Analysis of phenolic compounds in Tropaeolum majus L. processed by ionizing radiation

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Program

Abstract Book

Edited by

Marina B. A. VASCONCELLOS

4th Inter

nat

ional N

uc

lear C

hemist

ry Cong

ress

14 – 19

September

2014

, Mar

esias,

S

ão P

aulo

, Br

azil

4th International Nuclear Chemistry Congress

14 – 19 September 2014, Maresias, São Paulo, Brazil

4th International Nuclear Chemistry Congress

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SUMMARY

Committee ...06

Promotion and Sponsors ...07

General Information ...08

Program ...10

Invited Speakers ...12

Detailed Program ...14

Poster Session ...18

Abstracts ...31

Invited Speakers...33

Oral Session ...45

Poster Session ...119

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6 COMMITTEE

Chair:

Marina Beatriz Agostini Vasconcellos

|

IPEN - CNEN/SP

Co-Chair:

Turan Ünak

|

Emeritus of Ege University, Izmir, Turkey

President of the International Nuclear Chemistry Society

Local Committee:

Ana Maria Graciano Figueiredo

|

IPEN - CNEN/SP

Casimiro J. S. Munita

|

IPEN- CNEN/SP

Déborah I. T. Fávaro

|

IPEN - CNEN/SP

Edson Gonçalves Moreira

|

IPEN - CNEN/SP

Maria José Armelin

|

IPEN - CNEN/SP

Mitiko Saiki

|

IPEN - CNEN/SP

Paulo S. Cardoso da Silva

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IPEN - CNEN/SP

Vera Akiko Maihara

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IPEN - CNEN/SP

Almir Faria Clain

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IRD - CNEN/RJ

Barbara Mazzilli

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IPEN - CNEN/SP

Elvis Joacir de França

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CRCN/NE/PE

Maria Ângela de Menezes

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CDTN - CNEN/MG

International Scientific Board:

Aleksander Bilewicz

|

Poland

Amares Chatt

|

Canada

Boris L. Zhuikov

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Russia

Borut Smodis

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Slovenia

Chai Zhifang

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China

Eduardo Cortes Toro

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Chile

Flavia Groppi

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Italy

James D. Â Navratil

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USA

João Osso Junior

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Austria

Kattesh V. Katti

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USA

Manuel Navarrete

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Mexico

Maria do Carmo Freitas

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Portugal

Maria Helena Sampa

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Brazil

Mathias Rossbach

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Germany

Namik K. Aras

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Turkey

Panagiotis Misaelides

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Greece

Rita Pla

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Argentina

Robert Parr

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Austria

Rolf Zeisler

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USA

Simon Jerome

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UK

Suresh K. Aggarwal

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India

Tibor Braun

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Hungary

Turan Ünak

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Turkey

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POSTER SESSION

1 -

SEP 16 | Tuesday

eduCATioN iN NuCleAR ChemiSTRy

neutron actiVation analysis and its aPPlication to deterMine the concentration of eleMents in coMPleX Matrices

Valerian LoBo1_,1_{Wollo University ...123} KnoWledge aBout nuclear energy and radioactiVity of senior high school students

Aline Sabastiane Gonçales Ramos de oLIVEIRA1_{, Lucio LEoNARDo}1-2_{, Sandra Regina DAMATTo}1_,1_{Laboratório de Radiometria Ambiental - Instituto de} Pesquisas Energéticas e Nucleares (IPEN / CNEN) São Paulo, SP, 2 _{Universidade Paulista - UNIP ...124}

NuCleAR ANd RAdioChemiSTRy

MechanisM of uo₂(no₃)₂×6h₂o decoMPosition under MicroWaVe irradiation

Sergey A. kULYUkHIN1_,1_{Institute of Physical Chemistry and Electrochemistry, Russian Academy of Science ...127} sorPtion of uo22+ on sorBents Based on Modified silica gel containing cu, ni, and Zn froM aQueous solutions

Sergey A. kULYUkHIN1_{, Margarita P. GoRBACHEVA}1_,1_{frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Science ...128} forMation of nitrogen oXides during uraniuM nitride dissolution in nitric acid

Alexei A. BESSoNoV1_{, Sergey A. kULYUkHIN}2_{, Andrey Yu. SHADRIN}3_{, Yulia A. VoSkRESENSkAYA}4_{, oleg A. USTINoV}5_,1_{frumkin Institute of} Physical Chemistry and Electrochemistry, Russian Academy of Science, 2_{IOpen joint-stock company VNIINM ...129} aBsorPtion of nitrous oXide in aQueous solutions of gas cleaning systeM in technological scheMes of un dissolution

Sergey A. kULYUkHIN1_{, Andrey Yu. SHADRIN}2_{, Alexei A. BESSoNoV}1_{, Yulia A. VoSkRESENSkAYA}2_{, oleg A. USTINoV}2, _,1_{frumkin Institute of} Physical Chemistry and Electrochemistry, Russian Academy of Science, 2_{IOpen joint-stock company VNIINM ...131} np(V)-Phenanthroline-dicarBoXylic acid coMPounds:

synthesis, structure, ProPerties

Alexei A. BESSoNoV1_{, A.B. YUSoV}1_{, I. A. CHARUSHNIkoVA}1_{, A. M. fEDoSSEEV}1_,1_{frumkin Institute of Physical Chemistry and Electrochemistry, Russian} Academy of Sciences ...133 uranyl nitrate hydrolytic BehaVior in the Presence of reductant

Alexei A. BESSoNoV1_{, A.M. fEDoSSEEV}1_{, Y.M. kULYAko}2_{, S.A. PEREVALoV}2_{, A.Yu. SHADRIN}3_,1_{frumkin Institute of Physical Chemistry and} Electrochemistry of RAS, 2_{Vernadsky Institute of Geochemistry and Analytical Chemistry of RAS,}3_{Open joint-stock company VNIINM ...134}

NuCleAR ANd RelATed TeChNiqueS

crystalline structure and oXygen stoichioMetry of the Ba_0.50sr_0.50co_0.80fe_0.20o_3-d PoWders oBtained By edta-citrate Method Measured By X-ray and neutron diffraction

Everton BoNTURIM1_{, Nelson Batista de LIMA}1_{, Vera Lúcia MAzzoCCHI}1_{, Carlos Benedicto Ramos PARENTE}1_{, José MESTNIk fILHo}1_{, Emília Satoshi} Miyamaru SEo1_,1_{Instituto de Pesquisas Energéticas e Nucleares IPEN-CNEN/SP ...137} eValuation of a 99m_{tc coMPleX as an oil MultiPhase radiotracer}

Martha Sahylí ortega PIJEIRA1_{, Judith DoMÍNGUEz}1_{, Jorge L. BATISTA}1_{, Yuniel TEJEDA}1_{, Ernesto Martínez BAEz}1_{, Jorge Borroto PoRTELA}1_, 1_{Department of Radiochemistry, High Institute of Applied Sciences and Technologies ...138} Variations on uo2-doPed and undoPed fuel Pellets Microstructures By the addition of recycled Material

Diogo Ribeiro CoSTA1_{, franciole José EzEQUIEL}1_{, Rodrigo Aparecido BARBoSA}1_{, João Paulo Rodrigues CARNAVAL}1_,1 _{Brazilian Nuclear Industries} (Indústrias Nucleares do Brasil S.A.– INB) ...139 heterogeneity eValuation of uo2 Pellets to Be used in a BraZilian MeasureMents systeMs intercoMParison

PrograMs

Bárbara fernandes Gonçalves CRISTIANo1_{, José Ubiratan DELGADo}1_{, José Wanderley S. da SILVA}1_{, Aline Gonzalez VIANA}1_{, fábio Cordeiro DIAS}1_, Marcos Sodre GRUND1_{, Ricardo Tadeu LoPES}1_,1_{Comissão Nacional de Energia Nuclear (CNEN), Instituto de Radioproteção e Dosimetria (IRD/CNEN) ..140} concePtion and construction of a reMote ProBe for a PortaBle sPectroMeter using the energy disPersiVe X-ray fluorescence tecniQue

francisco Antonio BRANDão Junior1-2_{, Arno Heeren de oLIVEIRA}1_{, Antonella LoMBARDI Costa}1_,1_{Departamento de Engenharia Nuclear, Universidade} federal de Minas Gerais, 2_{Centro federal de Educação Tecnológica de Minas Gerais (CEfETMG) ...141}

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21

MaJor eleMental features of a Portuguese Bread-Wheat archiVal collection, deterMined By instruMental neutron actiVation analysis

Catarina Isabel Alves Lourenço GALINHA1-2-4_{, Adriano M. G. PACHECo}2_{, Maria do Carmo fREITAS}1_{, Ana R. P. CoSTA}3_{, Nuno M. B. PINHEIRo}3_, Benvindo MAçãS3_{, Ana Sofia ALMEIDA}3_{, Hubert T. WoLTERBEEk}4_,1_{URSN/CTN-IST, University of Lisbon,}2_{CERENA-IST, University of Lisbon,} 3_{INIAV, National Institute of Agricultural and Veterinary Research, Savavém,}4_{Department of Radiation Science and Technology, faculty of Applied Sciences,} Delft University of Technology Portugal ...177

RAdiATioN ChemiSTRy

iMProVeMent in the radiation staBility of ePdM/incorPorated ePdM PoWder/carBon BlacK coMPound Ludmila de Ysasa Pozzo kIYAN1_{, Traian zAHARESCU}2_{, Duclerc fernandes PARRA}1_{, Ademar Benévolo LUGão}1_,1_{IPEN, Center of Chemistry and} Environment, 2_{INCDIE ICPE CA, Department of Advanced Materials ...181} siMultaneous use of anion eXchanger and sr resin for efficient strontiuM isolation froM coMPleX Matrices Gorana KArANOVIć1_{, Ivana MILANOVIć}1_{, Željko GrAHEK}1_,1_{ruđer Bošković Institute ...182} eValuation of Physico-cheMical ProPerties and Biodegradation of PolyMeric MeMBranes Based chitosana, starch, and PolyVinylPyrrolidone (PVP) synthesiZed By gaMMa radiation at different doses and dose rates Jorge gabriel dos santos Batista1_{, ana carolina Moreira fonseca}2_{, ademar Benévolo lugão}3_,1_{Instituto de Pesquisas Energéticas e Nucleares} (IPEN / CNEN - SP) ...183 effect of γ-irradiation on radical scaVenging, reducing PoWer and liPid PeroXidation inhiBition ProPerties of hydroalcoholic eXtracts froM MALVA NEGLECTA

José Virgílio Santulhão PINELA1-2_{, Amilcar L. ANToNIo}1-3_{, Lillian Bouçada de BARRoS}1_{, Ana M. CARVALHo}1_{, M. Beatriz P. P. oLIVEIRA}2_{, Isabel C. f.} R. fERREIRA1_,1_{Centro de Investigação de Montanha (CIMo), ESA, Instituto Politécnico de Bragança,}2_{REQUIMTE/Departamento de Ciências Químicas,} faculdade de farmácia, Universidade do Porto, 3_{Centro de Ciências e Tecnologias Nucleares, IST, Universidade de Lisboa ...184} analysis of Phenolic coMPounds in Tropaeolum majus l. Processed By ioniZing radiation

Amanda Cristina Ramos koIkE1-2_{, João C. M. BARREIRA}2_{, Lillian BARRoS}2_{, Celestino SANToS-BUELGA}3_{, Anna Lucia C. H. VILLAVICENCIo}1_, Isabel C. f. R. fERREIRA2_,1_{Instituto de Pesquisas Energéticas e Nucleares (IPEN - CNEN/SP),}2_{Centro de Investigação de Montanha (CIMo), ESA, Instituto} Politécnico de Bragança, 3_{Grupo de Investigación en Polifenoles (GIP-USAL), faculty of Pharmacy, University of Salamanca ...185} iMPact of gaMMa irradiation on cheMical coMPosition of MELISSA OffICINALIS l.

Eliana PEREIRA1-2_{, Amanda Cristina Ramos koIkE}3_{, Amilcar L. ANToNIo}1-4_{, Lillian BARRoS}1_{, Isabel C. f. R. fERREIRA}1_,1_{Mountain Research Centre} (CIMo), ESA, Polytechnic Institute of Bragança, 2_{GIP-USAL, faculty of Pharmacy, University of Salamanca,}3_{Instituto de Pesquisas Energéticas e Nucleares} (IPEN/CNEN-SP), 4_{Centro de Ciências e Tecnologias Nucleares, IST, Universidade de Lisboa ...186} influence of antioXidant loading on the γ-eXPosure of ethylene-ProPylene terPolyMer

Heloísa Augusto zEN1_{, Traian zAHARESCU}2_{, Mariana Mădălina MARINESCU}2_{, Sandra Regina SCAGLIUSI}1_{, Elizabeth Carvalho Leite CARDoSo}1_, Ademar Benevolo LUGão1_,1_{IPEN, Center of Chemistry and Environment,}2_{INCDIE ICPE CA, Department of Advanced Materials...187} therMal resistance of ePdM/iir systeMs under γ-irradiation

Sandra Regina SCAGLIUSI1_{, Traian zAHARESCU}2_{, Heloísa Augusto zEN}1_{, Elizabeth Leite Carvalho CARDoSo}1_{, Silviu JIPA}3_{, Ademar Benévolo LUGão}1_, 1_{IPEN, Center of Chemistry and Environment,}2_{INCDIE ICPE CA, Department of Advanced Materials,}3_{University of Valachia, faculty of Science and Arts ... 188}

RAdioeColoGiCAl ANd GeoChemiSTRy

rn-222 and staBle isotoPes as a natural tracer in groundWater-surface Water interactions at the artificial recharge systeM

Yoon Yeol YooN1_{, kil Yong LEE}1_{, Soo Young CHo}1_{, kyu Chul HA}1_,1_{Geologic Environment Division, korea Institute of Geoscience and Mineral Resources} (kIGAM) ...191 the contriBution of Mining actiVities on anthroPogenic inPut of cu, Pb and Zn in the cananÉia-iguaPe systeM keila Modesto TRAMoNTE1_{, Paulo Alves de Lima fERREIRA}1_{, Andreza Portella RIBEIRo}1-2_{, Rubens César Lopes fIGUEIRA}1_{, Michel Michaelovitch} de MAHIQUES1_,1_{Instituto Oceanográfico da Universidade de São Paulo,}2_{Universidade Nove de Julho (UNINoVE), Mestrado de Gestão Ambiental e} Sustentabilidade ...192 sediMentation Processes in the seMi-enclosed Bay deduced froM Vertical Profiles of 137_{cs Massic actiVities}

(KaŠtela Bay, adriatic sea, croatia)

Ivanka Lovrenčić MIkELIC1_{, Višnja OrEŠČANIN}2_{, Krunoslav ŠKArO}3_{, Delko BArIŠIć}1_,1_{Laboratory for Radioecology, Division for Marine and}

Environmental research, ruđer Bošković Institute, 2_{Advanced Energy Ltd,}3_{Hydrographic Institute of the Republic of Croatia, oceanographic Department ... 193} statiscal analisys of discrePants radioecological data using Monte carlo BootstraP Method

Arykerne Nascimento Casado da SILVA1_{, Romilton dos Santos AMARAL}1_{, José Wilson VIEIRA}1_{, José Araújo dos SANToS Júnior}1_,1_{Nuclear Energy} Department of federal University of Pernambuco ...194 a 10-year record of seasonal Variation of 7_{Be in Particulate Matter and Plants of cerrado BioMe, BraZil}

Bruno Burini Robles ARINE1_{, Marco Antonio Proença Vieira MoRAES}1_{, André Luis Lima de ARAúJo}1_,1_{Centro Tecnológico da Marinha em São Paulo -} Laboratório Radioecológico ...195

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4

th

_{-INCC 2014 I 4}

th

_{International Nuclear Chemistry Congress}

analysis of Phenolic coMPounds in Tropaeolum majus l. Processed By

ioniZing radiation

amanda cristina ramos KoiKe

1-2

_{, João c. M. Barreira}

2

_{, lillian Barros}

2

_{, celestino}

santos-Buelga

3

_{, anna lucia c. h. VillaVicencio}

1

_{, isabel c. f. r. ferreira}

2

1

_{Instituto de Pesquisas Energéticas e Nucleares (IPEN - CNEN/SP),}

2

_{Centro de Investigação de Montanha (CIMO), ESA, Instituto}

Politécnico de Bragança,

3

_{Grupo de Investigación en Polifenoles (GIP-USAL), Faculty of Pharmacy, University of Salamanca,}

São Paulo, Brazil, amandaramosk@gmail.com

Tropaeolum majus L. (garden nasturtium) is an ornamental plant that belongs to Tropaeolaceae family, native

to South America in the Andes and that is widely distributed around the world. Its flowers are extensively

used in food preparations and have strong spicy flavours as watercress, being also acknowledged for their

antioxidant properties and high content of phenolic compounds [1, 2]. The use of edible flowers as food

ingredients requires new approaches to improve conservation and safety. The extension of post-harvest

storage, preserving the quality of the plants, will benefit the industrial development [3]. Food irradiation

is a method that can be used for the extension of shelf life of perishable commodities and to increase food

safety [4]. The purpose of this study was to evaluate the dose-response effects of gamma and electron

beam irradiation (doses of 0, 0.5, 0.8 and 1 kGy) on the phenolic profile of garden nasturtium, using

HPLC-DAD-ESI/MS. Kaempferol-O-hexoside-O-hexoside was the most abundant compound

in all the studied samples (8 and 14 mg/g of extract, after gamma and electron beam irradiation,

respectively), followed by 5-O-caffeoylquinic acid (2.3 mg/g for both irradiation technologies) and

3-O-caffeoylquinic acid (2.2 and 2.0 mg/g for gamma and electron beam irradiation, respectively).

Regarding anthocyanins, pelargonidin-3-O-sophoroside and delphinidin-O-dihexoside were the most

abundant compounds (4 and 2 μg/g, respectively, after both types of irradiation). According to the obtained

results, the applied irradiation treatments seemed feasible technologies to keep the phenolic composition

and preserve the quality of edible flower petals and might be useful to expand the post-harvest storage,

preserving the quality of T. majus.

Acknowledgments: FCT- Portugal for financial support to CIMO (strategic project PEst-OE/AGR/

UI0690/2011), João C.M. Barreira (SFRH/BPD/72802/2010 grant) and L. Barros (“Compromisso para

a Ciência 2008” contract). The GIP-USAL is financially supported by the Spanish Government through

the Consolider-Ingenio 2010 Programme (FUN-C-FOOD, CSD2007-00063). This research is included in

a Bilateral action FCT-CNPq, Portugal/Brazil 2014 and CNEN, CAPES, CNPq and IPEN-CNEN/SP for

financial support to Amanda Koike.

references

1) Creasy, R. The Edible Flowers Garden. Periplus Editions, Boston (1999).

2) Garzón, G.A. and Wrolstad R.E. Food Chemistry, 114, (2009) 44-49.

3) Rop, O., Mlcek, J., Jurikova, T., Neugebauerova, J., Vabkova, J. Molecules, 17, (2012). 6672-6683.

4) Farkas, J. Trends in Food Science and Technology, 17, (2006) 148-152.