N., GENS A., OLIVELLA S. (2007). Coupled Thermo- Hydro Mechanical and Chemical Analysis of Expansive Clay Subjected to Heating and Hydration. Transport in Porous Media, vol. 66, pp. 341–372.

34. GUIMARÃES, L.J.N, GENS, A., SÁNCHEZ, M., OLIVELLA, S. (2013). A chemo-mechanical constitutive model accounting for cation exchange in expansive clays. Geotechnique 63, No. 3: 221–234.

35. GUIMARÃES, L.J.N., GOMES, I.F., VALADARES, J.P. (2009). Influence of mechanical constitutive model on the coupled hydro-geomechanical analysis of fault reactivation. In: Reservoir Simulation Symposium - Society of Petroleum

Engineers SPE, The Woodlands, 2-4 February 2009, SPE-119168-PP. Texas:

EUA.

36. GUNDOGAN N, CITAK S, YALCIN E (2011). Virulence properties of extended spectrum beta-lactamase-producing Klebsiella species in meat samples. J. Food Prot. 74:559-564.

37. GUNTER, W.D., S. BACHU AND S. BENSON, 2004: The role of hydrogeological and geochemical trapping in sedimentary basins for secure geological storage for carbon dioxide. In: Geological Storage of Carbon Dioxide: Technology. S. Baines and R.H. Worden (eds.), Special Publication of Geological Society, London, UK. Special Publication 233, pp. 129–145.

38. GOOGLE MAPS. [Brasil Região Nordeste]. Disponível em: https://www.google.com.br/earth/download/ge/agree.html.

39. HESJEVIK S M, OLSEN S and SEIERSTEN M: 'Corrosion at high CO2 pressure'. Corrosion 2003, NACE paper number 03345.

40. IEA(2008). International Energy Agency. Disponível em Acessado em 10/05/2014

41. IEA. CO2 Emissions From Fuel Combustion Highlights, 2009

42. IGLESIAS, R. S. et al. CO2-water-rock interactions in the Hygiene Sandstones (Upper Cretaceous), Denver Basin, USA: Implications for carbon dioxide storage in sandstone reservoirs. Applied Geochemistry, v. submitted, 2013. 43. IPCC (2005). Intergovernmental Panel on Climate Change Special Report.

Carbon Dioxide Capture and Storage: Summary for Policymakers and Technical Summary.

44. IPCC. IPCC Special Report on Carbon Dioxide Capture and Storage. Prepared by Working Group III of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, p. 442. 2005.

45. KASZUBA, J. P., JANECKY, D. R.; SNOW, M. G. (2003). Carbon dioxide reaction process in a model brine aquifer at 200ºC and 200 bars: implications for geologic sequestration of carbon. Applied Geochemistry, v. 18, p. 1065-1080. 46. KOTZ, John C.; TREICHEL JUNIOR, Paul M. Química Geral e Reações

Químicas. vol. 1, 5ª. ed., São Paulo: Pioneira Thomson, 2005, 671p.

47. LAGREGA, M.D.; BUCKINGHAM, P.L.; EVANS, J.C. Hazardous waste management. New York, McGraw-Hill, 1994.

48. LINS, C.M.M.S., MELO, L.M.P., OLIVEIRA, A.D., FIRMO, A.L.B., GALINDO, K.B.T. (2012). Analysis of the carbon dioxide (CO2) injection on carbonate rocks. Cientec. V4 (2): 84-91.

49. MACHADO, C. X. ; KETZER, J. M. M. ; MARASCHIN, A. J. ; ROCKEt, G. C. ; SBRISSA, G. F. ; CAPORALE, G. ; MACALOS, C. L. ; ROCHA, L. H. S. ; CENTENO, C. I. ; CRUZ, A. O. (2009). Construção de um SIG para associação de fontes estacionárias e reservatórios geológicos de CO2 no Brasil. In: Ziliotto, M.A.. (Org.). Mudanças Climáticas, Sequestro e Mercado de Carbono no Brasil. Curitiba/PR: Instituto Ecoclima/UFPR , v., p. 267-279. 50. MERKEL BJ (2011) Thermodynamic Data Dilemma. In: The new Uranium

Mining Boom – Challenge and lessons learned (Eds) Merkel BJ, Schipek M, Uranium Mining and Hydrology VI, Springer, Freiberg.

51. MONCADA, M.P.H. (2004). Estudo em laboratório de características de colapso e transporte de solutos associados à infiltração de licor cáustico em um solo laterítico. Dissertação (Mestrado em Engenharia). Programa de Pós- Graduação em Engenharia Civil do Departamento de Engenharia Civil da PUCRJ. Rio de Janeiro, 190p.

52. ORTOLEVA, P. J.; DOVE, P.; RICHTER, F. Geochemical perspectives on CO2 sequestration., U.S Department of Energy Workshop "Terrestrial Sequestration of CO2

54. PARKHURST, D.L. APELLO, C.A.J. 1999. User’s guide to PHREEQC (version 2) - A computer program for speciation, batch-reaction, one- dimensional transport, and inverse geochemical calculations. U.S. Geological Survey Water-Resources Investigations Report 99-4259.

55. PATRIARCHE, D., MICHELOT, J.-L., LEDOUX, E., SAVOYE, S. (2004). Diffusion as the main process for mass transport in very low water content argilites : 2. Fluid low and mass transport modeling. Water Resour. Res. 40, W01517, doi : 10.1029/2003 WR0022700

56. PETROBRÁS (2008). Balanço Social e Ambiental 2008. Disponível em: <http://www.petrobras.com.br/minisite/ambiental/linksdownloads/downloads/pd f/BSA2008.pdf>Acessado em 26/01/2012.

57. PETROBRÁS (2008). Balanço Social e Ambiental 2008. Disponível em: Acessado em 26/01/2012.

58. PORTIER, S. and Rochelle, C. Modelling CO2 solubility in pure water and NaCl-typewaters from 0 to 300 degrees C and from 1 to 300 bar - Application to the UtsiraFormation at Sleipner. Chemical Geology 217, 187-199, 2005.

59. PRAUSNITZ, John M.; LICHTENTHALER, Rudiger N.; AZEVEDO, Edmundo G. Molecular Thermodynamics of fluid-phase equilibria. 3. ed. New Jersey: Prentice Hall PTR, 1999.

60. ROBERTS, W.L., T.J. CAMPBELL, G.E. RAPP. Encyclopedia of Minerals. 2nd Edition. Van Nostrand Reinhold, New York. p. 979. 1990.

61. ROCHELLE, C.A., I. CZERNICHOWSKI-LAURIOL and A.E. MILODOWSKI, 2004: The impact of chemical reactions on CO2 storage in geological formations, a brief review. In: Geological Storage of Carbon Dioxide for Emissions Reduction: Technology, S.J. Baines and R.H. Worden (eds.). Geological Society Special Publication, Bath, UK.

62. SBRISSA, G. F. ; KETZER, J. M. M. Geoquímica e Integridade Mineralógica do Sistema CO2-rocha-fluído em Reservatórios da Formação Rio Bonito Bacia do Paraná. In: IV Mostra de pesquisa da pós-graduação. Porto Alegre. Anais da IV Mostra de pesquisa da pósgraduação, p.750-752. 2009.

63. SBRISSA, G. F; KETZER, J.M.M. (2009). Geoquímica e Integridade Mineralógica do Sistema CO2-rocha-fluído em Reservatórios da Formação Rio Bonito – Bacia do Paraná. In: IV Mostra de Pesquisa da Pós-Graduação, PUC- RS.

64. SCHMAL, Martin. Cinética e Reatores: Aplicação na Engenharia Química: teoria e exercícios. Editora Synergia, 2010. Capítulo 4.

65. SHACKELFORD, C.D. (1993). Contaminant transport. Geotechnical practice for waste disposal. D.E. Daniel, ed., Chapman and Hall, London, England, 33- 65.

66. TIANFU XU, GUANHONG FENG,YAN SHI, 2014: On fluid-rock chemical interaction in CO2-based geothermal systems. Jornal chemical exploration. Publication, China.

67. TRUESDELL A. H. and JONES B. F. (1974) WATEQ. A computer program for calculating chemical equilibria of natural waters. U.S. Geof. Sur& J. Res. 2, i33- 248.

68. Ueda, A., K. Kato, T. Ohsumi, T. Yajima, H. Ito, H. Kaieda, R. Metcalfe and H. Takase. calculations. Water Resources Investigation Report 99-4259, Denver, USA

69. VALTZ, Alain; CHAPOY, Antonin; COQUELET, Christophe; PARICAUD, Patrice; RICHON, Dominique. Vapour–liquid equilibria in the carbon dioxide– water system, measurement and modelling from 278.2 to 318.2 K. Fluid Phase Equilibria, v. 226, p. 333-344, 2004.

70. VOLESKY, B. Biosorption by fungal biomass. In Biosorption of Heavy Metals; Volesky, B., Ed.; CRC Press: Boca Raton, FL, 1990; pp 139-172.

71. YU, Z. et al. An experimental study of CO2–brine–rock interaction at in situ pressure–temperature reservoir conditions. Chemical Geology, v. 326–327, n. 0, p. 88-101, 10/9/ 2012. ISSN 0009-2541. Disponível em:<http://www.sciencedirect.com/science/article/pii/S0009254112003361 >.

72. ZHU C (2002) In situ feldspar dissolution rates in an aquifer. Geochim Cosmochim Acta 69:1435-1453

73. ZHU C, Anderson GM (2002) Environmental Applications of Geochemical Modeling. Cambridge University Press, London