R59 Dados dos Padrões

(1)

GRUPO DOS ORGANOFOSFORADOS

Nome CAS Fórmula/ Peso

molecular Estrutura

Acephate 30560-19-1 C

4

H

10

NO

3

PS 183.17

Azinphos-ethyl 2642-71-9 C

12

H

16

N

3

O

3

PS

2

345.38 Azinphos-methyl 86-50-0 C

10

H

12

N

3

O

3

PS

2

317.32 Bromophos-ethyl 4824-78-6 C

10

H

12

BrCl

2

O

3

PS 394.05

Bromophos -methyl 2104-96-3 C

8

H

8

BrCl

2

O

3

PS 366.00

Cadusafos 95465-99-9 C

10

H

23

O

2

PS

2

270.39 Chlorfenvinphos

(cis e trans) 470-90-6 C

12

H

14

Cl

3

O

4

P

359.57

(2)

Chlorpyrifos 2921-88-2 C

9

H

11

Cl

3

NO

3

PS 350.59

Chlorpyrifos-methyl 5598-13-0 C

7

H

7

Cl

3

NO

3

PS 322.53

Demeton-S-methyl 919-86-8 C

6

H

15

O

3

PS

2

230.29 Demeton-S-

methylsulfon 17040-19-6 C

6

H

15

O

5

PS

2

262.29 Diazinon 333-41-5 C

12

H

21

N

2

O

3

PS 304.35

Dichlorvos 62-73-7 C

4

H

7

Cl

2

O

4

P 220.98

Dimefox 115-26-4 C

4

H

12

FN

2

OP 154.12

Dimethoate 60-51-5 C

5

H

12

NO

3

PS

2

229.26 Dioxabenzofos

(Salithion) 3811-49-2 C

8

H

9

O

3

PS

216.20

(3)

Disulfoton 298-04-4 C

8

H

19

O

2

PS

3

274.41 EPN 2104-64-5 C

14

H

14

NO

4

PS 323.3

Ethion 563-12-2 C

9

H

22

O

4

P

2

S

4

384.48 Ethoprophos 13194-48-4 C

8

H

19

O

2

PS

2

242.34 Fenamiphos 22224-92-6 C

13

H

22

NO

3

PS 303.36

Fenitrothion 122-14-5 C

9

H

12

NO

5

PS 277.2

Fensulfothion 115-90-2 C

11

H

17

O

4

PS

2

308.36

(4)

Fenthion 55-38-9 C

10

H

15

O

3

PS

2

278.33 Fonofos 944-22-9 C

10

H

15

OPS

2

246.33 Formothion 2540-82-1 C

6

H

12

NO

4

PS

2

257.27 Heptenophos 23560-59-0 C

9

H

12

ClO

4

P 250.6

Iprobenphos 26087-47-8 C

13

H

21

O

3

PS 288.34

Malathion 121-75-5 C

10

H

19

O

6

PS

2

330.36 Mecarbam 2595-54-2 C

10

H

20

NO

5

PS

2

329.37

(5)

Methamidophos 10265-92-6 C

2

H

8

NO

2

PS 141.13

Methidathion 950-37-8 C

6

H

11

N

2

O

4

PS

3

302.33 Mevinphos

(cis e trans) 7786-34-7

C

7

H

13

O

6

P 224.15

Monocrotophos

6923-22-4 C

7

H

14

NO

5

P 223.16

Naled (Dibrom e

Bromchlophos) 300-76-5 C

4

H

7

Br

2

Cl

2

O

4

P 380.78

Omethoate 1113-02-6 C

5

H

12

NO

4

PS 213.19

Oxydemeton-

methyl 301-12-2 C

6

H

15

O

4

PS

2

99.99 Parathion-ethyl 56-38-2 C

10

H

14

NO

5

PS 291.27

Parathion-methyl 298-00-0 C

8

H

10

NO

5

PS

263.21

(6)

Phenthoate 2597-03-7 C

12

H

17

O

4

PS

2

320.36 Phorate 298-02-2 C

7

H

17

O

2

PS

3

260.38 Phosalone 2310-17-0 C

12

H

15

ClNO

4

PS

2

367.81 Phosphamidon

(cis e trans) 13171-21-6 C

10

H

19

ClNO

5

P 299.72

Phoxim 14816-18-3 C

12

H

15

N

2

O

3

PS 298.30

Pirimiphos-methyl 29232-93-7 C

11

H

20

N

3

O

3

PS 305.33

Profenofos 41198-08-7 C

11

H

15

BrClO

3

PS

373.63

(7)

Prothiofos 34643-46-4 C

11

H

15

Cl

2

O

2

PS

2

345.25 Pyrazophos 13457-18-6 C

14

H

20

N

3

O

5

PS 373.36

Quinalphos 13593-03-8 C

12

H

15

N

2

O

3

PS 298.29

Ronnel

(Fenchlorphos) 299-84-3 C

8

H

8

Cl

3

O

3

PS 321.57

Terbufos 13071-79-9 C

9

H

21

O

2

PS

3

288.43 Tetrachlorvinphos 22248-79-9 C

10

H

9

Cl

4

O

4

P 365.96

Thionazin 297-97-2 C

8

H

13

N

2

O

3

PS

248.24

(8)

Tolclofos-methyl 57018-04-9 C

9

H

11

Cl

2

O

3

PS 301.13

Triazophos 24017-47-8 C

12

H

16

N

3

O

3

PS 313.31

Tributylphosphate 126-73-8 C

12

H

27

O

4

P 266.31

Trichlorfon 52-68-6 C

4

H

8

Cl

3

O

4

P 257.44

Vamidothion 2275-23-2 C

8

H

18

NO

4

PS

2

287.36 Glyphosate 1071-83-6 C

3

H

8

NO

5

P 169.07

Glufosinate-

ammonium 77182-82-2 C

5

H

15

N

2

O

4

P

198.16

(9)

3-(Methyl- phosphinico) propionic acid

15090-23-0 C

4

H

9

O

4

P 152.09

AMPA 1066-51-9 NH

2

CH

2

PO(OH)

2

111.04 GRUPO DOS ORGANOSULFURADOS

Nome CAS Fórmula/ Peso

molecular Estrutura

Aldicarb 116-06-3 C

7

H

14

N

2

O

2

S 190.26

Chinomethionate 2439-01-2 C

10

H

6

N

2

OS

2

234.30 Ethiofencarb 29973-13-5 C

11

H

15

NO

2

S 225.31

Ethofumesate 26225-79-6 C

13

H

18

O

5

S

286.34

O

CH₃ H₃C

O

CH2 CH3

O S O O H₃C

Methiocarb 2032-65-7 C

11

H

15

NO

2

S

240.34

(10)

Methomyl 16752-77-5 C

5

H

10

N

2

O

2

S 162.2

Oxamyl 23135-22-0 C

7

H

13

N

3

O

3

S 219.26

Pebulate 1114-71-2 C

10

H

21

NOS 203.34

GRUPO DOS ORGANOCLORADOS

Nome CAS Fórmula/ Peso

molecular Estrutura

Alachlor 15972-60-8 C

14

H

20

ClNO

2

269.77 Aldrin 309-00-2 C

12

H

8

Cl

6

364.9 Camphechlor

(Toxaphene) 232-283-3 C

10

H

10

Cl

8

414 (média)

Captan 133-06-2 C

9

H

8

Cl

3

NO

2

S 300.59

Chlordane

(alpha e gamma) 57-74-9 C

10

H

6

Cl

8

409.78

(11)

g-Chlordane 5103-74-2 C

10

H

6

Cl

8

409.7 -

Chlordimeform 6164-98-3 C

10

H

13

ClN

2

196.7 Chlorobenzene 108-90-7 C

6

H

5

Cl 112.56

Chlorobenzilate 510-15-6 C

16

H

14

Cl

2

O

3

325.19 Chlorothalonil

1897-45-6 C

8

Cl

4

N

2

265.91 DDD (TDE) (pp- DDD e op-DDD)

72-54-8 e 53-19-0

C

14

H

10

Cl

4

320.04 DDE (pp-DDE e op- DDE)

72-55-9 e 3424-82-6

C

14

H

8

Cl

4

318.03

C Cl

Cl

Cl C Cl

DDT

(pp-DDT e op-DDT)

50-29-3 e 789-02-6

C

14

H

9

Cl

5

Dichloran 99-30-9

Cl

2

C

6

H

2

(NO

2

)N H

2

207.01

(12)

Dieldrin 60-57-1 C

12

H

8

Cl

6

O 380.91

Diflubenzuron 35367-38-5 C

14

H

9

ClF

2

N

2

O

2

310.68 Dimethomorph

(cis e trans) 110488-70-5 C

21

H

22

ClNO

4

387.86 Diuron

330-54-1 C

9

H

10

Cl

2

N

2

O 233.09

Endosulfan

(alpha e beta) 115-29-7 C

9

H

6

Cl

6

O

3

S 406.95

Endosulfan sulfate 1031-07-8 C

9

H

6

Cl

6

O

4

S 422.92

Endrin 72-20-8 C

12

H

8

Cl

6

O 380.91

Endrin aldeyde 7421-93-4 C

12

H

8

Cl

6

O 380.91

Cl Cl Cl

O H

(13)

Endrin ketone 53494-70-5 C

12

H

8

Cl

6

O 380.91

Cl Cl

Cl Cl Cl O

Cl

Folpet 133-07-3 C

9

H

4

Cl

3

NO

2

S 296.56

HCH (BHC Tech)

(alpha, beta e delta) 608-73-1 C

6

H

6

Cl

6

290.83 Heptachlor 76-44-8 C

10

H

5

Cl

7

Heptachlor epoxide

B 1024-57-3 C

10

H

5

Cl

7

O 389.32

Hexabromobenzene 87-82-1 C

6

Br

6

551.49 Hexachlorobenzene 118-74-1 C

6

Cl

6

284.78 Iprodione 36734-19-7 C

13

H

13

Cl

2

N

3

O

3

330.17

(14)

Kit CLP Organochlorine

Pesticide Mix

47426U - -

Linuron 330-55-2 C

9

H

10

Cl

2

N

2

O

2

249.09 Methoxychlor 72-43-5 C

16

H

15

Cl

3

O

2

345.65 Metobromuron 3060-89-7 C

9

H

11

BrN

2

O

2

259.10 Metolachlor 51218-45-2 C

15

H

22

ClNO

2

283.79 Metoxuron 19937-59-8 C

10

H

13

ClN

2

O

2

228.68 Mirex 2385-85-5 C

10

Cl

12

545.54 Monolinuron 1746-81-2 C

9

H

11

ClN

2

O

2

214.65 Monuron 150-68-5 C

9

H

11

ClN

2

O

198.65

(15)

Nitrofen 1836-75-5 C

12

H

7

Cl

2

NO

3

284.09 GRUPO DOS ORGANONITRADOS

Nome CAS Fórmula/ Peso

molecular Estrutura

Benfluralin 1861-40-1 C

13

H

16

F

3

N

3

O

4

335.28 Butralin 33629-47-9 C

14

H

21

N

3

O

4

276.18 Dinocap

(4 e 6) 39300-45-3 C

18

H

24

N

2

O

6

364.39 Flumetralin 62924-70-3 C

16

H

12

ClF

4

N

3

O

4

421.74 Isopropalin 33820-53-0 C

15

H

23

N

3

O

4

309.36

(16)

Pendimethalin 40487-42-1 C

13

H

19

N

3

O

4

281.31 Trifluralin 1582-09-8 C

13

H

16

F

3

N

3

O

4

335.32 GRUPO DOS PIRETRÓIDES Nome CAS Fórmula/ Peso

molecular

Estrutura

Bifenthrin 82657-04-3 C

23

H

22

ClF

3

O

2

422.87 Cyfluthrin (alpha, beta, gamma

e delta)

68359-37-5

C

22

H

18

Cl

2

FNO

3

434.29 Lambda-cyhalothrin 91465-08-6 C

23

H

19

ClF

3

NO

3

449.85 Cypermethrin (alpha, beta, gamma

e delta)

52315-07-8 C

22

H

19

Cl

2

NO

3

416.30 Deltamethrin

52918-63-5 C

22

H

19

Br

2

NO

3

505.20

(17)

Fenvalerate 51630-58-1 C

25

H

22

ClNO

3

419.90 Flucythrinate (cis e trans)

70124-77-5 C

26

H

23

F

2

NO

4

451.46 Permethrin

(cis e trans) 52645-53-1 C

21

H

20

Cl

2

O

3

391.29 GRUPO DOS EDB’S Nome CAS Fórmula/ Peso

molecular Estrutura Dibromochloropropa

ne DBCP

96-12-8 C

3

H

5

Br

2

Cl 236.33

Ethylene dibromide 106-93-4 C

2

H

4

Br

2

1,2,3-

Trichloropropane 96-18-4 C

3

H

5

Cl

3

147.50

(18)

GRUPO DAS MOLÉCULAS NEUTRAS

Nome CAS Fórmula/ Peso

molecular Estrutura

Aminocarb 2032-59-9 C

11

H

16

N

2

O

2

208.26 Baygon

(Propoxur) 114-26-1 C

11

H

15

NO

3

209.24 Benalaxyl 71626-11-4 C

20

H

23

NO

3

325.40 Carbaryl 63-25-2 C

12

H

11

NO

2

201.22 Carbendazim 10605-21-7 C

9

H

9

N

3

O

2

191.19 Carbofuran 1563-66-2 C

12

H

15

NO

3

221.25

(19)

Diphenamid 957-51-7 C

16

H

17

NO 239.32

Metalaxyl 57837-19-1 C

15

H

21

NO

4

279.33 Methoprene 40596-69-8 C

19

H

34

O

3

Napropamid 15299-99-7 C

17

H

21

NO

2

271.35 Oxadixyl 77732-09-3 C

14

H

18

N

2

O

4

278.31 Piperonyl butoxide 51-03-6 C

19

H

30

O

5

338.44 Pirimicarb

23103-98-2 C

11

H

18

N

4

O

2

238.29

(20)

Pyrethrins

(6 isômeros) 8003-34-7 Mistura de isômeros

GRUPO DOS ORGANOÁCIDOS

Nome CAS Fórmula/ Peso

molecular Estrutura

4-Br-Benzoic Acid 586-76-5 C

7

H

5

BrO

2

201.02 4-Br-Benzoic methyl

ester 619-42-1 BrC

6

H

4

CO

2

CH

3

215.04 Chlorthal 2136-79-0 C

8

H

2

Cl

4

O

4

303.91 Chlorthal dimethyl 1861-32-1 C

10

H

6

Cl

4

O

4

331.97 2,4-D 94-75-7 C

8

H

6

Cl

2

O

3

221.04

(21)

2,4-D methyl ester 1928-38-7 C

9

H

8

Cl

2

O

3

235.06 Dicamba 1918-00-9 C

8

H

6

Cl

2

O

3

221.04 Dicamba methyl

ester 6597-78-0 C

9

H

8

Cl

2

O

3

235.06 2,4,5-T 93-76-5 C

8

H

5

Cl

3

O

3

255.49 2,4,5-T methyl ester 1928-37-6 C

9

H

7

Cl

3

O

3

269.51 GRUPO DOS ALCALÓIDES

Nome CAS Fórmula/ Peso

molecular Estrutura

(R,S) Anabasine 494-52-0 C

10

H

14

N

2

160.22 (R,S) Anatabine 2743-90-0 C

10

H

12

N

2

160.21 Myosine 532-12-7 C

9

H

10

N

2

146.20 Nicotine 54-11-5 C

10

H

14

N

2

162.23

(22)

Nornicotine 5746-86-1 C

9

H

12

N

2

148.20 GRUPO DOS OUTROS

Nome CAS Fórmula/ Peso

molecular Estrutura

Thiamethoxam 153719-23-4 C

8

H

10

ClN

5

O

3

S 291.71

Azoxystrobin 131860-33-8 C

22

H

17

N

3

O

5

403.4 Biphenyl 92-52-4 C

12

H

10

154.21 Fipronil 120068-37-3 C

12

H

4

Cl

2

F

6

N

4

OS 437.15

Iminodibenzyl 494-19-9 C

14

H

13

N

195.26

(23)

Maleic hydrazide 123-33-1 C

4

H

4

N

2

O

2

112.09 Pyraclostrobin

175013-18-0 C

19

H

18

ClN

3

O

4

387.82 Triflumuron 64628-44-0 C

15

H

10

ClF

3

N

2

O

3

358.70 Cyproconazole 94361-06-5 291.78

Tebuconazole 107534-96-3 307.82

Rotenone 83-79-4 394.42

Clothianidin 210880-92-5 249.68

Teflubenzuron 83121-18-0 381.11

Fluopicolide 239110-15-7 383.58

(24)

Iprovalicarb 140923-17-7 320.43

Propamocarb 24579-73-5 182.27

Clomazone 81777-89-1 C

12

H

14

ClNO

2

239.70 Imidacloprid 138261-41-3 C

9

H

10

ClN

5

O

2

255.66 Thiamethoxam 153719-23-4 C

8

H

10

ClN

5

O

3

S 291.71

GRUPO DOS HALOFENÓIS

Nome CAS Fórmula/ Peso

molecular Estrutura

2,4-DIBROMOANISOLE

21702- 84-1

Br

2

C

6

H

3

OCH

3

265.94

2,4-DIBROMOPHENOL

615-58-7 C

6

H

4

Br

2

O 252.00 2,4-Dibromofenol

Acetilado - - -

PENTACHLOROANISOLE

1825-21- 4

C

7

H

3

Cl

5

O

280.35

(25)

PENTACHLOROPHENOL

87-86-5 C

6

HCl

5

O 266.34

Pentaclorofenol

Acetilado - - -

2,4,6-

TRIBROMOANISOLE

607-99-8 C

7

H

5

Br

3

O 344.83

2,4,6-

TRIBROMOPHENOL

118-79-6 Br

3

C

6

H

2

OH 330.82 2,4,6-Tribromofenol

Acetilado - - -

2,4,6-

TRICHLOROANISOLE

87-40-1 C

7

H

5

OCl

3

211.48

2,4,6-

TRICHLOROPHENOL

88-06-2 C

6

H

2

Cl

3

OH 197.45

2,4,6-Triclorofenol

Acetilado - - -

GRUPO DOS PCB’s Nome CAS Fórmula/ Peso

molecular Estrutura

2,3,4,4’-

Tetrachlorobiphenyl

33025- 41-1

C

12

H

6

Cl

4

291.99 WHO/NIST/NOAA

Congener List - - -

(26)

GRUPO DAS NITROSAMINAS

Nome CAS Fórmula/ Peso

molecular Estrutura

Cafeína - - -

N-Nitrosoanabasine 37620-20-5 C

10

H

13

N

3

O 191.23

N

N NO

N-Nitrosoanatabine 71267-22-6 C

10

H

11

N

3

O 189.22

N

N NO

N-Nitrosoguvacoline 55557-02-3 170.07 -

N-Nitrosonornicotine 16543-55-8 C

9

H

11

N

3

O 177.20

N

N NO

4-methylamino-1-(3- pyridyl)-1-butanone- 1-dihidroxychloride

- - -

4-methyl- nitosoamino-1(3- pyridil)-1 butanone

- C

10

H

13

N

3

O

2