Estudos espectroscópicos de materiais metal-orgânicos baseado em íons lantanídeos
Texto
(2) . .
(3). . .
(4) .
(5) . !"#!$% ! & "'&()%. %$)*! *(+($% ! $(,".
(6)
(7) . .
(8). . !"#$ % !%&!' $ (!$)*+% ' ),'-. .%'% !# $%. !/)--#% ! %0#"*+% $ #,#)1% $ %)#%! ' ),'-.2. 1)"%3 !.1% 1-4-! %$!-&). !-"#$%!3 4!-"% 14 56"-%! 7 -10!#% 2 $ 8. &9".- -"".-$%!3 /. .-:. )#)0!%; <=>=. . .
(9) .
(10)
(11) .
(12) !"
(13) #
(14) $! !
(15) !%
(16) !&%!
(17)
(18) !
(19) ' !!
(20) !
(21) ( ! (
(22) !)"
(23) #
(24)
(25) !
(26)
(27) *+ ,,-. * #
(28) *
(29)
(30) +
(31) !/0 1
(32) 2
(33) 3
(34) !
(35) 45 67
(36) !
(37) 2
(38)
(39)
(40) 8
(41) $9: ( ;
(42) , : ( ' < (
(43) !=<
(44) ! > %!!
(45)
(46) ;+
(47) !/0
(48)
(49) ;;1
(50) 2
(51) ;;;3( ?@4
(52) 62:.
(53)
(54) . .
(55) . . . .
(56)
(57) . !" !#$ ! %
(58) &'$ ! ()
(59) *$ (!"$ + , -.
(60) /0
(61) " !1$ ! )
(62) -.
(63) /0
(64) " !1$ ! / -.
(65) /01$ ( -. (!
(66) 1$ 23 -. (!
(67) 1$ (! /3 -. 1 + ! -. 1) 4 # !5 /
(68) ! -. 1$
(69) 4 6!! -. 1$ + -!1$
(70) ! -7 1$ ( - (1$ !* -/!8!1$ 34 -
(71) #9!:981$ ( - ; <1$ !$ -=%# 21$
(72) ! 3 ! -! !1) / % # >! %!). . .
(73) "&!. -$.# # %-$.#% #" ! -)#$!)/-()! +E$(! %#$(%(. #%*$,O.()! AC )!.#. ! '!. *%.#%.' ! #E (+( ( % & #$8. )%-'#"*!4 %-'#"*! = (.#(#"*% !5 L! *%,& #" ! -)#$!)/-()! . %#$(%( #%*!$,O.()! )!.#. ! '!.
(74) %.#%.' !M: & 2" $E. %-$.#% % % '.# D( $!#$&%*: )%$%)#$(G%01! #" ! -)#$!)/-()!. #/$()!PB-$(&.#(%(. #$8
(75) A
(76) %.#D%.( $,%.() $%&K!$JC "%. !. )!&! ).#$! &#E*()! ! '!. "QR: 3QR . QR ! E)(. S
(77) .;A
(78)
(79) CAH;CTU A!.
(80) .QRV "QR: 3QR !". . QR :. ! &*'#()! A
(81)
(82) C5. .#1! (,.% ! )!&!. A=4=C: A=4;C . A=4QC: $-)#(+%&.#4. )%-'#"*! ;: (.#(#"*% ! L $!)! . $%.9$8.)(%. .$,(%. (.?$,()! & !*'&$!. !!$ .%01!. H#$!3(&#E*()! )!.#. !
(83) %.#%.' !M: $-!$#% % "&% (.+#(,%01! #%*D% %. ! -$!)! #$%.9$8.)(% .$,(%.
(84) (,%.#W#%* #%*W#%* &. !( -!*'&$! )!!$ .%01! (!#$"#"$%(: XSA3=B"BCA CAH CU: !. . H; ? ! E)( ! (-()!*'.()! B V <:<Y <:Y $-)#(+%&.#4 )%-'#"*! Q:. (.#(#"*% ! L'.# #" ! /$()! B-$(&.#%*. % $!-$( % . -)#$!)/-()% !&-!#! (9!9!.%#! )!&
(85) %.#%.' !M: &!#$% %. '.#. )%$%)#$(G%01!. . #" !. S
(86) .AH-& CAH;CU: !.
(87) .QR V "QR AAQ4=C: . -)#$!)/-()!. !. QR A AQ4;C: 3QR AAQ4QC A". &%#$(%(. QR <:<Y3<:ZYC. AQ4[C\ H[-& % ? ! E)( ! =:[ .(*3(A&#(*.!C (9!9!.()!4. . Palavras Chaves: Lantanídeos, Luminescência, Compostos de Coordenação. .
(88) 3#$%)#. D -$.# #D( D!K -)#$!)!-() #" ( !9 (+$ #%*$,%.(). %#$(%* 3% !. *%.#D%.( (!.: 3(., (+( (. #D$ )D%-#$4 D 9($#:. .#(#* % L! *(.,: #$")#"$%* %. -)#$!)!-() #" ( !9
(89) %.#D%.( . $,%.() $%&K!$JM. %$ $-!$# #D DI $!#D$&%* I.#D(: )D%$%)#$(G%#(!.. %. #D!$#()%*PB-$(&.#%* -)#$!)!-() (.+#(,%#(!. !9 #D$ *%.#D%.( !$,%.() 9$%&K!$J &%#$(%* "(., % -$(&%$I 3"(* (., 3*!)J #D &#%**() ).#$. "QR: 3QR %. . QR%.. $( " !9 &**(#() %)( 5 S
(90) .;A
(91)
(92) CAH;CTU AKD$
(93) .QR. V "QR: 3QR R %. Q\ D$%9#$ (,.%# % AA=4=C: AA=4;C %. AA=4QCC4. D%-#$ ;:. .#(#* % LI.$,() .$,I $%.9$ $!) (. H#$!3(&#%**()
(94) %.#D%.( . !!$ (.%#(!. !*I&$M %$ BD(3(# %. #%(* (.+#(,%#(!. !9 #D.
(95) (,%. W#%* %. #%*W#%* .$,I #$%.9$ (. #K! (!#$")#"$%* ;. )!!$ (.%#(!. -!*I&$: XSA3=B"BCA CAH CU:. KD$. H; . ( -I$( (.. ;:T ()%$3!BI*() %)( %. B V <4<Y: %. <4Y< $-)#(+*I4 D )D%-#$ Q .#(#*. % LI.#D(: D!$#()%* %.. B-$(&.#%* -)#$!)!-() $!-$#( !9.
(96) %I$
(97) %.#D%.( (-D!-D!.%#M %$ D!K. #D I.#D(: )D%$%)#$(G%#(!.. %. -)#$!)!-() #" ( !9 -"$-D% !9
(98) .AH-& CAH;CU &%#$(%* SKD$.
(99) .QR V "QR AAQ4=C: . QR A AQ4;C: 3QR AAQ4QC %.. A"<4<Y3<4ZYCQR AAQ4[C\ H[-& % V =:[. -D.I*.3(A&#DI*.C (-D!-D!.() %)( AH[-& C4. . Keywords: Lanthanides, Luminescence, Coordination Compounds . .
(100)
(101) . $. !"#$%& '( )* "+ ,) ,- !./#% 0 1#2& # 0( )34 & !%567. +. !%)& $ 89 !% :7 !,% 1+7 ! %. :.
(102) ;7!%
(103) &<(&:"=#;& +>4 <' 6'? . =. (@AB *, 4 #;&! C,( ";DE;$E#;;%& : 89 * '' . D. 89&!% (9*F '<7!,% (9& =
(104) *'& H89-< 89I0. G +. &<(&$D& D& 89 -< 89
(105) < . H. &!%!,%,< 9 ,) 5 < , 6 7 ! % 3 , ) 5 <J < 89 7!%
(106) '' 89) 57!%!(%
(107) '',) 5<J <& &890 * &. $=. &# 3 . 89 * * . +G. K#!%!I#%=L" . < <)&. <8M <0F ' -"N")7 $E#-"N2E#"$E#)7 $E#-"NE#"$E#)&. . .
(108) (,"$% =4Q5 (#% %! *!.,!. ! (B! )$(#%*!,$E9()! ). % #$"#"$%. Y;. S
(109) .;A
(110)
(111) CAH;CTU:. +( .)(%. ! ! )%.%( DB%,!.%( !)"-% ! -*!. %2"%*(,%.#4 *(,%0`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
(112) .A CAH CU. % -$!a01! ).#$%*. #$"#"$%. !. ^T. %! *!.,! ! (B! )$(#%*!,$E9()! 3: +( .)(%. ! %. (#O.)(% (.#$&#E*()% &%( -$/B(&%4. !. ^_. (,"$% ;4[5 A%C &%,. &()$!)!-(% *#$F.()% &%-%&.#! -!$. ^Z. (,"$% ;4Q5 % $`. . (9$%01!. $%(!B. $"*#% ! 9(.%*. 9(.%&.#! (#+*. -%$% XSA3<:ZY"<:<YCA CAH CU4. !3#( % -%$% XSA3<:ZY"<:<YCA CAH CU:. A3C 3QRP"QR: A)C "QR . A C 3QR4. . .
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
(114) . =;=. (,"$% ;4; 5 "$+% #$&!,$%+(&?#$()% A C #$&!,$%+(&#$(%. =;;. (,"$%. ;4= 5. % $1!. . (9$%01!. . $%(!B. XSA3<:ZY"<:<YCA CAH CU4. $(+% %. AC5. A%C. XSA3<:ZY"<:<YCA CAH CU\. A3C. XSA3<:Y "<:YCA CAH CU4. (,"$%. ;4Q 5. -)#$!. XSA3<:ZY"<:<YCA CAH CU:. . .9$%+$&*D!. . XSA3<:Y"<:YCA CAH CU. . =;Q. XS3A CAH CU4. (,"$% ;4Q 5 ! XSA3<:ZY"<:<YCA CAH CU4. =;Y. (,"$% ;4[ 5 ! XSA3<:Y"<:YCA CAH CU4. =;T. (,"$% Q4=5 *"#$%01! ! -$!)! !3#.01! ! E)( ! =:[ .(*. =;Z. 3(A&#(*.!C (9!9!.()! % -%$#($ ! $(+% ! #$%#(*-B(*.! (9!9!.%#!4. (,"$% Q4;5 *"#$%01! % #$"#"$% ! S
(115) .AH-& CAH;CU +(#% %! *!.,! !. =Q_. (B! )$(#%*!,$E9()! %4. (,"$% Q4Q5 !*( $!. )!!$ .%01! b
(116) ._c. ! &%#$(%(. =Q^. S
(117) .AH-& CAH;CU4 -$%0` (&#$(% "% % -%$% ,$%$ E#!&!. 2"(+%*.#5 ;B: =I: G\ A((C QB: I: G\ A(((C ;B: I: G4. (,"$% Q4[5 % $1! (9$%01! $%(!B: $"*#% ! 9(.%* ! $9(.%&.#!. =QZ. (#+*. (&%,& -%$% AAQ4=C4. (,"$% Q4Y5 $%,&.#!. % #$"#"$% AQ4=C !#(&(G% % -*! ! *!. =[Q. -%$J*P Q % )!&-%$%01! .#$ ! -!*( $! )!!$ .%01! A G"*5. B-$(&.#%*\ $&*D!5 %*)"*% !C4. (,"$% Q4T5 -)#$! &(1! AAQ4;C % __ N4. =[[. (,"$% Q4_5 -)#$! B)(#%01! )!*#% ! % Q<< N5 A%C5 AQ4=C\. A3C5 AQ4QC4. =[Y. (,"$% Q4^5 -)#$! &(1! AQ4QC % Q<< N % (&%,& !. =[T. )!&-!$#%&.#! ! &%#$(%* !3 ($$% (%01! *"G 4. (,"$% Q4Z5 &-! +( % & 9".01! % #&-$%#"$% AAQ4QC % Q<< N. =[_. &!.(#!$%. ! % &(1! % #$%.(01! Y[W_ Y AY[Y .&C B)(#%01! &. . .
(118) ;TT .&4. (,"$% Q4=<5 -)#$! &(1! AQ4=C % T N % (&%,& !. =[Z. )!&-!$#%&.#! ! &%#$(%* !3 ($$% (%01! *"G 4. (,"$% Q4==5 &-! +( % A%C %B% )%(&.#! A3C !. =YQ. )!&-!#! AQ4=C & 9".01! % #&-$%#"$%: !3#( % -*! &!.(#!$%&.#!. % &(1! % #$%.(01! Y<W_ ; AT=< .&C B)(#%01! & ;TT .&4. (,"$% Q4=;5 A%C "$+% B)(#%01!\ A3C &-! B)(#%01! d A \ A)C. =Y[. %B% B)(#%01! d AJ$C )!&! 9".0` %. 9".01! % #&-$%#"$% -%$%. ! )!&-!#! AAQ4=C4. (,"$% Q4=Q5 !-"*%0` $*%#(+% ! #% ! B)(#% ! Y= Y< &. =YY. 9".01! % #&-$%#"$%4. (,"$% Q4=[5 (%,$%&% #$%.9$8.)(% .$,(% -%$% % #$"#"$%. =Y_. )%*)"*% % -*! &! *! -%$J*P Q -%$% ! )!&-!#! AAQ4=C4. (,"$% Q4=Y5 -)#$! B)(#%01! AAQ4[C !3#( ! +(% &!.(#!$%&.#!. =Y^. % #$%.(0` A%C Y[W_ Y & Y[Y.& ! 3QR A3C Y<W_ ; & T=< !. '!. "QR4. (,"$% Q4=T5 -)#$! &(1! AQ4[C !3#( ! +(% &!.(#!$%&.#!. =YZ. % #$%.(0` A%C Y[W_ Y & Y[Y.& ! 3QR A3C Y<W_ ; & T=< !. '!. "QR4. (,"$% Q4=_5 *"#$%01! % !3$-!(01! ! -)#$! %3!$01! !. =T=. "QR A+$&*D!C &(1! ! 3QR A+$ C !3#( % ! -)#$! !. &%#$(%( 2" )!.#?& =<<e ! '!. AAQ4=C AAQ4QC: $-)#(+%&.#4. (,"$% Q4=^5 &-! +( % & 9".01! % #&-$%#"$% !3 B)(#%01!. =TQ. & ;TT .&5 A%C 3QR f& V Y[Y .&\ A3C "QR f& V T=< .&4. (,"$% Q4=Z5 !-"*%0` $*%#(+% ! .'+( Y= A$&*D!C Y< A G"*C. =T[. & 9".01! % #&-$%#"$%4. (,"$% Q4;<5 A%C %B% A3C 9()(8.)(% #$%.9$8.)(% .$,(% !. =TY. -$!)! 3QRW "QR & 9".01! % #&-$%#"$%4. (,"$% Q4= 5 % $1! (9$%01! $%(!B ! &%#$(%( AQ4[C: AQ4QC . =__. AQ4;C (&%,. 4. . .
(119) (,"$% Q4; 5 "$+% #$&!,$%+(&?#$()% A C4. =_^. (,"$% Q4Q 5 -)#$! .9$%+$&*D! ! *(,%.# A%)(&%C !. =_Z. &%#$(%( S
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a"# % )"$+%4. . .
(121)
(122)
(123) . %3*% =4=4. % ! )$(#%*!,$E9()! . #%*D. ! $9(.%&.#!. AgC. O.,"*!. !. [Z. &. Y=. S
(124) .;A
(125)
(126) CAH;CTU4. %3*% =4;4. (#O.)(%. (.#$%#F&()%. . AhC. S
(127) .;A
(128)
(129) CAH;CTU4. %3*% =4Q4.
(130) (,%0` D( $!,8.(! & S
(131) .;A
(132)
(133) CAH;CTU: Ag h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` ! 3QR "QR & Y[; T=T .& #&-! B)(#%01! A$C. -%$% ! .'+* Y<. ! "QR & XSA3<:ZY" <:<YCA CAH CU4. . =;[. %3*% Q4=4 %*!$ -%$% % #(&%#(+% ."&?$()% ! -$!)! . =QT. %3*% ;4= 4 &-!. +( % & 9".01!. % #&-$%#"$%. XS3A CAH CU4. #$%.9$8.)(% .$,(%4. %3*% Q4;4. % ! )$(#%*!,$E9()! #%*D ! $9(.%&.#! (#+*. -%$% S
(134) .AH-& CAH;CU: !.
(135) .QR V "QR AQ4=C: . =QZ. QR AQ4;C: 3QR AQ4QC . A"<:<Y3<:ZYCQR AAQ4[C4. . .
(136) %3*% Q4Q4. (#O.)(% (.#$%#F&()% AgC O.,"*! A,$%"C *)(!.% !. =[=. -%$% ! %&3(.# )!!$ .%01! ! "QR &. AQ4=C4. %3*% Q4[4 !!$ .% % %#F&()% -%$% #$"#"$% )$(#%*!,$E9()% . =[Q. !#(&(G% % -*! &! *! -%$J*P Q A.#$ -%$8.#C ! 9%#!$ . )%$,% A,C -!*%G%3(*( % AiC !3#( ! -%$% AAQ4=C4. %3*% Q4Y4. %$O&#$! (.#.( % . j;: j[ jT: #%B% $% (%#(+% A $% C. =Y<. .1!$% (%#(+% A .$% C: 9()(8.)(% 2"O.#()% Ak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
(137)
(138)
(139) :
(140) . <. $! (&.(!.%*. =. &% (&.1!. ;. "% (&.`. Q. $8 (&.`. &-?$. . D &$()%& !)(#I 9!$ #(., %. %#$(%*. . G( !#(&( (.%. . =:[3.G.! ()%$3!B(*%#!. 3-I. (-($( (.%. . =:Q:Y3.G.!#$()%$3!B(*%#!. Q<<. "Q;. H. %$3!.!: .(#$!,8.(!: D( $!,8.(! .B!9$.
(141). (-!(#(+! !*)"*%$ !.+$!$
(142) "G. . (&#(*9!$&%&( %. . (&#(*"9/B( !.
(143). (! ! $,O.()! *#$!*"&(.).#. . (-()!*(.%#!. . $&!,$%+(&#$(% $(+% %. . .
(144) . .$,I (-$(+ %I -)#$!)!-I. . ".D!# ( " A' "! (-%$! %$&% 9!,!C. H; . l)( ! (-()!*'.()!. H;. l,"%. . !$#()"*%$ #%*!$,%.() $%&K!$J. . .9$%+$&*D!. N. N*+(.. N$. $!&#! -!#E(!.
(145) ..
(146) %.#%.' !.
(147)
(148). l)( ! &*'#()!. . ()$!)!-(% *#$F.()% %$$ "$%.
(149). %#$(%* ! .#(#"#!
(150) %+!(($. . %#$(%* &#%*!$,O.()!. . #%*!$,%.() $%&K!$J. . !*'&$! )!!$ .%01!. - ). Q:Y-($( (.% ()%$3!B(*%#!. . !$9($(.%. --&. %$# -!$ &(*D1!. -I ). Q:Y-($( (.% ()%$3!B(*%#!. . !.O.)(% %,.?#()% ")*%$. . .
(151) . $%.9$8.)(% .$,(%. . $&!,$%+(&#$(%. H. #$%D( $!#(!9.!. . *#$%+(!*#%. . !*#. H,. .F.(!&$)7$(!. . 7&$! &!*?)"*% -!$ )?*"*%. .. (.)!. .[. *"#$ G(.)!. . !.O.)(% %,.?#()% &%,&. H[-&. l)( ! =:[ .(*3(A&#(*.!C (9!9F.()!. . .
(152) l. . (+. . +. . +(.
(153) . +(((.
(154)
(155) . B(((.
(156)
(157) :
(158) . B+.
(159). 4 %#$(%( #%*$,O.()! AC m -)#! H(#/$()!. =. 4 '.# %#$(%( #%*$,O.()!. _. 4 -*()%01! %#$(%( #%*$,O.()!. ==. 4 9$8.)(%. =^.
(160) =5 ! *%,& #" ! -)#$!)/-()! %#$(%( #%*. QQ. !$,O.()! !.#. ! !.
(161) %.#%.' !. =4=.#$! "01!. Q[. =4; %#$(%( ?#! !. Q_. =4;4= %,.#. Q_. . .
(162). =4;4; $-%$%01! ! (#$%#!
(163) %.#%.' !. Q_. =4;4Q '.#. QZ. =4;4[ .#$"&.#%01!. [<. =4;4[4= .E*( *&.#%$. [<. =4;4[4; -)#$!)!-(% 3!$01! .% ,(1! ! .9$%+$&*D!. [<. =4;4[4Q $&!,$%+(&#$(% $&!,$%+(&#$(% $(+% %. [<. =4;4[4[ -)#$!)!-(%
(164) "&(.)8.)(%. [<. =4;4[4Y &-! )%(&.#! ! #% ! B)(#% !. [=. =4;4[4T . (&.#! "O.#()! &(1!. [=. =4;4[4_ (9$%01! %(!B !.!)$(#%*. [Q. =4;4[4^ %$O&#$! (.#.( % . [[. =4;4[4Z ! *%,&. [_. =4Q4 "*#% ! ()"1!. [_. =4Q4= #$"#"$% $(#%*!,$E9()% #(&(G%01! +(% -%$J*P =. [_. =4Q4; $!-$( % -)#$!)/-()%. Y[. =4[ !.)*"1!. T[. =4Y 9$8.)(%. TY. =. _Y.
(165) ;5 $!)! $%.9$8.)(%. . .$,(% (.?$,()! &. .
(166) !*'&$! !!$ .%01! H#$!3(&#E*()! )!.#. !
(167) %.#%.' !. ;4=.#$! "01!. _Z. ;4; %#$(%( ?#! !. ^=. ;4;4= %,.#. ^=. ;4;4; '.#. ^=. ;4;4Q .#$"&.#%01!. ^;. ;4;4Q4= .E*( *&.#%$. ^;. ;4;4Q4; -)#$!)!-(% 3!$01! .% ,(1! ! .9$%+$&*D!. ^;. ;4;4Q4Q $&!,$%+(&#$(% $&!,$%+(&#$(% $(+% %. ^;. ;4;4Q4[ -)#$!)!-(%
(168) "&(.)8.)(%. ^Q. ;4;4Q4Y &-! )%(&.#! ! #% ! B)(#% !. ^Q. ;4;4Q4T . (&.#! "O.#()! &(1!. ^[. ;4;4Q4_ (9$%01! %(!B -!$ / !.!)$(#%*. ^[. ;4;4Q4^ ()$!)!-(% *#$F.()% %$$ "$% %-% . ^Y. ;4Q4 "*#% ! ()"1!. ^Y. ;4[ !.)*"1!. ===. ;4Y 9$8.)(%. ==;. ;. =;=.
(169) Q5 '.# #" ! /$()! B-$(&.#%* % $!-$( % . . .
(170) -)#$!)/-()% !&-!#! (9!9!.%#! )!&
(171) %.#%.' !. Q4= .#$! "01!. =;^. Q4; %#$(%( ?#! !. =;Z. Q4;4= %,.#. =;Z. Q4;4; '.#. =;Z. Q4;4Q .#$"&.#%01!. =Q<. Q4;4Q4= .E*( *&.#%$. =Q<. Q4;4Q4; -)#$!)!-(% 3!$01! .% ,(1! ! .9$%+$&*D!. =Q<. Q4;4Q4Q $&!,$%+(&#$(% $&!,$%+(&#$(% $(+% %. =Q<. Q4;4Q4[ -)#$!)!-(%
(172) "&(.)8.)(%. =Q=. Q4;4Q4Y &-!. )%(&.#! B)(#%01!. ! #% ! =Q=. B)(#% !. Q4;4Q4T . (&.#! "O.#()! % &(1!. Q4;4Q4_ (9$%01!. =Q;. %(!B -!$ / 9(.%&.#!. % =Q;. Q4;4Q4^ ()$!)!-(% *#$F.()% %$$ "$% %-% . =QQ. #$"#"$%. Q4;4Q4Z E*)"*! /$()! % %B% $%.9$8.)(% .$,(% =QQ. .#$ !.. Q4Q "*#% ! ()"1!. Q4Q4= #$"#"$% $(#%*!,$E9()% !&#$(% -%J*P Q. . =QT. =QT. .
(173) Q4Q4; $!-$( % -)#$!)/-()%. =[[. Q4Q4;4= $!-$( % -)#$!)/-()% ! !&-!#! AQ4=C =[[. AQ4;C AQ4QC. Q4Q4;4; $!-$( % -)#$!)/-()% ! !&-!#! AQ4[C. =Y_. Q4[ !.)*"1!. =T^. Q4Y 9$8.)(%. =TZ. Q. =__. Y4< $-)#(+% $%(. =Z=. [5. =Z;. $#(,! -"3*()% ! %#.#. . .
(174) .
(175) . .
(176) . 4 %#$(%( #%*$,O.()! AC m -)#! H(#/$()!4. +!*"01! % !)( % #& +( .)(% ! "&% ?$( -$!3*&% 2":. .% &%(!$(% ! )%!: .)(#%& !*"0` -)'9()%4 !.2n.#&.#:. % B-*!$%01! .!+% #).!*!,(% 2" %#. %& % .)( % )!.#(#"(. "& ! #!$ #$%#?,()! &%( (&-!$#%.# % %#"%*( % 4 #% )$).#. &%. % #& 9!&.#% ! ! .+!*+(&.#! .!+! &%#$(%( )!& *+% %. -)(9()( % 9".)(!.%*( % 4. "'&()% ! #% ! /*( ! )!.(# & (.+#(,%0` $*%)(!.% % o. '.#: )%$%)#$'#()% #$"#"$%(: -$!-$( % A9'()% 2"'&()%C . %-*()%0` &%#$(%( /*( !4 # $%&! % )(8.)(% ? 9". %&.#%*. (&-!$#O.)(%: +( ! % # )!&-!#! -!"'$& *+% % (,.(9()O.)(% -%$% %. !)( % %#"%*4. -$!+% (#! % +?& % +%#% "#(*(G%01! &%#$(%( /*( ! .%. )!.9)01!. . (-!(#(+! #).!*!,()%&.# #$%#?,()! )!&!5 *%$:. "-$)!. "#!$: &%,.#!: &%#$(%( *"&(.).#: )%#%*(% !$: .#$. !"#$!4=. -$!-$( % 9'()% 2"'&()% ! )!&-!#! -. & 2"% 2". B)*"(+%&.# % (-!(01! -%)(%* ! " E#!&!: '!. !" &!*?)"*% %. .%#"$G% % *(,%0` 2"'&()% .#$ " )!.#(#"(.#:; .! .#%.#!: &"(#!. -$!)! &%( #$% ()(!.%( -$-%$%01! &%#$(%( /*( ! $#$(.,& %!. )!.#$!* #$"#"$%* o $%#(+( % ! &%#$(%(4 #% -$-)#(+%: &"(#!. . .
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` A=: ; !" QC:Z=; (,"$% =4. . .
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
(179) =Z^<: !3(.!. #. %*4 (.()(%$%& "&% %3!$ %,& %)$)% ! (,. -!*'&$!. )!!$ .%01!: )".D%. ! ! 9%&!! #$&! L.! %. -%$)$M4 =[. (,"$% ;5 #$"#"$% )$(#%*!,$E9()% ! G"* % $7(%4 AC5 $&*D!\ AC5. G"*4. !& % (.#$! "01! % "'&()% #()"*%$: -!$ %*,". )!.( $% % )!&!. . ! "&% +$#.#. % .,.D%$(%. -*%.a%&.#! #$"#"$%*. %*,".. $(#%(: #!$.!" -!'+* !. )!&-!#! 3%% ! .!. $)!.D)(&.#! -% $` (.#?#()! 2" 9%+!$)& "& #$&(.% ! &! !. )!!$ .%01! &#%**(,%.#4 !& % -"3*()%01! % Y & =ZZZ=Y . "32n.#&.# % =T A (,"$% QC: p%,D( -$!+!" % D(-/# 2" &. . .
(180) )!. (0` B-$(&.#%( % 2"%( -$$+%& ! %-)#! ,!&?#$()! . ($)(!.%( ).#$! &#E*()! *(,%.# !$,O.()! ? -!'+* % 9!$&%01! . %$2"(##"$% &!*)"*%$ -)'9()%4Q:=_:=^ %* %*(.#%$ 2" & ". B-$(&.#! -%$% !3#.01! % Y % : p%,D( 3%!" .%. #$"#"$% ! )*"#$ G(.)! A.[C -$.# .! %)#%#! G(.)! %.( $!:=Z. )!.D)( % =ZYQ4;<. (,"$% Q5 *"#$%01! % #$"#"$%5 A%C Y\ A3C )*"#$ .[\ A)C =<\ A C 4 %-#% ! % $94 =Y: =T ;<4. "32n.#&.#:. "3#%.)(%*&.# -%$% !. . (+$!. ,$"-!. .+!*+(&.#!. . -2"(%. )!.#$(3"'$%&. (.+#(,%0` %)$)%. %. .
(181) #$"#"$% -$!-$( % . /*( !4 %#! #: (. "3(#%+*&.#. +( .)(% ! -*! *+% ! .7&$! %$#(,! )(.#'9()! -"3*()% ! .% *(#$%#"$%. .#1! A (,"$% [C4_:;=;[. . . . . .
(182) . . . . . (,"$% [5 7&$!. %$#(,! )!.#. ! % -%*%+$%)D%+ L&#%*!$,%.(). 9$%&K!$JM )!.#( ! .! #'#"*! !" %3#$%)# ! 7*#(&! ;< %.!4 A !.#5 ]3 !9. )(.): <^P<QP;<=<C4. . .
(183) . 4 '.# %#$(%( #%*$,O.()!4. &#! !*!,(% -$-%$%01! 1! )!.( $% % -$!)!. (&-* 2"%. ! )!&-%$% ! )!& '.# &!*?)"*% !$,O.()% )!&!5. ?#$ )!$!%: )$(-#%#!: . $'&$! !"#$!4 ! .#%.#!: #% (&-*()( % . #& " -$0!: "&% +G 2" ? 9". %&.#%* !3#$ )$(#%( )!&. #%&%.D! 2"%*( % % 2"% ! -%$% #$&(.%01! #$"#"$%*4. & #&-$%#"$% (.9$(!$ % =<<q .!$&%*&.# 1! "% ! &?#! !. (.#?#()! 2" .+!*+& ,$% (.# )!.).#$%01!:=Y:;Y;_ .#$#%.#! -%$%. '.# %)(&% #% #&-$%#"$% ? %-*()% % % #?).()% !*+!#$&%*4;^ . &?#! ! ,$% (.# )!.).#$%01! -%$% -$-%$%01! .+!*+& %. +%$(%01! % )!.).#$%01! % %&!#$% !" ! $%,.# -*% $&!01! !. !*+.# !" -*! #$%.-!$# &%% & &(! !. ! &&! 1! -!")!. !*7+(4 %$% #% &#! !*!,(% -! & $ #%)% % % +%-!$%01! %. (9"` A& ,*: *'2"( !*'2"( !: *'2"( !+%-!$C4;Z -%$. #% '.#. ,$%$& )$(#%( )!& 3!% 2"%*( % : 1! *(&(#% % -!$ &%. %$& #&-!: .1!. -$&(#($& &%(!$ )!.#$!* % )(.?#()% .")*%01! % %$2"(##"$%. &!*)"*%$: -!( $#$(.,& %a"# o )!. (0` '.#4Q<. % 9(,"$%. Y. 1! &!#$% ! 2"&%. % '.# 2" .+!*+& ,$% (.#. . )!.).#$%01!4. .
(184) .
(185) . (,"$% Y5 *"#$%01!. '.#. .+!*+. ! ,$% (.#. . )!.).#$%01!4. A%C (9"1! *'2"( !+%-!$\ A3C (9"1! & ,*4. &?#! ! !*+!#$&%* !)"-% *",%$ #%2" .! 2" $9$ o '.#. 4 #(-! '.# .+!*+ ! "! % E,"% !" !"#$! !*+.#. !$,O.()! A%*)!/(:. (%*2"(*9!$&%&( %: -($( (.%: C & "& $)(-(.#. D$&#()%&.# 9)D% ! A%"#!)*%+: (,"$% TC "3&#( ! % #&-$%#"$%. .!$&%*&.# %)(&% ! -!.#! 3"*(01! ! !*+.#4. &%(!$(% ! #$%3%*D!. "#(*(G% % E,"% )!&! !*+.#: -!( ! -$!)! D( $!#$&%* &(&#(G% -$!)!. ,!*/,()! )$)(&.#! )$(#%( 2" !)!$$& .% )$!#% #$$#$4. . .
(186) . (,"$% T5 %#!$ "% ! & '.# !*+!#$&%*4. !3 )!. (0` +$% #&-$%#"$% -$1! % -$!-$( % 9'()%. ! !*+.# "#(*(G% ! &" %& )!.( $%+*&.#4 !$ B&-*!: % +()!( % %. E,"% (&(."( )!& ! %"&.#! % #&-$%#"$%4. Y<<h )!& =< 3%$ -$1!. !&.# =<e "% &%,.(#" ? -$$+% %4
(187) !,!: % &!3(*( % ! '!. . &!*?)"*% (!*+( ! ? )!.( $%+*&.# %"&.#% % 2"%. ! )!&-%$% % %. )!. (0` .!$&%( #&-$%#"$% -$1!: (#! -$&(# % .")*%01! . )$)(&.#! ! )$(#%(4 (&(*%$&.#: % )!.#%.# (*?#$()% % E,"% ?. (,.(9()%#(+%&.# $ "G( % & )!. (0` B#$&%4 (&-*()%0` (#! #1!. %!)(% % %! %"&.#! % !*"3(*( % ! $%,.# /*( ! .% )!. (0` %. $%01! %"&.#! % )!.#%.# (!)(%01! +( ! o $ "01! % (.#$%01!. . .
(188) (.#$&!*)"*%$4 $%$ (. #4 %* &!.(#!$%$%& % +%$(%01! -H % E,"% &. )!. (0` D( $!#$&%( "%. ! )!.#%#%$%& 2" % =^<q. ! $-)#(+!. +%*!$ ? Y:Y4Q=. %$(%0`. % '.# !*+!#$&%* #8& ( ! -$!-!#%4 D#D%& . )!*%3!$% !$Q; &!#$%$%& "#(*(G%01! !( *'2"( ! (&()'+( AE,"% = -.#%.!* !" )()*!DB%.!*C -%$% -$-%$!. : .! 2"%* )$(#%( )!&. B)*.# 2"%*( % 9!$%& 9!$&% ! .% (.#$9%) ! !( !*+.#4 "#$%. +%$(%.# 3%#%.# (.#$%.# )!.(# .! "! $% (%01! &()$!!. %4. !& # &?#! ! ? -!'+* (.##(G%$ & #&-! )"$#!: )!.#$!*%$ %. (#$(3"(01! #%&%.D! % -%$#')"*%:QQ %*?& 9%)(*(#%$ ! )!.#$!* !. -%$O&#$! B-$(&.#%(4;= (*+%. # %*Q[. &!.#$%$%& % '.#. %. S;A-I )C;AH-I )CAH;C;U*rAZRICH; )!& %-.% Q< &(."#! ($$% (%01!. )!.#$% ! Q (% % '.# !*+!#$&%* )!.+.)(!.%*4 % &&% 9!$&%: D%.,. )!*%3!$% !$ -$-%$%& %
(189) =<< -!$ = D!$% ($$% (%01! & ;;<q )!.#$%. % ZT D!$% ! &?#! ! D( $!#$&%*4QY. & +($#" . ! *%$,! (.#$ . &%#$(%(: .!+% %*#$.%#(+%. (.#?#()% +8& . ! -$!-!#%4 & $).# #$%3%*D!: p%,D(: -$! "G(" "&%. ?$( A Y: _[: =__: =ZZ <C "#(*(G%. !. -$)(-(#%01! o #&-$%#"$% %&3(.#4QT %()%&.#: ! &%#$(%( 1! !3#( !. %#$%+? % %,(#%01! #! ! ! $%,.# -!$ %*,"&% D!$% & 3%*`. . .
(190) )!.#. ! 4 *#$.%#(+%&.#: (" &!#$!" % +$%#(*( % ! "! . "*#$%!& -%$% % '.# S.QAC;s=;H;UQ_ -2"(% !$ % . .+!*+$%& "&% $!#% *#$!2"'&()% -%$% -$-%$%01! % " A%!*(#t. Q<<C & )%*% (. "#$(%*4Q^ ! 7*#(&! )%!: O.! ! %)$(9()(%( )!3$ )!&. Y:< && -"$% 1! !B( % ! & -$.0% ! =:Q:Y3G.!#$()%$3!B(*%#!. (!*+( ! & &#%.!* "$%.# =Y< &(."#! !3 =;=Z Q:< 4QZ. 4 -*()%01! %#$(%( #%*$,O.()!. /*( ! (.!$,O.()! -!$!! 1! )!.( $% ! -!$ &"(#!. -2"(% !$ &%#$(%( (. "#$(%*&.# #$%#?,()!:[< -!( )$)% ;<Q<e. ! #!#%* &%#$(%( "! !&?#()! & -%' (. "#$(%*(G% ! ! "#(*(G%& . %*,"&% &%.($%4[= -*()%0` & )%#E*(: -#$!2"'&()%: -%$%01! *#(+%:. .#$ !"#$%[;[T "#(*(G%& % *+% % #%3(*( % #?$&()%: E$% "-$9()(%* %. -!$!( % # )!&-!#!: )!&-$!+%. ! ! 2"%.#! # &%#$(%( #1!. )!.!*( % ! 1! (&-!$#%.# .! ).E$(! &". (%*4[_. *,". )!&3(.%& ! 2"% (*(&(#% ! )!.#$!* (&.(!.%* % E$%. "-$9()(%*[^Y< & ! )!&-$!&#(&.#! % -$!-$( % 9'()% 2"'&()%:Y=. )%$%)#$'#()% 2" ! #!$.%& -$(.)(-%( )!.)!$$.# % G/*(#% !"#$!. /*( ! (.!$,O.()! $*%)(!.% !4Y= &3!$% % +%.#%,. ! !3$ !. /*( ! (.!$,O.()! )*E()! a%& +( .#: !&.# "& *(&(#% ! .7&$! . . .
(191) %-*()%0` ! #& ( ! ()"#( ! & )%*% *%3!$%#!$(%*Y; B(#. !&.# "& ,$"-! -2"(% 2" #& %+.#"$% ! & ## % .'+(. (. "#$(%(4Q^:QZ. u (&-!$#%.# #%)%$ 2" +( ! %! -%-* )$")(%* & &"(#! -$!)!. 2"'&()! (. "#$(%(: % )%#E*( D#$!,8.% & 7+( % ? "&% % &%(. -$!&(!$% %-*()%0` ! 4YQYY "a(#% 9!( ! -(!.($! % &!.#$%$ %. -!#.)(%*( % 2"%. ! $-!$#!" % -$!-$( % )%#%*'#()% -)'9()%. !. S AQCA[:[v3-IC;U -%$% % $%01! )(%.!*(G%01! %* ' !4YT ",I. #4. %*4 &!#$!" 2" ! &%#$(%* (.#(#"*% ! . A $(+% ! G(.)! -!$9($(.%C. -$! "G "& %"&.#! .% #%B% % $%01! #$%.9$8.)(% ! ,$"-! %)(*% .#$ !. %)#(*(&( %G!* ! Q-($( (*)%$3(.!* A2"&% AA=CC: & ;[;< +G & $*%01!. % $%01! .1!)%#%*(% %4Y_. Y #& ( ! "% % )!&! "-!$# )%#%*'#()! -%$% .%.!-%$#')"*% . /B( ! &#E*()! &. . (+$% $%0` )!&!5 '.#. &#%.!*Y^ . .
(192) D( $!,.%01!. ! #(*)(.%&%#!YZ4 ).#&.#: ]!*)G%.J (%"B. +$(9()%$%& ! -!#.)(%* & $%0` (,*$%##% -%$% -$-%$%01!. -!*'&$! (-$!: *(.%$ %#E#()!4T<:T= & $%0` 2" .+!*+&. )!&-!#! 2"($%(: N(& # %* $-!$#!" ! -$(&($! B&-*!. )%#E*(. %(&?#$()% )!&! "&% D!&!2"($%* 3%% % & "& $(+% ! ! E)( !. #%$#E$()!T;
(193) (. -$-%$!" "&% ?$( D!&!2"($%( 3%% % &. *%.#%.' ! *(,%.# 9!9!.%#! B%&(.!" % %#(+( % )%#%*'#()% . &%#$(%(4TQ. & +($#" % .)( % .+!*+(&.#! #).!*!,(% *(&-% . )$?)(&! % $$+% .$,?#()% !$(,& 9/(*: (+$! ,$"-! #8& . ()% ! % -2"(% .+!*+. ! ! .+!*+(&.#! #).!*!,(% -%$% %. #!)%,&: -"$(9()%01! -%$%01! ,%: 3%% % & 4T[TZ . -$(&($! B&-*! 9!( (+"*,% ! -!$ N(#%,%K% & =ZZ_ 2"%. ! )!.9(.!" "&%. ,$%. 2"%.#( % ,E &#%.! & 4_< "32n.#&.#: !"#$!. #$%3%*D! &!.#$%$%& % +%#% )%-%)( % % !$01! ,% )!&!5. &#%.! AH[C: _=:_; D( $!,8.(! AH;C:_Q:_[. (/B( !. )%$3!.! A;C_Y__ . .(#$!,8.(! A;C4_^. $&!01! #(! $(+% ! AH: ##$%D( $!#(!9.!C & ,E. .%#"$%* 9!( $%*(G% % -!$ -2"(% !$. % 4 # B-$(&.#!:. $-$.#% ! -*% (,"$% _: % " 9!( )%-%G $&!+$ #$%0! . H A=<=Y --&C % .'+( )!&-%$E+( % -$! "#! )!&$)(%*(G% ! -%$% #%. . .
(194) 9(.%*( % A!$(#[ %$3! )DQ^P[C4Q^ (. % .! O&3(#! % -"$(9()%01! . $&!01! )!.#%&(.%.#: !! )!*%3!$% !$ +%*$%& % %9(.( % . %*,"&% -!$ $(+% ! .B!9$ -%$% "#(*(G%$&.% .% "*9!$(G%01!. )!&3"#'+(4_Z. (,"$% _5 *"#$%01! ! B-$(&.#! $&!01! H & ,E .%#"$%* "%. !. 4 %-#% ! % $94 Q^4. "#$% &$,.# %-*()%0` )!.(#& .% "#(*(G%0` ! )!&!. )%$$% !$ $!,% %,.# )!.#$%# & !.O.)(% %,.?#()% . . .
(195) &%,&4^<:^= #% -$-)#(+%: H!$)%a% % )!*%3!$% !$ #&. (+"*,% ! %. $E#()% % !$01! %.%*,?()! 3!-$!9.! A<:QY % =:[ ,P,C .% . ( $%#% %:
(196) =<<
(197) =<=4^; ! " &%( $).# #$%3%*D! (+$!. 9E$&%)! A : 3.G!9.!.%: )%9'.%:. !B!$(3")(.% !"#$!C #8& ( !. % !$+( ! & " 9(#! ##% ! (. +(+!: % ()(!.%*&.# .%(! . . A!.O.)(% %,.?#()% &%,&C 9!$%& $%*(G% !4^< 6E !I . )!*%3!$% !$ -$!-`& ! "! .% "*#(9".)(.%* %.!& ()(.% +(%. !. % &%$)%01! #$%#%&.#! O.)$4^Q. . .+!*+(&.#!. .!$ /-#()! 3%% ! . &%#$(%(. #%&3?& #& ( ! -$!-!#!4Y<:^[^T -$(.)'-(! 3E()! ! 9".)(!.%&.#! . (#&% )!.(# .% +%$(%01! ! (.%* /-#()! %-/ % (.#$%01! ! %.%*(#! )!& %. 9% .!$% AC4^_ D., )!*%3!$% !$ +& $-!$#%. ! "&% ?$( . -$!#/#(-! 3%% ! & )!& *%.#%.' ! -%$% ! .!$(%&.#! . -?)(4 3ACr A V G.!#$()%$3!B(*%#!: V &!*?)"*% . !*+.#C 9!( -$!-!#! -%$% ! .!$(%&.#! ! O.(!. :^^ .2"%.#! ! ". -%$%. -2".%. &!*?)"*%. A#%.!*:. :. %)#!.%C^Z. . !. S"A- )C=:YA CUwA C<:YAH;C<:YU A- ) V Q:Y-($( (. ()%$3!B(*%#!C -%$% %. #)01! '!. &#E*()!4Z< H%$3"G%$" #4 %*4 #8& %-$.#% ! .!+! . 3%% ! &
(198) .QR '!. ! 9(#! "-$1! %"&.#! % *"&(.)8.)(%. & -$.0% % E,"% !" #%.!* & 9".01! ! -H: $-)#(+%&.#4^T:Z= . . .
(199) *"&(.)8.)(% !$(". % ! *(,%.# !$,O.()! #%&3?& #& ( ! "#(*(G% % -%$%. ! &!.(#!$%&.#!. -?)(: ! B&-*! (.#$%.# ? ! "!. !. S.QAC;s=;H;U. -%$% % %.E*( %*2"(*%&(.% & !*"01! %)#!.(#$(*%. +(% #(#"*%01! -)#$!9!#!&?#$()%4Q_. & #$%3%*D! $).# .+!*+( ! -*! ,$"-! #$$% $%$% !. -%$#%&.#!. "'&()% ". %&.#%*. % .(+$( % $%*. . $.%&3")!: +8& . ! &-$,% ! )!&! .!+% 9% #%)(!.E$(%. -%$% B#$%01! & 9% /*( %. XSA. -#()( %4Z;:ZQ &%#$(%* ;. CA CAH CU: &!#$!" "&% -!#.)(%* % !$01! *#(+%. #$8. -#()( % A3(9.#$(.: ##$% (9!. 9!%*!.%C ! ( #" % !: .2"%.#! ! Q. XSA
(200) %<:Z"<:=C;A CQAH;CQU -!. $ "% ! & %.E*( -($(&()%$3: &#(*. -%$%#(!.: &%*%#(!.: -$!)(&( !.%: x. !"*9%.! y. !"*9%.!4 6E !. S.ACAH;C;U. (.##(G% ! -!$ ]%. $*I %-$.#% 3!% -$9!&%.) -%$%. %.E*( ( -#()( % ! # #" % ! & &%#$(G -*%.#% & ()(.%*4Z[. % +%.,"%$ %: $ )!*%3!$% !$. .+!*+$%& %*#%&.#. *"&(.).# 2" 9!$%& %-*()% ! & "&% .!+% &#! !*!,(% -%$% B%&. $( !,$E9()! %$&% 9!,! A (,"$% ^C4ZY. . .
(201) . (,"$% ^5 *"#$%01! ! B-$(&.#! #)01! -!$ *"&(.).#4. A%C A3C5 &3$! "-$(!$ &1! ! %#($% !$ !3 *"G &!#$%. ! -!.#!. 3$(*D%.# ! &%$)% !$\ A)C5 (#!*% !3 *"G %-/ (-%$! )!& &".(01!. &%$)% %\ A C5 +!*+$ & ($$% (%01! % *"G \ AC A9C5 +!*+$ !3 *"G. %-/ (-%$!4. "#(*(G%01! ! !3 % 9!$&% ,$%."*%$: %-%$ $ % &%(. (9". ( % %#"%*&.#: $#$(., o !-0` B-*!$%01! % -!#.)(%*( % . # )!&-!#!4ZT
(202) !,!: % (.)!$-!$%01! & &%#$(G % 9(B%01! &. .
(203) .
(204) "-$9')( 1! %*#$.%#(+% +(E+( 2" 9%)(*(#%& % &%.(-"*%01! !9(#()%& %. %-*()%01! &%#$(%(4 ).#&.#: ** !$9 !3$+!" 2" % .$,(% %. (.#$%01! &!*)"*%$ %.%*(#! -! $ )!.+$#( % & .$,(% &)O.()%. -%$% )$(%01!. )$)(&.#!. "& .!$ $+$'+* %*#%&.# *#(+! %#$%+?. "&% &!.!)%&% %. .% "-$9')(. !. "&. &()$!)%.#(*+$4ZT. 4 9$8.)(%. . . !
(205)
(206) .
(207)
(208)
(209)
(210)
(211)
(212) "#$%&' &()*&+"#$%&,"#$%&&-&./ + . . 0& ! ! "#$% $&! ''(
(213) . )
(214) )
(215)
(216) *
(217) ) % +#
(218) 1 . . /%20234&&55&026.%7&849$$:$0. 4"!
(219)
(220)
(221) )
(222) (,+
(223) 1
(224) . . " ;7(( %"0< - . /
(225)
(226) % 0 . )%)!1 *. 23
(227) 4 56
(228) 7 1 . . .
(229) . . 26.% 7 =&%$1>&$6 2 234&&55& 0 /% 2 0. 3
(230)
(231) /
(232) )
(233) ) 6
(234) ) 4 1
(235) ) +8
(236) 1 . . *&5((: < 06) ? 9
(237) !
(238) . ) ! )
(239)
(240)
(241)
(242) ,(7 1 .
(243) . ? % ! /% 2 0 / ) !
(244) . ) % +81 . . .&!?/%20. !
(245) )
(246) ). .
(247) . . :+1 . . ?: 71 ! % ? >& % @1? ?: A1B 4 +6 ; . . 23
(248) 4 < =
(249) ;. ) 56
(250) 8 1 . . C %<<:/< %/?/CC:80& %D/
(251)
(252) . 4 4
(253) ) $99' *
(254)
(255) - ) ,,>++>! / 6
(256) 0 %
(257) %
(258) ; ; 56
(259) 7 1
(260) . . ?: 71 ! % ? >& % @1? ?: A1B / +6
(261)
(262) . ;
(263) * $99'
(264) ?
(265) $99' 9@ !(#!6 *
(266) ((>! AA
(267) A 56
(268) 7 1
(269) . . 7: 1= 0 ? ? 7 - 3 - . . 23
(270) 4 A ) "
(271) =
(272)
(273) %B 9
(274)
(275) (: 1 . . .
(276) . . <(:( B((& <:E & 0 && =$ A: &
(277)
(278) . ; 6
(279) 1
(280)
(281) 1
(282) <*:# %+"#$%& . . # 1
(283) !*
(284)
(285)
(286) ). % !6
(287) /
(288)
(289)
(290) 1
(291) . . ?89$$:$0234&&55&0/%206
(292)
(293)
(294) ).
(295)
(296) *
(297) !
(298) ) (C,
(299) 1
(300) . . 9$$:$ 0 4" ! F$ = 76(& ! 234&&55& 0. /%20% 6
(301) ); %@
(302) 4
(303)
(304)
(305) 9 .34
(306) /1
(307)
(308) .
(309) % %
(310) ,D# 1
(311) .
(312) . A 6&" (% &=!?C234&&55&0/%20 . ) !
(313) 1
(314)
(315) !9
(316)
(317)
(318) "
(319) (: 1
(320) . . A 6&" (% & =!0& $E1(&!?234&&55&0/%2. 0 %
(321) *
(322)
(323)
(324)
(325) *
(326)
(327)
(328) ) !
(329) ) % +8
(330) 1 . . B% > ? % ? % ) )
(331)
(332) @ !.
(333) ) * *
(334) ) . % /-"3-".:&71 . . F. && ! <6& % > ? A#( ! 8 / . % ) ?
(335) 1 6 ?
(336) $-+33',,-,3 1 7
(337) 1
(338) . . >&&)-*
(339) ) % . +:1 . . .
(340) . . 4(%. < 4(: < 4
(341)
(342)
(343)
(344) . 1
(345) 9
(346) ""
(347) (+ 1
(348) . . " &
(349)
(350) ) !!
(351) E6
(352) /
(353) .
(354)
(355) 1 . . ?D7C %7/0G 62<4 #&B<($$(!>. /% 2 0 1 !
(356) )
(357) !
(358)
(359)
(360)
(361) (7 1 . . $&B&((& 6:(1=; 9 !* ,6
(362)
(363) ). "$999'$999'
(364) /*$999'"
(365)
(366)
(367) ) *!
(368)
(369)
(370) .
(371) @
(372) 9
(373)
(374) ((
(375) 1
(376) . . 4" ! & B & && A 0 ? 8 9$$:$ 0 0& = B. 234&&55& 0 /% 2 0 1 * ) . 23
(377) 4 ) = 3
(378)
(379) 9
(380)
(381) %
(382) A
(383) F
(384) 0 "
(385) %)
(386) ;
(387) ) %
(388) ) 1
(389) % &,+ 1
(390) .
(391) . : @ C: > % D @:& 0 A <: ! ? @ D: <. %
(392) %
(393) =
(394)
(395) ; ) "
(396)
(397) ;
(398) ) ;!G A
(399) A 9
(400)
(401) (( 1 . . . 4) ;4"( 08(( A-
(402)
(403) .
(404)
(405) )
(406) )*
(407) @
(408) * $ ' 1,.,H!7$33'7I
(409) 8-$,'3 !
(410)
(411) 9
(412)
(413) 1 +#: 1 . . .
(414) . . D:<C: .
(415)
(416)
(417) )
(418) @
(419)
(420) . ) !
(421) ) )
(422)
(423)
(424)
(425) ,#+ 1 . . *E>;;6!4 .!A $$&A<>105?. 3
(426) ) !
(427)
(428) *
(429)
(430)
(431)
(432)
(433) ) *
(434)
(435) ;
(436) % % ++1 . . &$ H 0 ;:6& ? 8: 0 A:&& > 9
(437) % -. ; *
(438) ) - %
(439) * . ) . && 1 . . >(& * 0 A" * 0 &&(" ; 4 A % . %
(440) 1 1 ) -* 9
(441)
(442) 23
(443) . ) . &(
(444) 1 . . A) 4 0 ? ! ; ? 7 B %)
(445) !
(446) ).
(447)
(448)
(449) !
(450) ) )
(451)
(452) 1
(453)
(454) !9
(455)
(456)
(457) "
(458) (:
(459)
(460) 1
(461)
(462) . . < * 6 F& (& ; ; 6 ! ;"&$ *E > ; 4 . . %
(463) ) . =
(464)
(465) 23
(466) 4 56
(467) &C 1 . . !: % < 8 ?&& ! 8 % ! < .
(468) ) .
(469)
(470) * A
(471) ) J
(472) % ,7 1 . . A 6&" (% & = ! 8: ( ! /% 2 0 .
(473) ) !
(474) ) .34!# .34!:( .34!&:: .34!&DD
Documentos relacionados
Considerando o fato do principal objetivo do design ser a resolver problemas complexos por meio do planejamento de alternativas e formulação de “melhores modos de fazer”,
Neste contexto, os objetivos deste trabalho foram: (1) estudar os efeitos de diferentes composições do meio de cultura no crescimento do fungo; (2) estudar os
Sou Lana Keren de Mendonça, concluinte do Curso de Biblioteconomia na Universidade Federal de Goiás em 2008. Meu trabalho de Conclusão de Curso resultará em
Embora diversos estudos tenham sido realizados sobre a germinação de sementes Ayensu, 1973; Silva, 1985; 1987; Mercier & Guerreiro Filho, 1989; Garcia & Diniz, 2003; Oliveira
A utilização de fasores resulta nos conceitos de impedância e admitância, análogos à resistência e condutância em circuitos puramente resistivos; Os métodos de análise e
• Pela mecânica quântica: teremos reflexão da função de onda do eletron, bem como uma transmissão da função de onda. A solução da função de onda
Neste trabalho em especifico, objetivou-se avaliar por meio da análise multivariada a produção por ano e por período, bem como, a composição química gordura, proteína, lactose
Dando continuidade ao projeto, no segundo capítulo abordaremos o tema da transgressão burtoniana do Feio, ou seja, como o diretor Tim Burton promove a integração do Feio em seus