Optimization of analitycal control over residues of active ingridients of modern pesticides in reservoirs water

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ɇɚɰɿɨɧɚɥɶɧɨɝɨ ɦɟɞɢɱɧɨɝɨ ɭɧɿɜɟɪɫɢɬɟɬɭ ɿɦ.Ɉ.Ɉ.Ȼɨɝɨɦɨɥɶɰɹ ɤɚɮɟɞɪɚ ɝɿɝɿɽɧɢ ɬɚ ɟɤɨɥɨɝɿʀ

ɩɪ.ɉɟɪɟɦɨɝɢ, 34, Ʉɢʀɜ, 01601, ɍɤɪɚʀɧɚ Hygiene and ecology institute

O.O. Bogomolets National Medical University department of hygiene and ecology

Peremogy Avenue, 34, Kiev, 01601, Ukraine e-mail: viestas@ukr.net

Ʉɥɸɱɨɜɿ ɫɥɨɜɚ:ɩɟɫɬɢɰɢɞɢ,ɜɢɫɨɤɨɟɮɟɤɬɢɜɧɚ ɪɿɞɢɧɧɚ ɯɪɨɦɚɬɨɝɪɚɮɿɹ,ɜɨɞɚ ɜɨɞɨɣɦ

Key words: pesticides, high-performance liquid chromatography, water of reservoirs

Ɋɟɮɟɪɚɬ. Ɉɩɬɢɦɢɡɚɰɢɹ ɚɧɚɥɢɬɢɱɟɫɤɨɝɨ ɤɨɧɬɪɨɥɹ ɨɫɬɚɬɨɱɧɵɯ ɤɨɥɢɱɟɫɬɜ ɞɟɣɫɬɜɭɸɳɢɯ ɜɟɳɟɫɬɜ ɫɨɜɪɟɦɟɧɧɵɯ ɩɟɫɬɢɰɢɞɨɜ ɜ ɜɨɞɟ ɜɨɞɨɟɦɨɜ.ɋɟɦɟɧɟɧɤɨ ȼ.Ɇ., Ȼɚɪɞɨɜ ȼ.Ƚ., Ʉɨɪɲɭɧ Ɉ.Ɇ., Ʌɢɩɚɜɫɤɚɹ Ⱥ.Ⱥ., Ʉɨɪɲɭɧ Ɇ.Ɇ. Ɋɚɡɪɚɛɨɬɚɧ ɜɵɫɨɤɨɱɭɜɫɬɜɢɬɟɥɶɧɵɣ ɢ ɫɟɥɟɤɬɢɜɧɵɣ ɦɟɬɨɞ ɨɩɪɟɞɟɥɟɧɢɹ ɩɢɪɚɤɥɨɫɬɪɨɛɢɧɚ, ɛɨɫɤɚɥɢɞɚ, ɬɟɛɭɮɟɧɩɢɪɚɞɚ ɢ ɩɪɨɝɟɤɫɚɞɢɨɧ-ɤɚɥɶɰɢɹ ɩɪɢ ɫɨɜɦɟɫɬɧɨɦ ɩɪɢɫɭɬɫɬɜɢɢ ɜ ɨɞɧɨɣ ɩɪɨɛɟ ɜɨɞɵ ɫ ɢɫɩɨɥɶɡɨɜɚɧɢɟɦ ɜɵɫɨɤɨɷɮɮɟɤɬɢɜɧɨɣ ɠɢɞɤɨɫɬɧɨɣ ɯɪɨɦɚɬɨɝɪɚɮɢɢ. ɉɟɫɬɢɰɢɞɵ ɧɚ ɨɫɧɨɜɟ ɭɤɚɡɚɧɧɵɯ ɞɟɣ -ɫɬɜɭɸɳɢɯ ɜɟɳɟɫɬɜ (ɤɨɦɛɢɧɢɪɨɜɚɧɧɵɣ ɮɭɧɝɢɰɢɞ Ȼɟɥɥɢɫ,ɢɧɫɟɤɬɨ-ɚɤɚɪɢɰɢɞ Ɇɚɫɚɣ ɢ ɪɟɝɭɥɹɬɨɪ ɪɨɫɬɚ ɪɚɫɬɟɧɢɣ Ɋɟɝɚɥɢɫ) ɦɨɝɭɬ ɩɪɢɦɟɧɹɬɶɫɹ ɜ ɨɞɢɧ ɜɟɝɟɬɚɰɢɨɧɧɵɣ ɫɟɡɨɧ ɞɥɹ ɡɚɳɢɬɵ ɩɥɨɞɨɜɵɯ ɧɚɫɚɠɞɟɧɢɣ. Ɇɟɬɨɞ ɫɨɜ -ɦɟɫɬɧɨɝɨ ɨɩɪɟɞɟɥɟɧɢɹ ɢɫɫɥɟɞɭɟɦɵɯ ɜɟɳɟɫɬɜ ɨɫɧɨɜɚɧ ɧɚ ɩɨɞɝɨɬɨɜɤɟ ɩɪɨɛ ɜɨɞɵ ɤ ɷɤɫɬɪɚɤɰɢɢ, ɢɡɜɥɟɱɟɧɢɢ ɩɢɪɚɤɥɨɫɬɪɨɛɢɧɚ, ɛɨɫɤɚɥɢɞɚ, ɬɟɛɭɮɟɧɩɢɪɚɞɚ ɢ ɩɪɨɝɟɤɫɚɞɢɨɧ-ɤɚɥɶɰɢɹ, ɤɨɧɰɟɧɬɪɢɪɨɜɚɧɢɢ ɷɤɫɬɪɚɤɬɚ ɫɦɟɫɢ ɜɟɳɟɫɬɜ ɢ ɯɪɨɦɚɬɨɝɪɚɮɢɱɟɫɤɨɦ ɨɩɪɟɞɟɥɟɧɢɢ ɫ ɭɥɶɬɪɚɮɢɨɥɟɬɨɜɵɦ ɞɟɬɟɤɬɢɪɨɜɚɧɢɟɦ. Ɉɬɥɢɱɢɬɟɥɶɧɨɣ ɨɫɨ -ɛɟɧɧɨɫɬɶɸ ɦɟɬɨɞɚ ɹɜɥɹɟɬɫɹ ɢɡɦɟɧɟɧɢɟ ɫɨɨɬɧɨɲɟɧɢɹ ɤɨɦɩɨɧɟɧɬɨɜ ɩɨɞɜɢɠɧɨɣ ɮɚɡɵ (ɫɦɟɫɶ ɚɰɟɬɨɧɢɬɪɢɥ– 0,1 % ɜɨɞɧɵɣ ɪɚɫɬɜɨɪ ɨɪɬɨɮɨɫɮɨɪɧɨɣ ɤɢɫɥɨɬɵ) ɜ ɩɪɨɰɟɫɫɟ ɯɪɨɦɚɬɨɝɪɚɮɢɱɟɫɤɨɝɨ ɚɧɚɥɢɡɚ, ɱɬɨ ɩɨɡɜɨɥɢɥɨ ɱɟɬɤɨ ɜɢɡɭɚɥɢɡɢɪɨɜɚɬɶ ɢɫɫɥɟɞɭɟɦɵɟ ɜɟɳɟɫɬɜɚ ɩɪɢ ɢɯ ɫɨɜɦɟɫɬɧɨɦ ɩɪɢɫɭɬɫɬɜɢɢ ɜ ɨɞɧɨɣ ɩɪɨɛɟ. ȼɧɟɞɪɟɧɢɟ ɪɚɡɪɚɛɨɬɚɧɧɨɝɨ ɢ ɡɚɩɚɬɟɧɬɨɜɚɧɧɨɝɨ ɦɟɬɨɞɚ ɜ ɩɪɚɤɬɢɤɭ ɨɩɬɢɦɢɡɢɪɭɟɬ ɤɨɧɬɪɨɥɶ ɡɚ ɩɪɢɦɟɧɟɧɢɟɦ ɢɡɭɱɟɧɧɵɯ ɯɢɦɢɱɟɫɤɢɯ ɫɪɟɞɫɬɜ ɡɚɳɢɬɵ ɪɚɫɬɟɧɢɣ ɜ ɫɟɥɶɫɤɨɦ ɯɨɡɹɣɫɬɜɟ ɢ ɢɯ ɦɨɧɢɬɨɪɢɧɝ ɜ ɜɨɞɟ ɜɨɞɨɟɦɨɜ ɡɚ ɫɱɟɬ ɫɭɳɟɫɬɜɟɧɧɨɝɨ ɭɫɤɨɪɟɧɢɹ ɚɧɚɥɢɡɚ ɢ ɭɦɟɧɶɲɟɧɢɹ ɡɚɬɪɚɬ ɧɚ ɟɝɨ ɩɪɨɜɟɞɟɧɢɟ.

Abstract. Optimization of analitycal control over residues of active ingridients of modern pesticides in reservoirs water. Semenenko V.M., Bardov V.G., Korshun Ɉ.M., Lipavska A.Ɉ., Korshun M.M. A highly sensitive and selective method of pyraclostrobin, boscalid, tebufenpyrad and prohexadione-calcium determination under their combined presence in water sample, using high-performance liquid chromatography was developed. On the base of mentioned active ingredients (combined fungicide Bellis, insecto-acaricide Masai and plant growth regulator Regalis) pesticides may be used in one vegetation season for fruit trees protection. Method of co-determination of these substances is based on the preparation of water samples for extraction, extraction of pyraclostrobin, boscalid, tebufenpyrad and prohexadione-calcium, concentrating of extract of substances mixtures and chromatographic deter-mination with ultraviolet detection. A distinctive feature of this method is changing of ratio of components of mobile phase (mixture of acetonitrile and 0,1 % aqueous solution of phosphoric acid) in the process of chromatographic analysis, which allowed to clearly visualize test substances in case of their joint presence in one sample. Imple-mentation of developed and patented method into practice optimizes control over application of pesticides in agricul-ture and their monitoring in reservoirs water by significant acceleration of analysis and reduction of expenses in its carying out.

ɇɚ ɫɶɨɝɨɞɧɿ ɜ ɫɿɥɶɫɶɤɨɝɨɫɩɨɞɚɪɫɶɤɿɣ ɩɪɚɤɬɢɰɿ ɜɫɟ ɛɿɥɶɲɟ ɜɢɤɨɪɢɫɬɨɜɭɸɬɶ ɤɨɦɛɿɧɨɜɚɧɿ ɩɟɫɬɢ

-ɰɢɞɢ, ɹɤɿ ɜ ɫɜɨɽɦɭ ɫɤɥɚɞɿ ɦɿɫɬɹɬɶ ɞɜɿ ɬɚ ɛɿɥɶɲɟ

ɞɿɸɱɢɯ ɪɟɱɨɜɢɧ (ɞ.ɪ.). Ɍɚɤ, ɚɛɫɨɥɸɬɧɚ ɤɿɥɶɤɿɫɬɶ

ɤɨɦɛɿɧɨɜɚɧɢɯ ɮɭɧɝɿɰɢɞɿɜ, ɳɨ ɞɨɡɜɨɥɟɧɿ ɞɨ ɜɢɤɨ

-ɪɢɫɬɚɧɧɹ ɜ ɍɤɪɚʀɧɿ, ɡɚ ɩɟɪɿɨɞ ɡ 2001 ɩɨ 2012 ɪɿɤ

ɡɛɿɥɶɲɢɥɚɫɶ ɡ 15 ɞɨ 102 ɩɪɟɩɚɪɚɬɿɜ, ɳɨ ɫɬɚɧɨ

-ɜɢɬɶ 25,4 % ɬɚ 36,3 % ɜɿɞɩɨɜɿɞɧɨ ɫɟɪɟɞ ɡɚɝɚɥɶɧɨʀ

ɤɿɥɶɤɨɫɬɿ ɮɭɧɝɿɰɢɞɿɜ (2001 ɪɿɤ – 59 ɮɭɧɝɿɰɢɞɧɢɯ

ɩɪɟɩɚɪɚɬɿɜ, 2012 ɪɿɤ – 281 ɩɪɟɩɚɪɚɬ) [7, 8].

Ⱦɥɹ ɟɮɟɤɬɢɜɧɨɝɨ ɡɚɯɢɫɬɭ ɫɿɥɶɫɶɤɨɝɨɫɩɨɞɚɪɫɶ

-ɤɢɯ ɤɭɥɶɬɭɪ ɜɿɞ ɲɤɿɞɥɢɜɢɯ ɤɨɦɚɯ, ɯɜɨɪɨɛ ɬɚ

ɛɭɪ’ɹɧɿɜ ɜɢɤɨɪɢɫɬɨɜɭɸɬɶ ɫɩɟɰɿɚɥɶɧɨ ɪɨɡɪɨɛɥɟɧɿ

ɫɯɟɦɢ ɯɿɦɿɱɧɨɝɨ ɡɚɯɢɫɬɭ, ɹɤɿ ɜɤɥɸɱɚɸɬɶ ɜ ɫɟɛɟ

ɩɟɫɬɢɰɢɞɢ ɡ ɪɿɡɧɢɯ ɡɚ ɩɪɢɡɧɚɱɟɧɧɹɦ ɝɪɭɩ.

ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ

ɩɪɨɜɿɞɧɚ ɪɨɥɶ ɭ ɬɚɤɢɯ ɫɯɟɦɚɯ ɧɚɥɟɠɢɬɶ ɿɧɫɟɤɬɢ

-ɰɢɞɚɦ, ɿɧɫɟɤɬɨ-ɚɤɚɪɢɰɢɞɚɦ ɬɚ ɮɭɧɝɿɰɢɞɚɦ. Ʉɪɿɦ

ɬɨɝɨ, ɞɥɹ ɤɪɚɳɨɝɨ ɪɨɫɬɭ ɬɚ ɪɨɡɜɢɬɤɭ ɩɥɨɞɨɜɢɯ

ɧɚɫɚɞɠɟɧɶ ɿ, ɜ ɩɨɞɚɥɶɲɨɦɭ, ɞɥɹ ɩɨɤɪɚɳɟɧɧɹ

ɬɨɜɚɪɧɢɯ ɹɤɨɫɬɟɣ ɜɢɪɨɳɟɧɨʀ ɩɪɨɞɭɤɰɿʀ ɩɨɪɹɞ ɡ ɩɟɫɬɢɰɢɞɚɦɢ ɜɫɟ ɱɚɫɬɿɲɟ ɜɢɤɨɪɢɫɬɨɜɭɸɬɶ ɪɟɝɭ

-ɥɹɬɨɪɢ ɪɨɫɬɭ ɪɨɫɥɢɧ.Ɍɚɤ,ɡɚ ɞɚɧɢɦɢ [13], ɫɩɿɥɶɧɟ

ɡɚɫɬɨɫɭɜɚɧɧɹ ɨɫɬɚɧɧɿɯ ɿɡ ɫɭɱɚɫɧɢɦɢ ɩɟɫɬɢɰɢɞ

-ɧɢɦɢ ɩɪɟɩɚɪɚɬɚɦɢ ɞɨɡɜɨɥɹɽ ɡɦɟɧɲɢɬɢ ɧɨɪɦɭ ɜɢɤɨɪɢɫɬɚɧɧɹ ɩɟɫɬɢɰɢɞɿɜ ɧɚ 20–25% ɛɟɡ ɡɧɢɠɟɧ

-ɧɹ ɡɚɯɢɫɧɨɝɨ ɟɮɟɤɬɭ.

Ⱦɥɹ ɡɚɯɢɫɬɭ ɹɛɥɭɧɟɜɢɯ ɫɚɞɿɜ ɭ ɧɚɲɿɣ ɤɪɚʀɧɿ ɪɟɤɨɦɟɧɞɨɜɚɧɿ ɬɚɤɿ ɫɭɱɚɫɧɿ ɩɪɟɩɚɪɚɬɢ: ɤɨɦɛɿɧɨ

-ɜɚɧɢɣ ɮɭɧɝɿɰɢɞ Ȼɟɥɥɿɫ (ɞ.ɪ. – ɩɿɪɚɤɥɨɫɬɪɨɛɿɧ ɬɚ

ɛɨɫɤɚɥɿɞ), ɿɧɫɟɤɬɨ-ɚɤɚɪɢɰɢɞ Ɇɚɫɚɣ (ɞ.ɪ. – ɬɟɛɭ

-ɮɟɧɩɿɪɚɞ)ɬɚ ɪɟɝɭɥɹɬɨɪ ɪɨɫɬɭ ɪɨɫɥɢɧ Ɋɟɝɚɥɿɫ (ɞ.ɪ. –ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɣ).ȼɿɞɨɦɨ,ɳɨ ɞ.ɪ.ɩɿɪɚɤɥɨ

-ɫɬɪɨɛɿɧ ɿ ɛɨɫɤɚɥɿɞ (ɿɧɲɚ ɧɚɡɜɚ – ɧɿɤɨɛɿɮɟɧ) ɞɨɫ

-ɬɚɬɧɶɨ ɱɚɫɬɨ ɩɨɽɞɧɭɸɬɶ ɜ ɨɞɧɨɦɭ ɮɭɧɝɿɰɢɞɧɨɦɭ ɩɪɟɩɚɪɚɬɿ (ɧɚɩɪɢɤɥɚɞ, ɋɿɝɧɭɦ ɬɚ ȱɧɲɭɪ ɉɪɨɮɿ).

ɓɨɞɨ ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ,ɬɨ

ɰɿ ɪɟɱɨɜɢɧɢ ɽ ɜɿɞɧɨɫɧɨ ɧɨɜɢɦɢ ɞɥɹ ɍɤɪɚʀɧɢ ɬɚ,

ɡɝɿɞɧɨ ɡ [8], ɧɚ ʀɯ ɨɫɧɨɜɿ ɞɥɹ ɡɚɯɢɫɬɭ ɹɛɥɭɧɟɜɢɯ

ɫɚɞɿɜ ɡɚɪɟɽɫɬɪɨɜɚɧɨ ɩɨ ɨɞɧɨɦɭ ɩɪɟɩɚɪɚɬɭ (Ɇɚɫɚɣ

ɬɚ Ɋɟɝɚɥɿɫ ɜɿɞɩɨɜɿɞɧɨ).

Ɂ ɟɤɨɥɨɝɨ-ɝɿɝɿɽɧɿɱɧɢɯ ɩɨɡɢɰɿɣ ɩɨɬɟɧɰɿɣɧɚ ɧɟ

-ɛɟɡɩɟɤɚ ɡɚɫɬɨɫɭɜɚɧɧɹ ɩɟɫɬɢɰɢɞɿɜ ɬɚ ɚɝɪɨɯɿɦɿɤɚɬɿɜ ɬɿɫɧɨ ɩɨɜ’ɹɡɚɧɚ ɡ ɨɫɨɛɥɢɜɨɫɬɹɦɢ ʀɯ ɩɨɜɟɞɿɧɤɢ ɜ

ɞɨɜɤɿɥɥɿ, ɡɨɤɪɟɦɚ ɡɿ ɫɬɿɣɤɿɫɬɸ ɭ ɜɨɞɿ. Ɉɫɤɿɥɶɤɢ,

ɡɝɿɞɧɨ ɡ ɝɿɝɿɽɧɿɱɧɨɸ ɤɥɚɫɢɮɿɤɚɰɿɽɸ ɩɟɫɬɢɰɢɞɿɜ

[9], ɛɨɫɤɚɥɿɞ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞ ɡɚ ɫɬɚɛɿɥɶɧɿɫɬɸ ɭ

ɜɨɞɿ ɧɚɥɟɠɚɬɶ ɞɨ I ɤɥɚɫɭ ɧɟɛɟɡɩɟɱɧɨɫɬɿ (ɜɢɫɨ

-ɤɨɫɬɿɣɤɿ),ɚ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶ

-ɰɿɣ – ɞɨ II ɤɥɚɫɭ ɧɟɛɟɡɩɟɱɧɨɫɬɿ (ɫɬɿɣɤɿ), ɬɨ ɞɭɠɟ

ɜɚɠɥɢɜɢɦ ɽ ɤɨɧɬɪɨɥɶ ɡɚ ʀɯ ɜɦɿɫɬɨɦ ɭ ɜɨɞɿ ɜɨɞɨɣɦ ɝɨɫɩɨɞɚɪɫɶɤɨ-ɩɢɬɧɨɝɨ ɬɚ ɤɭɥɶɬɭɪɧɨ-ɩɨɛɭɬɨɜɨɝɨ

ɩɪɢɡɧɚɱɟɧɧɹ.

ȼɪɚɯɨɜɭɸɱɢ ɦɨɠɥɢɜɿɫɬɶ ɨɞɧɨɱɚɫɧɨɝɨ ɜɢɤɨ

-ɪɢɫɬɚɧɧɹ ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɩɪɟɩɚɪɚɬɿɜ Ȼɟɥɥɿɫ,

Ɇɚɫɚɣ ɬɚ Ɋɟɝɚɥɿɫ ɭ ɫɢɫɬɟɦɿ ɯɿɦɿɱɧɨɝɨ ɡɚɯɢɫɬɭ ɹɛɥɭɧɶ,ɚɤɬɭɚɥɶɧɢɦ ɫɬɚɽ ɡɚɜɞɚɧɧɹ ɳɨɞɨ ɪɨɡɪɨɛɤɢ

ɦɟɬɨɞɭ ɜɢɡɧɚɱɟɧɧɹ ɭ ɜɨɞɿ ʀɯ ɞ.ɪ. ɩɪɢ ɫɭɦɿɫɧɿɣ

ɩɪɢɫɭɬɧɨɫɬɿ. ɐɟ ɞɨɡɜɨɥɢɥɨ ɛ ɡɧɚɱɧɨ ɩɪɢɫɤɨɪɢɬɢ

ɲɜɢɞɤɿɫɬɶ ɜɢɡɧɚɱɟɧɧɹ ɰɢɯ ɞ.ɪ. ɬɚ ɡɦɟɧɲɢɬɢ ɜɢ

-ɬɪɚɬɢ ɧɚ ɣɨɝɨ ɩɪɨɜɟɞɟɧɧɹ. Ɍɚɤɢɣ ɦɟɬɨɞ ɦɚɽ ɧɟ

ɥɢɲɟ ɟɤɨɧɨɦɿɱɧɟ,ɚ ɣ ɛɿɨɟɬɢɱɧɟ ɡɧɚɱɟɧɧɹ.

Ɋɚɧɿɲɟ ɮɚɯɿɜɰɹɦɢ ȱɧɫɬɢɬɭɬɭ ɟɤɨɝɿɝɿɽɧɢ ɿ ɬɨɤ

-ɫɢɤɨɥɨɝɿʀ ɿɦɟɧɿ Ʌ.ȱ.Ɇɟɞɜɟɞɹ ɛɭɜ ɪɨɡɪɨɛɥɟɧɢɣ

ɚɧɚɥɿɬɢɱɧɢɣ ɦɟɬɨɞ ɫɭɦɿɫɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɿɪɚ

-ɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɛɨɫɤɚɥɿɞɭ (ɧɿɤɨɛɿɮɟɧɭ) ɜ ɨɞɧɿɣ

ɩɪɨɛɿ ɜɨɞɢ [3]; ɮɚɯɿɜɰɹɦɢ ȱɧɫɬɢɬɭɬɭ ɝɿɝɿɽɧɢ ɬɚ

ɟɤɨɥɨɝɿʀ ɇɚɰɿɨɧɚɥɶɧɨɝɨ ɦɟɞɢɱɧɨɝɨ ɭɧɿɜɟɪɫɢɬɟɬɭ ɿɦɟɧɿ Ɉ.Ɉ.Ȼɨɝɨɦɨɥɶɰɹ – ɦɟɬɨɞɢ ɜɢɡɧɚɱɟɧɧɹ ɬɟ

-ɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ ɭ ɜɨɞɿ (ɬɚɛɥ. 1) [4, 5]. Ɇɟɬɨɞɢɤɢ ɡ ɜɢɡɧɚɱɟɧɧɹ ɩɿɪɚɤɥɨ

-ɫɬɪɨɛɿɧɭ, ɛɨɫɤɚɥɿɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ

ʉɪɭɧɬɭɜɚɥɢɫɶ ɧɚ ɜɢɫɨɤɨɟɮɟɤɬɢɜɧɿɣ ɪɿɞɢɧɧɿɣ ɯɪɨɦɚɬɨɝɪɚɮɿʀ (ȼȿɊɏ), ɦɟɬɨɞɢɤɚ ɡ ɜɢɡɧɚɱɟɧɧɹ

ɬɟɛɭɮɟɧɩɿɪɚɞɭ – ɧɚ ɝɚɡɨɪɿɞɢɧɧɿɣ ɯɪɨɦɚɬɨɝɪɚɮɿʀ (ȽɊɏ).

Ɍ ɚ ɛ ɥ ɢ ɰ ɹ 1

Ƚɿɝɿɽɧɿɱɧɿ ɧɨɪɦɚɬɢɜɢ ɬɚ ɦɟɠɿ ɤɿɥɶɤɿɫɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ,ɛɨɫɤɚɥɿɞɭ,

ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ ɭ ɜɨɞɿ

Ⱦɿɸɱɚ ɪɟɱɨɜɢɧɚ Ƚɿɝɿɽɧɿɱɧɢɣ_{ɧɨɪɦɚɬɢɜ} ɤɿɥɶɤɿɫɧɨɝɨɆɟɠɚ ɜɢɡɧɚɱɟɧɧɹ

ɇɨɦɟɪ ɦɟɬɨɞɢɱɧɢɯ

ɜɤɚɡɿɜɨɤ ɉɿɪɚɤɥɨɫɬɪɨɛɿɧ ȽȾɄ – 0,02 ɦɝ/ɞɦ3 _{0,01 ɦɝ/ɞɦ}3

Ȼɨɫɤɚɥɿɞ ȽȾɄ – 0,03 ɦɝ/ɞɦ3 _{0,01 ɦɝ/ɞɦ}3

ʋ 452-2003 (ɫɭɦɿɫɧɟ ɜɢɡɧɚɱɟɧɧɹ)

Ɍɟɛɭɮɟɧɩɿɪɚɞ ȽȾɄ – 0,004 ɦɝ/ɞɦ3 0,003 ɦɝ/ɞɦ3 ʋ 1078-2011

ɉɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɣ ȽȾɄ – 0,03 ɦɝ/ɞɦ3 _{0,01 ɦɝ/ɞɦ}3 _{ʋ 976-2010}

Ɂɚɡɧɚɱɟɧɟ ɡɭɦɨɜɢɥɨ ɦɟɬɭ ɧɚɲɨɝɨ ɞɨɫɥɿɞɠɟɧ

-ɧɹ, ɹɤɚ ɩɨɥɹɝɚɥɚ ɜ ɪɨɡɪɨɛɰɿ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ

ɦɟɬɨɞɭ ɚɧɚɥɿɬɢɱɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɿɪɚɤɥɨɫɬɪɨ

-ɛɿɧɭ, ɛɨɫɤɚɥɿɞɭ, ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ

-ɤɚɥɶɰɿɸ ɩɪɢ ɫɭɦɿɫɧɿɣ ɩɪɢɫɭɬɧɨɫɬɿ ɜ ɨɞɧɿɣ ɩɪɨɛɿ ɜɨɞɢ.

ɆȺɌȿɊȱȺɅɂ ɌȺ ɆȿɌɈȾɂ ȾɈɋɅȱȾɀȿɇɖ

Ⱦɥɹ ɞɨɫɹɝɧɟɧɧɹ ɦɟɬɢ ɛɭɥɨ ɧɟɨɛɯɿɞɧɨ ɨɛɪɚɬɢ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɢɣ ɦɟɬɨɞ, ɪɨɡɪɨɛɢɬɢ ɭɦɨɜɢ ɹɤɿɫ

-ɧɨʀ ɿɞɟɧɬɢɮɿɤɚɰɿʀ ɬɚ ɤɿɥɶɤɿɫɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɿ

-ɪɚɤɥɨɫɬɪɨɛɿɧɭ, ɛɨɫɤɚɥɿɞɭ, ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨ

-ɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ ɩɪɢ ɫɭɦɿɫɧɿɣ ɩɪɢɫɭɬɧɨɫɬɿ,

ɜɢɡɧɚɱɢɬɢ ɟɤɫɬɪɚɝɟɧɬɢ ɬɚ ɫɩɨɫɨɛɢ ɤɨɧɰɟɧɬɪɭ

-ɜɚɧɧɹ ɟɤɫɬɪɚɤɬɿɜ ɩɪɨɛ ɜɨɞɢ.

ɉɪɢ ɪɨɡɪɨɛɰɿ ɚɧɚɥɿɬɢɱɧɨɝɨ ɦɟɬɨɞɭ ɜɢɡɧɚ

-ɱɟɧɧɹ ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɫɩɨɥɭɤ ɜɢɤɨɪɢɫɬɨɜɭɜɚɥɢ ɚɧɚɥɿɬɢɱɧɿ ɫɬɚɧɞɚɪɬɢ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ,ɛɨɫɤɚɥɿɞɭ,

ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ ɡ ɜɦɿɫ

-ɬɨɦ ɞ.ɪ. 99,9 %; 100,0 %; 99,7 % ɬɚ 94,8 % ɜɿɞɩɨ

-ɜɿɞɧɨ. ɏɿɦɿɱɧɿ ɧɚɡɜɢ, ɫɬɪɭɤɬɭɪɧɿ ɮɨɪɦɭɥɢ ɬɚ

ɮɿɡɢɤɨ-ɯɿɦɿɱɧɿ ɜɥɚɫɬɢɜɨɫɬɿ ɞɨɫɥɿɞɠɭɜɚɧɢɯ

ɋɩɨɥɭɤɢ Ɉɡɧɚɤɢ

ɩɿɪɚɤɥɨɫɬɪɨɛɿɧ ɛɨɫɤɚɥɿɞ ɬɟɛɭɮɟɧɩɿɪɚɞ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɣ

ɇɚɡɜɚ

ɡɚ ȱɘɉȺɄ ɯɥɨɪɨɮɟɧɿɥɦɟɬɢɥ N-{2-[1-(4-)-1ɇ-ɩɿɪɚɡɨɥ

-3-ɿɥɨɤɫɢɦɟɬɢɥ]ɮɟɧɿɥ

}(N-ɦɟɬɨɤɫɢ)ɤɚɪɛɚɦɚɬ

2-ɯɥɨɪɨ

-N-(4´-ɯɥɨɪɨɛɿɮɟɧɿɥ

-2-ɿɥ)ɧɿɤɨɬɢɧɚɦɿɞ

N-(4-ɬɪɟɬ-ɛɭɬɢɥɛɟɧɡɢɥ )-4-ɯɥɨɪ-3-ɟɬɢɥ

-1-ɦɟɬɢɥɩɿɪɚɡɨɥ

-5-ɤɚɪɛɨɤɫɚɦɿɞ

ɤɚɥɶɰɿɸ 3-ɨɤɫɢɞɨ

-5-ɨɤɫɨ-4-ɩɪɨɩɿɨɧɿɥ

-3-ɰɢɤɥɨɝɟɤɫɚɧɤɚɪɛɨ

-ɤɫɢɥɚɬ ɏɿɦɿɱɧɚ ɮɨɪɦɭɥɚ

ȿɦɩɿɪɢɱɧɚ ɮɨɪɦɭɥɚ C19H18ClN3O4 C18H12Cl2N2O C18H24ClN3O ɋ10ɇ12O5ɋɚ

Ɇɨɥɟɤɭɥɹɪɧɚ ɦɚɫɚ,ɝ/ɦɨɥɶ 387,8 343,2 333,9 250,3

Ɍɟɦɩɟɪɚɬɭɪɚ ɩɥɚɜɥɟɧɧɹ,qɋ 63,7–65,2 142,8–143,8 64–66 >360

Ɍɢɫɤ ɧɚɫɢɱɟɧɨʀ ɩɚɪɢ,ɦɉɚ 2,6×10-5 (20 qɋ)

7,2×10-4 (20 qɋ)

<1×10-2 (25 qɋ)

1,33×10-2 (25 qɋ)

Ʉɨɟɮɿɰɿɽɧɬ ɪɨɡɩɨɞɿɥɭ Ʉow, logɊow

3,99 (22 qɋ) 2,96 (20 qɋ) 4,93 (25 qɋ) -2,9 (20 qɋ)

Ɋɨɡɱɢɧɧɿɫɬɶ ɭ ɜɨɞɿ,ɦɝ/ɥ 1,9 (20 qɋ) 4,6 (20 qɋ) 2,8 (25 qɋ) 786 (25 qɋ)

Ɋɨɡɱɢɧɧɿɫɬɶ ɜ ɨɪɝɚɧɿɱɧɢɯ ɪɨɡɱɢɧɧɢɤɚɯ (20 qɋ),ɦɝ/ɥ

ɚɰɟɬɨɧ – >5,0×105

ɦɟɬɚɧɨɥ – 1,0×105

ɨɤɬɚɧɨɥ – 2,4×104

ɝɟɩɬɚɧ – 3,7×103

ɚɰɟɬɨɧ – (1,6–2,0)×105

ɦɟɬɚɧɨɥ – (4,0– 5,0)×105

ɝɟɩɬɚɧ – <1,0×104

ɚɰɟɬɨɧ – 8,2×105

ɦɟɬɚɧɨɥ – 8,2×105

ɞɢɯɥɨɪɦɟɬɚɧ – 10,44×105

ɝɟɤɫɚɧ – 2,6×105

ɚɰɟɬɨɧ – 3,8×10-2

ɦɟɬɚɧɨɥ – 1,1

ɟɬɢɥɚɰɟɬɚɬ – 1,0×10-2

ɝɟɤɫɚɧ – 3,0×10-3

ȼɢɯɿɞɧɢɣ ɫɬɚɧɞɚɪɬɧɢɣ ɪɨɡɱɢɧ ɤɨɠɧɨʀ ɡ ɞɨ

-ɫɥɿɞɠɭɜɚɧɢɯ ɪɟɱɨɜɢɧ ɦɿɫɬɢɜ 100 ɦɤɝ ɫɩɨɥɭɤɢ ɜ 1ɦɥ ɪɨɡɱɢɧɧɢɤɚ. Ɂɦɿɲɭɜɚɧɧɹɦ ɬɚ ɩɨɫɥɿɞɨɜɧɢɦ

ɪɨɡɜɟɞɟɧɧɹɦ ɰɢɯ ɜɢɯɿɞɧɢɯ ɪɨɡɱɢɧɿɜ ɫɭɦɿɲɲɸ ɚɰɟɬɨɧɿɬɪɢɥ–0,1 % ɜɨɞɧɢɣ ɪɨɡɱɢɧ ɨɪɬɨɮɨɫɮɨɪ

-ɧɨʀ ɤɢɫɥɨɬɢ (50+50, ɡɚ ɨɛ’ɽɦɨɦ) ɝɨɬɭɜɚɥɢ 5

ɪɨɛɨɱɢɯ ɝɪɚɞɭɸɜɚɥɶɧɢɯ ɪɨɡɱɢɧɿɜ ɫɭɦɿɲɿ ɞɨɫɥɿɞ

-ɠɭɜɚɧɢɯ ɪɟɱɨɜɢɧ ɡ ɦɚɫɨɜɨɸ ɤɨɧɰɟɧɬɪɚɰɿɽɸ ɤɨɠ

-ɧɨʀ ɫɩɨɥɭɤɢ 0,5; 1; 2; 5 ɬɚ 10 ɦɤɝ/ɦɥ ɬɚ ɤɨɧɬɪɨɥɶ

-ɧɢɣ ɪɨɡɱɢɧ ɫɭɦɿɲɿ ɡ ɦɚɫɨɜɨɸ ɤɨɧɰɟɧɬɪɚɰɿɽɸ ɤɨɠɧɨʀ ɫɩɨɥɭɤɢ 6 ɦɤɝ/ɦɥ.

ɏɪɨɦɚɬɨɝɪɚɮɿɱɧɢɣ ɚɧɚɥɿɡ ɪɨɡɱɢɧɿɜ ɫɭɦɿɲɿ ɞɨ

-ɫɥɿɞɠɭɜɚɧɢɯ ɫɩɨɥɭɤ ɩɪɨɜɨɞɢɥɢ ɧɚ ɪɿɞɢɧɧɨɦɭ ɯɪɨɦɚɬɨɝɪɚɮɿ ɮɿɪɦɢ «ɒɢɦɚɞɡɭ» (əɩɨɧɿɹ) ɡ ɭɥɶ

-ɬɪɚɮɿɨɥɟɬɨɜɢɦ (ɍɎ) ɞɟɬɟɤɬɭɜɚɧɧɹɦ. ɋɩɨɱɚɬɤɭ

ɩɪɨɜɨɞɢɥɢ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɢɣ ɚɧɚɥɿɡ ɪɨɡɱɢɧɭ

ɤɨɠɧɨʀ ɪɟɱɨɜɢɧɢ ɞɥɹ ɩɨɞɚɥɶɲɨʀ ɿɞɟɧɬɢɮɿɤɚɰɿʀ ɩɿɤɚ ɤɨɧɤɪɟɬɧɨʀ ɫɩɨɥɭɤɢ ɧɚ ɯɪɨɦɚɬɨɝɪɚɦɿ ɫɭɦɿɲɿ.

ɉɿɫɥɹ ɜɢɛɨɪɭ ɨɩɬɢɦɚɥɶɧɢɯ ɭɦɨɜ ɪɨɡɞɿɥɟɧɧɹ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ, ɛɨɫɤɚɥɿɞɭ, ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ

ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ, ɯɪɨɦɚɬɨɝɪɚɮɭɜɚɧɧɹ ɤɨɠ

-ɧɨɝɨ ɝɪɚɞɭɸɜɚɥɶ-ɧɨɝɨ ɪɨɡɱɢɧɭ ɫɭɦɿɲɿ ɩɪɨɜɨɞɢɥɢ ɬɪɢɱɿ ɞɥɹ ɩɨɛɭɞɨɜɢ ɝɪɚɮɿɤɿɜ ɡɚɥɟɠɧɨɫɬɿ ɩɥɨɳɿ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɩɿɤɚ ɤɨɠɧɨʀ ɫɩɨɥɭɤɢ ɜɿɞ ɤɨɧɰɟɧɬɪɚɰɿʀ.

ȱɞɟɧɬɢɮɿɤɚɰɿɸ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ,ɛɨɫɤɚɥɿɞɭ,ɬɟ

-ɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ ɜ ɟɤɫɬɪɚɤ

-ɬɚɯ ɩɪɨɛ ɜɨɞɢ ɩɪɨɜɨɞɢɥɢ ɡɚ ɱɚɫɨɦ ɭɬɪɢɦɭɜɚɧɧɹ ɤɨɠɧɨʀ ɡ ɱɨɬɢɪɶɨɯ ɫɩɨɥɭɤ ɭ ɝɪɚɞɭɸɜɚɥɶɧɢɯ ɪɨɡɱɢɧɚɯ ɫɭɦɿɲɿ,ɤɿɥɶɤɿɫɧɟ ɜɢɡɧɚɱɟɧɧɹ – ɡɚ ɜɿɞɩɨ

ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ

ɪɨɡɱɢɧɿ, ɹɤɭ ɜɫɬɚɧɨɜɥɸɜɚɥɢ ɧɚ ɩɿɞɫɬɚɜɿ ɤɨɪɟɥɹ

-ɰɿɣɧɨɝɨ ɬɚ ɪɟɝɪɟɫɿɣɧɨɝɨ ɚɧɚɥɿɡɿɜ.

ɊȿɁɍɅɖɌȺɌɂ ɌȺ Ȳɏ ɈȻȽɈȼɈɊȿɇɇə

Ɂ ɭɪɚɯɭɜɚɧɧɹɦ ɮɿɡɢɤɨ-ɯɿɦɿɱɧɢɯ ɜɥɚɫɬɢɜɨɫɬɟɣ

ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɫɩɨɥɭɤ (ɞɢɜ. ɬɚɛɥ. 2): ɤɪɚɳɚ ɪɨɡ

-ɱɢɧɧɿɫɬɶ ɭ ɩɨɥɹɪɧɢɯ (ɦɟɬɚɧɨɥ, ɚɰɟɬɨɧ), ɧɿɠ ɭ

ɧɟɩɨɥɹɪɧɢɯ (ɝɟɤɫɚɧ, ɝɟɩɬɚɧ) ɪɨɡɱɢɧɧɢɤɚɯ, ɦɨɥɟ

-ɤɭɥɹɪɧɚ ɦɚɫɚ ɧɚ ɪɿɜɧɿ 3000 ɝ/ɦɨɥɶ ɬɚ ɞɨɫɬɚɬɧɶɨ

ɧɢɡɶɤɚ ɥɟɬɤɿɫɬɶ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɣ ɛɨɫɤɚɥɿɞɭ, ɫɟ

-ɪɟɞ ɭɫɿɯ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɢɯ ɦɟɬɨɞɿɜ ɦɢ ɨɛɪɚɥɢ ɦɟɬɨɞ ɨɛɟɪɧɟɧɨ-ɮɚɡɨɜɨʀ ȼȿɊɏ.Ʉɪɿɦ ɬɨɝɨ,ɜɿɞɨɦɢɣ

ɦɟɬɨɞ ɜɢɡɧɚɱɟɧɧɹ ɛɨɫɤɚɥɿɞɭ ɬɚ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɭ ɜɨɞɿ ɡ ɜɢɤɨɪɢɫɬɚɧɧɹɦ ȼȿɊɏ [3] ɛɭɜ ɨɛɪɚɧɢɣ ɹɤ

ɩɪɨɬɨɬɢɩ.

ɏɪɨɦɚɬɨɝɪɚɮɿɱɧɟ ɪɨɡɞɿɥɟɧɧɹ ɬɚ ɞɟɬɟɤɬɭɜɚɧɧɹ ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɫɩɨɥɭɤ ɽ ɜɚɠɥɢɜɢɦ ɟɬɚɩɨɦ ɦɟɬɨ

-ɞɢɤɢ ɜɢɤɨɧɚɧɧɹ ɜɢɦɿɪɸɜɚɧɶ. Ⱦɥɹ ɨɬɪɢɦɚɧɧɹ

ɚɞɟɤɜɚɬɧɢɯ ɪɟɡɭɥɶɬɚɬɿɜ ɜɢɡɧɚɱɟɧɧɹ ɞɨɫɥɿɞɠɭ

-ɜɚɧɢɯ ɪɟɱɨɜɢɧ ɩɪɢ ɫɭɦɿɫɧɿɣ ɩɪɢɫɭɬɧɨɫɬɿ ɧɟɨɛ

-ɯɿɞɧɨ ɛɭɥɨ ɜɫɬɚɧɨɜɢɬɢ ɨɩɬɢɦɚɥɶɧɿ ɭɦɨɜɢ ɯɪɨɦɚ

-ɬɨɝɪɚɮɭɜɚɧɧɹ ɫɭɦɿɲɿ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ,ɛɨɫɤɚɥɿɞɭ,

ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ: ɧɚɣ

-ɛɿɥɶɲ ɱɭɬɥɢɜɢɣ ɬɚ ɫɟɥɟɤɬɢɜɧɢɣ ɞɟɬɟɤɬɨɪ, ɩɪɢ

-ɞɚɬɧɿ ɧɟɪɭɯɨɦɭ ɬɚ ɪɭɯɨɦɭ ɮɚɡɢ, ɲɜɢɞɤɿɫɬɶ ɩɨ

-ɬɨɤɭ ɪɭɯɨɦɨʀ ɮɚɡɢ,ɦɿɧɿɦɚɥɶɧɭ ɤɿɥɶɤɿɫɬɶ ɪɟɱɨɜɢɧ,

ɳɨ ɞɟɬɟɤɬɭɸɬɶ, ɬɚ ɥɿɧɿɣɧɢɣ ɞɿɚɩɚɡɨɧ ɞɟɬɟɤ

-ɬɭɜɚɧɧɹ.

ɉɪɢ ɨɛɟɪɧɟɧɨ-ɮɚɡɨɜɿɣ ɯɪɨɦɚɬɨɝɪɚɮɿʀ ɧɟɪɭ

-ɯɨɦɚ ɮɚɡɚ ɧɟɩɨɥɹɪɧɚ, ɪɭɯɨɦɚ – ɞɭɠɟ ɩɨɥɹɪɧɚ (ɧɚɩɪɢɤɥɚɞ, ɜɨɞɧɿ ɪɨɡɱɢɧɢ ɚɰɟɬɨɧɿɬɪɢɥɭ ɱɢ

ɦɟɬɚɧɨɥɭ). ɇɚɣɩɨɲɢɪɟɧɿɲɨɸ ɧɟɪɭɯɨɦɨɸ ɮɚɡɨɸ

ɽ ɮɚɡɚ ɋ18,ɹɤɭ ɜɢɤɨɪɢɫɬɨɜɭɸɬɶ ɞɥɹ ɪɨɡɞɿɥɟɧɧɹ ɹɤ

ɧɟɩɨɥɹɪɧɢɯ, ɬɚɤ ɿ ɩɨɥɹɪɧɢɯ ɜɨɞɨɪɨɡɱɢɧɧɢɯ ɬɚ

ɦɚɥɨɩɨɥɹɪɧɢɯ ɫɩɨɥɭɤ. Ɍɨɦɭ ɹɤ ɧɟɪɭɯɨɦɭ ɮɚɡɭ

ɦɢ ɜɢɤɨɪɢɫɬɚɥɢ ɇɭɤɥɟɨɫɢɥ 100-5 ɋ18, ɹɤɢɦ ɛɭɥɚ

ɡɚɩɨɜɧɟɧɚ ɫɬɚɥɟɜɚ ɤɨɥɨɧɤɚ ɞɨɜɠɢɧɨɸ 25 ɫɦ,

ɜɧɭɬɪɿɲɧɿɦ ɞɿɚɦɟɬɪɨɦ 4,6 ɦɦ.

ȼɢɛɿɪ ɟɥɸɟɧɬɭ ɿɫɬɨɬɧɨ ɜɩɥɢɜɚɽ ɧɚ ɟɮɟɤɬɢɜ

-ɧɿɫɬɶ ɪɨɡɞɿɥɟɧɧɹ ɪɟɱɨɜɢɧ. ɉɪɢ ɩɿɞɛɨɪɿ ɪɭɯɨɦɨʀ

ɮɚɡɢ ɞɥɹ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɪɨɡɞɿɥɟɧɧɹ ɞɨɫɥɿɞ

-ɠɭɜɚɧɢɯ ɫɩɨɥɭɤ ɦɢ ɜɢɩɪɨɛɨɜɭɜɚɥɢ ɫɭɦɿɲɿ ɚɰɟ

-ɬɨɧɿɬɪɢɥ–ɜɨɞɚ, ɦɟɬɚɧɨɥ–ɜɨɞɚ, ɚɰɟɬɨɧɿɬɪɢɥ–ɜɨɞɧɿ

ɪɨɡɱɢɧɢ ɨɪɬɨɮɨɫɮɨɪɧɨʀ ɚɛɨ ɨɰɬɨɜɨʀ ɤɢɫɥɨɬ ɭ ɪɿɡɧɢɯ ɡɚ ɨɛ’ɽɦɨɦ ɫɩɿɜɜɿɞɧɨɲɟɧɧɹɯ. ȼɫɬɚɧɨɜ

-ɥɟɧɨ,ɳɨ ɨɩɬɢɦɚɥɶɧɨɸ ɞɥɹ ɟɥɸɸɜɚɧɧɹ ɞɨɫɥɿɞɠɭ

-ɜɚɧɢɯ ɫɩɨɥɭɤ ɽ ɫɭɦɿɲ ɚɰɟɬɨɧɿɬɪɢɥ–0,1 % ɜɨɞɧɢɣ

ɪɨɡɱɢɧ ɨɪɬɨɮɨɫɮɨɪɧɨʀ ɤɢɫɥɨɬɢ ɡ ɨɛ’ɽɦɧɨɸ ɜɢɬ

-ɪɚɬɨɸ 0,8 ɦɥ/ɯɜ. ȼɩɪɨɞɨɜɠ ɩɟɪɿɨɞɭ ɯɪɨɦɚɬɨɝɪɚ

-ɮɿɱɧɨɝɨ ɚɧɚɥɿɡɭ ɫɩɿɜɜɿɞɧɨɲɟɧɧɹ ɤɨɦɩɨɧɟɧɬɿɜ ɨɛ

-ɪɚɧɨʀ ɪɭɯɨɦɨʀ ɮɚɡɢ ɦɢ ɡɦɿɧɸɜɚɥɢ ɡɚɥɟɠɧɨ ɜɿɞ ɱɚɫɭ ɯɪɨɦɚɬɨɝɪɚɮɭɜɚɧɧɹ (ɬɚɛɥ. 3). Ɍɚɤɢɣ ɫɩɨɫɿɛ

ɞɨɡɜɨɥɢɜ ɧɚɦ ɧɚɣɛɿɥɶɲ ɱɿɬɤɨ ɜɿɡɭɚɥɿɡɭɜɚɬɢ ɞɨɫɥɿɞɠɭɜɚɧɿ ɪɟɱɨɜɢɧɢ ɩɪɢ ʀɯ ɫɭɦɿɫɧɿɣ ɩɪɢɫɭɬ

-ɧɨɫɬɿ ɜ ɨɞɧɿɣ ɩɪɨɛɿ ɜɨɞɢ.

Ɍ ɚ ɛ ɥ ɢ ɰ ɹ 3

Ɂɦɿɧɚ ɫɩɿɜɜɿɞɧɨɲɟɧɧɹ ɤɨɦɩɨɧɟɧɬɿɜ ɪɭɯɨɦɨʀ ɮɚɡɢ ɩɿɞ ɱɚɫ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɚɧɚɥɿɡɭ

ɋɩɿɜɜɿɞɧɨɲɟɧɧɹ ɤɨɦɩɨɧɟɧɬɿɜ ɪɭɯɨɦɨʀ ɮɚɡɢ, %

ɑɚɫ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɚɧɚɥɿɡɭ,ɯɜ.

ɚɰɟɬɨɧɿɬɪɢɥ 0,1 % ɜɨɞɧɢɣ ɪɨɡɱɢɧ ɨɪɬɨɮɨɫɮɨɪɧɨʀ ɤɢɫɥɨɬɢ

0–4,5 50 50 4,5–7,0 Ĺ ɞɨ 80 Ļ ɞɨ 20

7,0–15,0 80 20

15,0–20,0 Ļ ɞɨ 50 Ĺ ɞɨ 50

ɋɩɟɤɬɪɢ ɛɿɥɶɲɨɫɬɿ ɩɟɫɬɢɰɢɞɿɜ ɯɚɪɚɤɬɟɪɢɡɭɸ

-ɬɶɫɹ ɩɨɝɥɢɧɚɧɧɹɦ ɜ ɍɎ ɡɨɧɿ, ɚ ɪɨɡɱɢɧɧɢɤɢ, ɳɨ

ɡɚɡɜɢɱɚɣ ɜɢɤɨɪɢɫɬɨɜɭɸɬɶ ɜ ɨɛɟɪɧɟɧɨ-ɮɚɡɨɜɿɣ

ȼȿɊɏ (ɚɰɟɬɨɧɿɬɪɢɥ, ɦɟɬɚɧɨɥ, ɜɨɞɚ), ɩɪɨɡɨɪɿ ɞɥɹ

ɍɎ ɜɢɩɪɨɦɿɧɸɜɚɧɧɹ [1, 14]. Ɍɨɦɭ ɞɥɹ ɜɢɡɧɚ

-ɱɟɧɧɹ ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɫɩɨɥɭɤ ɦɢ ɜɢɤɨɪɢɫɬɚɥɢ ɍɎ ɞɟɬɟɤɬɨɪ ɡ ɞɟɣɬɟɪɿɽɜɨɸ ɥɚɦɩɨɸ. ɏɪɨɦɚɬɨɝɪɚ

-ɮɿɱɧɢɣ ɚɧɚɥɿɡ ɩɪɨɜɨɞɢɥɢ ɩɪɢ ɞɨɜɠɢɧɿ ɯɜɢɥɿ

250ɧɦ, ɹɤɚ, ɡɚ ɪɟɡɭɥɶɬɚɬɚɦɢ ɩɪɨɜɟɞɟɧɢɯ ɧɚɦɢ

ɞɨɫɥɿɞɠɟɧɶ ɡɚɥɟɠɧɨɫɬɿ ɪɨɡɦɿɪɭ ɩɿɤɚ ɧɚ ɯɪɨ

-ɦɚɬɨɝɪɚɦɿ ɜɿɞ ɞɨɜɠɢɧɢ ɯɜɢɥɿ ɍɎ ɩɪɨɦɟɧɿɜ,ɛɭɥɚ

ɜɢɡɧɚɧɚ ɧɚɣɛɿɥɶɲ ɜɞɚɥɨɸ ɞɥɹ ɨɞɧɨɱɚɫɧɨɝɨ ɞɟ

-ɬɟɤɬɭɜɚɧɧɹ ɜɫɿɯ ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɪɟɱɨɜɢɧ (ɪɢɫ. 1).

Ⱦɥɹ ɜɫɬɚɧɨɜɥɟɧɧɹ ɨɩɬɢɦɚɥɶɧɨʀ ɱɭɬɥɢɜɨɫɬɿ,

ɦɿɧɿɦɚɥɶɧɨʀ ɤɿɥɶɤɨɫɬɿ ɤɨɠɧɨʀ ɫɩɨɥɭɤɢ, ɳɨ ɞɟ

-ɬɟɤɬɭɽ, ɬɚ ɥɿɧɿɣɧɨɝɨ ɞɿɚɩɚɡɨɧɭ ɞɟɬɟɤɬɭɜɚɧɧɹ ɜ

ɿɧɠɟɤɬɨɪ ɯɪɨɦɚɬɨɝɪɚɮɚ ɡ ɩɟɬɥɟɸ 20 ɦɤɥ ɜɜɨɞɢɥɢ

ɪɨɛɨɱɿ ɝɪɚɞɭɸɜɚɥɶɧɿ ɪɨɡɱɢɧɢ ɫɭɦɿɲɿ ɩɿɪɚɤ

-ɥɨɫɬɪɨɛɿɧɭ, ɛɨɫɤɚɥɿɞɭ, ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨ

-ɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ ɡ ɪɿɡɧɢɦɢ ɤɨɧɰɟɧɬɪɚɰɿɹɦɢ,ɩɨ

-ɱɢɧɚɸɱɢ ɡ ɦɚɤɫɢɦɚɥɶɧɨʀ. Ⱥɧɚɥɿɡ ɩɪɨɜɨɞɢɥɢ ɩɪɢ

ɬɟɦɩɟɪɚɬɭɪɿ ɤɨɥɨɧɤɢ 30 °ɋ.ɋɬɚɬɢɫɬɢɱɧɚ ɨɛɪɨɛɤɚ

ɪɟɡɭɥɶɬɚɬɿɜ ɡɞɿɣɫɧɟɧɚ ɡɚ ɩɪɨɝɪɚɦɨɸ «Ʌɢɧɟɣɧɚɹ

ɪɟɝɪɟɫɫɢɹ ISO 84866-1» (ɜɟɪɫɿɹ 1.0, 2000 ɪ.) ɧɚ

ȼɫɬɚɧɨɜɥɟɧɨ, ɳɨ ɦɿɧɿɦɚɥɶɧɚ ɤɿɥɶɤɿɫɬɶ ɞɟɬɟɤ

-ɬɭɜɚɧɧɹ ɤɨɠɧɨʀ ɫɩɨɥɭɤɢ ɫɬɚɧɨɜɢɬɶ 10 ɧɝ, ɥɿɧɿɣ

-ɧɢɣ ɞɿɚɩɚɡɨɧ ɞɟɬɟɤɬɭɜɚɧɧɹ – (10–200) ɧɝ.ɑɚɫ ɭɬ

-ɪɢɦɭɜɚɧɧɹ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ, ɛɨɫɤɚɥɿɞɭ, ɩɿ

-ɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɡɚ ɰɢɯ ɭɦɨɜ ɯɪɨɦɚɬɨɝɪɚɮɭɜɚɧɧɹ ɫɬɚɧɨɜɢɬɶ 3,8±0,1; 9,5±0,1; 11,1±0,1 ɬɚ 12,8±0,1 ɯɜɢɥɢɧɢ ɜɿɞɩɨɜɿɞɧɨ. Ɍɢɩɨɜɚ

ɯɪɨɦɚɬɨɝɪɚɦɚ ɫɭɦɿɲɿ ɧɚɜɟɞɟɧɚ ɧɚ ɪɢɫ. 2.

Ɋɢɫ. 2. ɏɪɨɦɚɬɨɝɪɚɦɚ ɝɪɚɞɭɸɜɚɥɶɧɨɝɨ ɪɨɡɱɢɧɭ ɫɭɦɿɲɿ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ,ɛɨɫɤɚɥɿɞɭ, ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɡ ɦɚɫɨɜɨɸ ɤɨɧɰɟɧɬɪɚɰɿɽɸ 5 ɦɤɝ/ɦɥ ɤɨɠɧɨʀ ɫɩɨɥɭɤɢ

Ƚɪɚɞɭɸɜɚɥɶɧɿ ɝɪɚɮɿɤɢ ɡɚɥɟɠɧɨɫɬɿ ɩɥɨɳɿ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɩɿɤɚ ɫɩɨɥɭɤɢ (ɭɦ.ɨɞ.) ɜɿɞ

ɤɨɧɰɟɧɬɪɚɰɿʀ ɭ ɝɪɚɞɭɸɜɚɥɶɧɨɦɭ ɪɨɡɱɢɧɿ (ɦɤɝ/ɦɥ)

ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ

Ɋɢɫ. 3. Ƚɪɚɞɭɸɜɚɥɶɧɿ ɡɚɥɟɠɧɨɫɬɿ ɩɥɨɳɿ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɩɿɤɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ,ɛɨɫɤɚɥɿɞɭ, ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ (ɭɦ.ɨɞ.)ɜɿɞ ɤɨɧɰɟɧɬɪɚɰɿʀ ɭ ɝɪɚɞɭɸɜɚɥɶɧɨɦɭ ɪɨɡɱɢɧɿ (ɦɤɝ/ɦɥ)

Ƚɪɚɞɭɸɜɚɥɶɧɚ ɡɚɥɟɠɧɿɫɬɶ ɞɥɹ ɤɨɠɧɨʀ ɫɩɨɥɭɤɢ ɜɢɡɧɚɧɚ ɡɚɞɨɜɿɥɶɧɨɸ, ɨɫɤɿɥɶɤɢ ɡɧɚɱɟɧɧɹ ɤɨɟɮɿ

-ɰɿɽɧɬɚ ɤɨɪɟɥɹɰɿʀ ɡɧɚɯɨɞɢɥɨɫɶ ɭ ɦɟɠɚɯ ɜɿɞ 0,8 ɞɨ 1,0 (ɧɚ ɪɿɜɧɿ 0,9).

Ƚɪɚɞɭɸɜɚɥɶɧɿ ɡɚɥɟɠɧɨɫɬɿ ɩɥɨɳɿ ɯɪɨɦɚɬɨɝɪɚ

-ɮɿɱɧɨɝɨ ɩɿɤɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ, ɛɨɫɤɚɥɿɞɭ,

ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɜɿɞ ɤɨɧɰɟɧ

-ɬɪɚɰɿʀ ɭ ɝɪɚɞɭɸɜɚɥɶɧɨɦɭ ɪɨɡɱɢɧɿ ɨɩɢɫɚɧɿ ɪɿɜɧɹɧ

-ɧɹɦɢ ɥɿɧɿɣɧɨʀ ɪɟɝɪɟɫɿʀ:

hpr= 26,9+38419,0×ȡ, (1)

hb= 3255,1+73793,6×ȡ, (2)

hp= 2078,9+30497,2×ȡ, (3)

ht= 1078,3+38487,8×ȡ, (4)

ɞɟ: hpr, hb, hp, ht – ɩɥɨɳɚ ɩɿɤɚ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ, ɛɨɫɤɚɥɿɞɭ,

ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ,ɭɦ.ɨɞ.;

ȡ – ɦɚɫɨɜɚ ɤɨɧɰɟɧɬɪɚɰɿɹ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ, ɛɨɫɤɚɥɿɞɭ,

ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɜ ɝɪɚɞɭɸɜɚɥɶɧɨɦɭ ɪɨɡɱɢɧɿ,

ɦɤɝ/ɦɥ.

Ɉɞɟɪɠɚɧɧɹ ɞɨɫɬɨɜɿɪɧɢɯ ɪɟɡɭɥɶɬɚɬɿɜ ɹɤɿɫɧɨɝɨ ɬɚ ɤɿɥɶɤɿɫɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɟɫɬɢɰɢɞɭ ɭ ɜɨɞɿ ɡɚɥɟɠɢɬɶ ɜɿɞ ɩɨɩɟɪɟɞɧɿɯ ɫɬɚɞɿɣ ɩɪɨɛɨɩɿɞɝɨɬɨɜɤɢ.

Ɍɨɦɭ ɧɚɫɬɭɩɧɢɦ ɟɬɚɩɨɦ ɧɚɲɨɝɨ ɞɨɫɥɿɞɠɟɧɧɹ ɛɭɥɚ ɪɨɡɪɨɛɤɚ ɫɩɨɫɨɛɭ ɩɿɞɝɨɬɨɜɤɢ ɩɪɨɛ ɜɨɞɢ ɞɨ ɩɨɞɚɥɶɲɨɝɨ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɜ ɧɢɯ ɞɨɫɥɿɞɠɭɜɚɧɢɯ ɫɩɨɥɭɤ. Ɋɨɡɪɨɛɥɟɧɢɣ ɧɚɦɢ

ɫɩɨɫɿɛ ʉɪɭɧɬɭɽɬɶɫɹ ɧɚ ɩɿɞɝɨɬɨɜɰɿ ɩɪɨɛɢ ɜɨɞɢ ɞɨ ɟɤɫɬɪɚɤɰɿʀ,ɜɢɥɭɱɟɧɧɿ ɩɪɨɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ,ɛɨɫ

-ɤɚɥɿɞɭ, ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɡ ɩɪɨ

-ɛɢ,ɩɿɞɫɭɲɭɜɚɧɧɿ ɬɚ ɤɨɧɰɟɧɬɪɭɜɚɧɧɿ ɟɤɫɬɪɚɤɬɭ.

ɉɿɞɝɨɬɨɜɤɚ ɩɪɨɛɢ ɜɨɞɢ ɞɨ ɟɤɫɬɪɚɤɰɿʀ ɩɨɥɹɝɚɥɚ ɜ ɞɨɞɚɜɚɧɧɿ 50 ɦɥ ɚɰɟɬɨɧɭ ɞɨ 500 ɦɥ ɜɨɞɢ ɬɚ

ɩɿɞɤɢɫɥɟɧɧɿ ɤɨɧɰɟɧɬɪɨɜɚɧɨɸ ɯɥɨɪɨɜɨɞɧɟɜɨɸ ɤɢ

-ɫɥɨɬɨɸ ɞɨ pH 3 (ɤɨɧɬɪɨɥɶ pH ɩɪɨɜɨɞɢɥɢ ɡɚ ɿɧɞɢ

-ɤɚɬɨɪɧɢɦ ɩɚɩɟɪɨɦ). Ⱦɥɹ ɜɢɥɭɱɟɧɧɹ ɩɪɨɝɟɤɫɚ

-ɞɿɨɧ-ɤɚɥɶɰɿɸ, ɛɨɫɤɚɥɿɞɭ, ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɿ ɬɟɛɭ

-ɮɟɧɩɿɪɚɞɭ ɡ ɩɪɨɛɢ ɜɨɞɢ ɛɭɥɚ ɜɢɤɨɪɢɫɬɚɧɚ ɪɿ

-ɞɢɧɧɚ ɟɤɫɬɪɚɤɰɿɹ, ɹɤɚ ɡɚɜɞɹɤɢ ɫɜɨʀɦ ɯɚɪɚɤɬɟ

-ɪɢɫɬɢɤɚɦ (ɭɧɿɜɟɪɫɚɥɶɧɿɫɬɶ, ɧɟɬɪɢɜɚɥɿɫɬɶ ɨɩɟɪɚ

-ɰɿɣ, ɟɤɫɩɪɟɫɧɿɫɬɶ ɬɚ ɜɿɞɫɭɬɧɿɫɬɶ ɪɭɣɧɚɰɿʀ ɞɨɫɥɿɞ

-ɠɭɜɚɧɢɯ ɤɨɦɩɨɧɟɧɬɿɜ) ɡɚɥɢɲɚɽɬɶɫɹ ɨɞɧɢɦ ɡ

ɧɚɣɩɨɲɢɪɟɧɿɲɢɯ ɦɟɬɨɞɿɜ ɜɢɥɭɱɟɧɧɹ ɩɟɫɬɢɰɢɞɿɜ ɡ ɪɿɡɧɢɯ ɦɚɬɪɢɰɶ [1, 11]. ȼɢɥɭɱɟɧɧɹ ɞɨɫɥɿɞɠɭɜɚ

-ɧɢɯ ɪɟɱɨɜɢɧ ɩɪɨɜɨɞɢɥɢ ɫɭɦɿɲɲɸ ɝɟɤɫɚɧ–ɞɢ

-ɯɥɨɪɦɟɬɚɧ (1+1, ɡɚ ɨɛ’ɽɦɨɦ)ɲɥɹɯɨɦ ɬɪɢɪɚɡɨɜɨɝɨ

ɫɬɪɭɲɭɜɚɧɧɹ ɜ ɞɿɥɢɥɶɧɿɣ ɥɿɣɰɿ.ɉɿɫɥɹ ɪɨɡɞɿɥɟɧɧɹ

ɲɚɪɿɜ ɡɛɢɪɚɥɢ ɨɪɝɚɧɿɱɧɢɣ (ɜɟɪɯɧɿɣ) ɲɚɪ. Ɉɛ’ɽɞ

-ɧɚɧɢɣ ɟɤɫɬɪɚɤɬ ɩɿɞɫɭɲɭɜɚɥɢ ɛɟɡɜɨɞɧɢɦ ɫɭɥɶ

-ɮɚɬɨɦ ɧɚɬɪɿɸ. ȿɤɫɬɪɚɤɬ ɩɟɪɟɧɨɫɢɥɢ ɭ ɝɪɭɲɨ

-ɩɨɞɿɛɧɭ ɤɨɥɛɭ ɞɥɹ ɜɿɞɝɨɧɭ ɪɨɡɱɢɧɧɢɤɿɜ ɬɚ ɤɨɧ

-ɰɟɧɬɪɭɜɚɥɢ ɧɚ ɪɨɬɚɰɿɣɧɨɦɭ ɜɢɩɚɪɧɢɤɭ. ɋɭɯɢɣ

ɡɚɥɢɲɨɤ ɪɨɡɱɢɧɹɥɢ ɜ 2 ɦɥ ɫɭɦɿɲɿ ɚɰɟɬɨɧɿɬɪɢɥ– 0,1 % ɜɨɞɧɢɣ ɪɨɡɱɢɧ ɨɪɬɨɮɨɫɮɨɪɧɨʀ ɤɢɫɥɨɬɢ (50+50, ɡɚ ɨɛ’ɽɦɨɦ), ɚɥɿɤɜɨɬɭ ɩɪɨɛɢ (20 ɦɤɥ)

ɱɢɫɥɸɜɚɥɢ, ɜɢɤɨɪɢɫɬɨɜɭɸɱɢ ɜɿɞɩɨɜɿɞɧɭ ɝɪɚɞɭ

-ɸɜɚɥɶɧɭ ɡɚɥɟɠɧɿɫɬɶ.

Ɋɨɡɪɨɛɥɟɧɿ ɧɚɦɢ ɨɩɬɢɦɚɥɶɧɿ ɭɦɨɜɢ ɟɤɫɬɪɚɤɰɿʀ,

ɨɱɢɳɟɧɧɹ ɬɚ ɯɪɨɦɚɬɨɝɪɚɮɿɱɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɪɨ

-ɝɟɤɫɚɞɿɨɧ-ɤɚɥɶɰɿɸ, ɛɨɫɤɚɥɿɞɭ, ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɬɚ

ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɩɪɢ ɫɭɦɿɫɧɿɣ ɩɪɢɫɭɬɧɨɫɬɿ ɜ ɩɪɨɛɿ ɜɨɞɢ ɛɭɥɢ ɩɨɤɥɚɞɟɧɿ ɜ ɨɫɧɨɜɭ ɩɚɬɟɧɬɭ ɧɚ ɤɨ

-ɪɢɫɧɭ ɦɨɞɟɥɶ [6]. ȼɂɋɇɈȼɄɂ

1. Ɋɨɡɪɨɛɥɟɧɨ ɭɦɨɜɢ ɫɭɦɿɫɧɨɝɨ ɜɢɡɧɚɱɟɧɧɹ ɩɿ

-ɪɚɤɥɨɫɬɪɨɛɿɧɭ, ɛɨɫɤɚɥɿɞɭ, ɬɟɛɭɮɟɧɩɿɪɚɞɭ ɬɚ ɩɪɨ

-ɩɪɢɫɤɨɪɢɬɢ ɚɧɚɥɿɡ ɬɚ ɡɦɟɧɲɢɬɢ ɜɢɬɪɚɬɢ ɧɚ ɣɨɝɨ ɩɪɨɜɟɞɟɧɧɹ.

2. ȼɩɪɨɜɚɞɠɟɧɧɹ ɪɨɡɪɨɛɥɟɧɨɝɨ ɬɚ ɡɚɩɚɬɟɧ

-ɬɨɜɚɧɨɝɨ ɦɟɬɨɞɭ ɜ ɩɪɚɤɬɢɤɭ ɪɨɛɨɬɢ ɭɫɬɚɧɨɜ Ⱦɟɪɠɚɜɧɨʀ ɫɚɧɿɬɚɪɧɨ-ɟɩɿɞɟɦɿɨɥɨɝɿɱɧɨʀ ɫɥɭɠɛɢ ɬɚ

Ɇɿɧɿɫɬɟɪɫɬɜɚ ɟɤɨɥɨɝɿʀ ɬɚ ɩɪɢɪɨɞɧɢɯ ɪɟɫɭɪɫɿɜ ɍɤɪɚʀɧɢ ɫɩɪɢɹɬɢɦɟ ɤɨɧɬɪɨɥɸ ɡɚ ɡɚɫɬɨɫɭɜɚɧɧɹɦ ɭ ɫɿɥɶɫɶɤɨɦɭ ɝɨɫɩɨɞɚɪɫɬɜɿ ɩɪɟɩɚɪɚɬɿɜ ɧɚ ʀɯ ɨɫɧɨɜɿ,

ɭɞɨɫɤɨɧɚɥɟɧɧɸ ɦɨɧɿɬɨɪɢɧɝɭ ɩɟɫɬɢɰɢɞɿɜ ɭ ɜɨɞɿ ɜɨɞɨɣɦ ɬɚ ɩɪɨɜɟɞɟɧɧɸ ɡɚɯɨɞɿɜ ɡ ɦɿɧɿɦɿɡɚɰɿʀ ʀɯ ɲɤɿɞɥɢɜɨʀ ɞɿʀ ɧɚ ɡɞɨɪɨɜ’ɹ ɧɚɫɟɥɟɧɧɹ.

ɋ

ɋ

ɉ

ɉ

ɂ

ɂ

ɋ

ɋ

Ɉ

Ɉ

Ʉ

Ʉ

Ʌ

Ʌ

ȱ

ȱ

Ɍ

Ɍ

ȿ

ȿ

Ɋ

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Ⱥ

Ⱥ

Ɍ

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ɩɟɫ-ɬɢɰɢɞɿɜ: (ɧɚɜɱ.ɩɨɫɿɛɧɢɤ) / Ɇ.Ⱥ.Ʉɥɢɫɟɧɤɨ,Ʌ.Ƚ.Ⱥɥɟɤ -ɫɚɧɞɪɨɜɚ,ȼ.Ɏ.Ⱦɟɦɱɟɧɤɨ,Ɍ.Ʌ.Ɇɚɤɚɪɱɭɤ. – Ʉ.: ȿɄɈ-ȽȱɇɌɈɄɋ, 1999. – 238 ɫ.

2. Ȼɨɫɤɚɥɢɞ: Ʉɚɬɚɥɨɝ ɩɟɫɬɢɰɢɞɨɜ: PPDB. – Ɋɟ-ɠɢɦ ɞɨɫɬɭɩɚ: http://rupest.ru/ppdb/boscalid.html.

3. Ɇɟɬɨɞɢɱɧɿ ɜɤɚɡɿɜɤɢ ɡ ɜɢɡɧɚɱɟɧɧɹ ɧɿɤɨɛɿɮɟɧɭ ɬɚ ɩɿɪɚɤɥɨɫɬɪɨɛɿɧɭ ɭ ɜɨɞɿ ɦɟɬɨɞɨɦ ɜɢɫɨɤɨɟɮɟɤɬɢɜɧɨʀ ɪɿɞɢɧɧɨʀ ɯɪɨɦɚɬɨɝɪɚɮɿʀ:Ɇȼ ʋ 452-2003 // Ɇɟɬɨɞɢɱɧɿ ɜɤɚɡɿɜɤɢ ɡ ɜɢɡɧɚɱɟɧɧɹ ɦɿɤɪɨɤɿɥɶɤɨɫɬɟɣ ɩɟɫɬɢɰɢɞɿɜ ɜ ɯɚɪɱɨɜɢɯ ɩɪɨɞɭɤɬɚɯ,ɤɨɪɦɚɯ ɬɚ ɧɚɜɤɨɥɢɲɧɶɨɦɭ ɫɟɪɟ -ɞɨɜɢɳɿ. – Ʉ., 2007 ɪɿɤ. – Ɂɛɿɪɤɚ ʋ 45. – ɋ. 104–116.

4. Ɇɟɬɨɞɢɱɧɿ ɜɤɚɡɿɜɤɢ ɡ ɜɢɡɧɚɱɟɧɧɹ ɩɪɨɝɟɤɫɚ -ɞɿɨɧ-ɤɚɥɶɰɿɸ ɭ ɜɨɞɿ ɦɟɬɨɞɨɦ ɜɢɫɨɤɨɟɮɟɤɬɢɜɧɨʀ ɪɿɞɢɧ -ɧɨʀ ɯɪɨɦɚɬɨɝɪɚɮɿʀ:Ɇȼ ʋ 976-2010 // ɉɨɝɨɞɠɟɧɨ ɆɈɁ 26.02.2010; ɉɨɫɬɚɧɨɜɚ ʋ 7, ɡɚɬɜɟɪɞɠɟɧɨ Ɇɿɧɿɫɬɟɪɫɬ-ɜɨɦ ɨɯɨɪɨɧɢ ɧɚɜɤɨɥɢɲɧɶɨɝɨ ɩɪɢɪɨɞɧɨɝɨ ɫɟɪɟɞɨɜɢɳɚ 11.06.2010, ɇɚɤɚɡ ʋ 239.

5. Ɇɟɬɨɞɢɱɧɿ ɜɤɚɡɿɜɤɢ ɡ ɜɢɡɧɚɱɟɧɧɹ ɬɟɛɭɮɟɧ-ɩɿɪɚɞɭ ɭ ɜɨɞɿ ɦɟɬɨɞɨɦ ɝɚɡɨɪɿɞɢɧɧɨʀ ɯɪɨɦɚɬɨɝɪɚɮɿʀ: Ɇȼ ʋ 1078-2011: ɉɨɝɨɞɠɟɧɨ ɆɈɁ 01.03.2011; ɉɨɫɬɚ -ɧɨɜɚ ʋ 6, ɡɚɬɜɟɪɞɠɟɧɨ Ɇɿɧɿɫɬɟɪɫɬɜɨɦ ɟɤɨɥɨɝɿʀ ɬɚ ɩɪɢɪɨɞɧɢɯ ɪɟɫɭɪɫɿɜ ɍɤɪɚʀɧɢ 25.03.2011, ɇɚɤɚɡ ʋ 95.

6. ɉɚɬ. 76331 UA, ɆɉɄ G01N 33/00 (2012.01). ɋɩɨɫɿɛ ɜɢɡɧɚɱɟɧɧɹ ɬɪɶɨɯ ɩɟɫɬɢɰɢɞɿɜ ɬɚ ɪɟɝɭɥɹɬɨɪɚ ɪɨɫɬɭ ɪɨɫɥɢɧ ɜ ɨɞɧɿɣ ɩɪɨɛɿ ɜɨɞɢ / Ȼɚɪɞɨɜ ȼ.Ƚ., ɋɟɦɟ-ɧɟɧɤɨ ȼ.Ɇ.,Ʉɨɪɲɭɧ Ɇ.Ɇ., Ƚɢɪɟɧɤɨ Ⱦ.Ȼ,Ʉɨɪɲɭɧ Ɉ.Ɇ., Ʌɿɩɚɜɫɶɤɚ Ⱥ.Ɉ.; ɜɥɚɫɧɢɤ ɧɚɰ. ɦɟɞ. ɭɧ-ɬ ɿɦ.Ɉ.Ɉ. Ȼɨɝɨ-ɦɨɥɶɰɹ. – ʋ u201209218; ɡɚɹɜɥ. 27.07.12; ɨɩɭɛɥ. 25.12.12, Ȼɸɥ.ʋ 24.

7. ɉɟɪɟɥɿɤ ɩɟɫɬɢɰɢɞɿɜ ɿ ɚɝɪɨɯɿɦɿɤɚɬɿɜ, ɞɨɡɜɨɥɟ-ɧɢɯ ɞɨ ɜɢɤɨɪɢɫɬɚɧɧɹ ɜ ɍɤɪɚʀɧɿ. – Ʉ. : ɘɧɿɜɟɫɬ Ɇɚɪɤɟ-ɬɢɧɝ, 2001. – 272 ɫ.

8. ɉɟɪɟɥɿɤ ɩɟɫɬɢɰɢɞɿɜ ɿ ɚɝɪɨɯɿɦɿɤɚɬɿɜ, ɞɨɡɜɨ-ɥɟɧɢɯ ɞɨ ɜɢɤɨɪɢɫɬɚɧɧɹ ɜ ɍɤɪɚʀɧɿ. – Ʉ.: ɘɧɿɜɟɫɬ Ɇɟ-ɞɿɚ, 2012. – 832 ɫ.

9. ɉɟɫɬɢɰɢɞɢ. Ʉɥɚɫɢɮɿɤɚɰɿɹ ɡɚ ɫɬɭɩɟɧɟɦ ɧɟɛɟɡ -ɩɟɱɧɨɫɬɿ:Ⱦɋɚɧɉɿɧ 8.8.1.002-98 – (Ɂɚɬɜ. 28.08.98) // Ɂɛ. ɜɚɠɥɢɜɢɯ ɨɮɿɰɿɣɧɢɯ ɦɚɬɟɪɿɚɥɿɜ ɡ ɫɚɧɿɬɚɪɧɢɯ ɿ ɩɪɨɬɢ -ɟɩɿɞɟɦɿɱɧɢɯ ɩɢɬɚɧɶ. – Ʉ., 2000. – Ɍ. 9, ɱ. 1. – ɋ. 249-266.

10. ɉɢɪɚɤɥɨɫɬɪɨɛɢɧ: Ʉɚɬɚɥɨɝ ɩɟɫɬɢɰɢɞɨɜ: PPDB. –Ɋɟɠɢɦ ɞɨɫɬɭɩɚ: http://rupest.ru/ppdb/pyraclostrobin.html.

11. ɉɪɢɦɟɧɟɧɢɟ ɠɢɞɤɨɫɬɧɨɣ ɷɤɫɬɪɚɤɰɢɢ ɜ ɚɧɚɥɢɡɟ ɜɨɞɨɪɚɫɬɜɨɪɢɦɵɯ ɜɢɬɚɦɢɧɨɜ / ɇ.ə.Ɇɨɤɲɢɧɚ,Ɉ.ȼ. ȿɪɢ-ɧɚ , Ƚ.ȼ. ɒɚɬɚɥɨɜ, Ⱦ.ȼ. Ȼɵɤɨɜɫɤɢɣ // Ⱥɧɚɥɢɬɢɤɚ ɢ ɚɧɚɥɢɬɢɤɢ:ɞɪɭɝɢɣ ɦɿɠɧɚɪ.ɮɨɪɭɦ, 22–26 ɜɟɪɟɫɧɹ 2008 ɪ.: ɪɟɮɟɪɚɬɢ ɞɨɤɥ. – ȼɨɪɨɧɟɠ, 2008. – Ɍ. 2. – ɋ. 481.

12. ɉɪɨɝɟɤɫɚɞɢɨɧ-ɤɚɥɰɢɭɦ: Ʉɚɬɚɥɨɝ ɩɟɫɬɢɰɢɞɨɜ: PPDB. – Ɋɟɠɢɦ ɞɨɫɬɭɩɚ: http://rupest.ru/ppdb/prohexadione-calcium.html.

13. Ɋɟɝɭɥɹɬɨɪɢ ɪɨɫɬɭ ɪɨɫɥɢɧ. – Ɋɟɠɢɦ ɞɨɫɬɭɩɭ: http://www.agrobiotech.com.ua/ua/about/.

14. ɋɚɞɟɤ ɉ. Ɋɚɫɬɜɨɪɢɬɟɥɢ ɞɥɹ ȼɗɀɏ / ɉɨɥ ɋɚ-ɞɟɤ. – Ɇ.: ȻɂɇɈɆ.Ʌɚɛɨɪɚɬɨɪɢɹ ɡɧɚɧɢɣ, 2006. – 704 ɫ.

15. Ɍɟɛɭɮɟɧɩɢɪɚɞ: Ʉɚɬɚɥɨɝ ɩɟɫɬɢɰɢɞɨɜ: PPDB. – Ɋɟɠɢɦ ɞɨɫɬɭɩɚ: http://rupest.ru/ppdb/tebufenpyrad.html.

16. The e-Pesticide Manual: A World Compendium The e-Pesticide Manual / Version 3.2 2005–06. – Thir-teenth Edition: ɋD-ɜɢɞ-ɜɨ CDS Tomlin, 2005. – 1 ɟɥɟɤ-ɬɪɨɧ.ɨɩɬ.ɞɢɫɤ (CD-R); 12 ɫɦ. – ɋɢɫɬɟɦ.ɜɢɦɨɝɢ: Pentium; 32 Mb RAM; CD-ROM Windows 95/98/2000/NT/XP. – ɇɚɡɜɚ ɡ ɬɢɬɭɥ.ɟɤɪɚɧɭ.

R

R

E

E

F

F

E

E

R

R

E

E

N

N

C

C

E

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S

S

1. Klisenko MA, Aleksandrova LG, Demchen-ko VF, Makarchuk TL. Analytical chemistry of pesticide residues: (navch. posɿbnik). EKOGȱNTOKS. 1999;238.

2. http://rupest.ru/ppdb/boscalid.html

3. MG N 452-2003. Methodological guidelines for the determination of nikobifen and pyraclostrobin in water by high performance liquid chromatography. Methodological guidelines for the determination of trace

amounts of pesticides in food, feed and the environment. 2007;45:104-16.

ɉɊɈɎȱɅȺɄɌɂɑɇȺ ɆȿȾɂɐɂɇȺ

5. MG N 1078-2011. Methodological guidelines for the determination of tebufenpyrad in water by gas-liquid chromatography. Ministry of Health approved 01.03.2011, Decree number 6, approved by the Ministry of Ecology and Natural Resources of Ukraine 25.03.2011, Order number 95.

6. Bardov VG, Semenenko VM, Korshun MM, Gi-renko DB, Korshun OM, Lɿpavs'ka AO. Pat. 76331 UA, MPK G01N 33/00 (2012.01). Method of determination of three pesticides and plant growth regulator in a water sample. Owner is O.O. Bogomolets National Medical University. N u201209218; appl. 27.07.12, publ. 12.25.12, Bull. number 24.

7. The list of pesticides and agrochemicals permitted for use in Ukraine. Univest Marketing. 2001;272.

8. The list of pesticides and agrochemicals permitted for use in Ukraine. Unɿvest Marketing. 2012;832.

9. SSanRN 8.8.1.002-98. Pesticides. Classification according to the degree of hazard. Collection of important

official materials of sanitary and epidemiological issues. 2000;9(1):249-66.

10. http://rupest.ru/ppdb/pyraclostrobin.html

11. Mokshina NYa, Erina OV, Shatalov GV, Bykovs-kiy DV. Application liquid extraction in the analysis of water soluble vitamins. Analytics and analysts: the second International Forum, 22-26 September 2008: abstracts of reports. 2008;2:481.

12. http://rupest.ru/ppdb/prohexadione-calcium.html 13. http://www.agrobiotech.com.ua/ua/about/ 14. Sadek P. Solvents for HPLC. BINOM. Know-ledge laboratory. 2006:704.

15. http://rupest.ru/ppdb/tebufenpyrad.html

16. The e-Pesticide Manual: A World Compendium The e-Pesticide Manual. Version 3.2 2005–06. Thirteenth Edition: CD-vid-vo CDS Tomlin, 2005. 1 electron. who-lesale. CD (CD-R); 12 sm. System. Requirements: Pentium; 32 Mb RAM; CD-ROM Windows 95/98/2000/NT/XP.

ɍȾɄ 613.86:37.03-053.66/.67 ȱ.ȼ.ɋɟɪɝɟɬɚ,

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ȼɿɧɧɢɰɶɤɢɣ ɧɚɰɿɨɧɚɥɶɧɢɣ ɦɟɞɢɱɧɢɣ ɭɧɿɜɟɪɫɢɬɟɬ ɿɦɟɧɿ Ɇ.ȱ.ɉɢɪɨɝɨɜɚ ɤɚɮɟɞɪɚ ɡɚɝɚɥɶɧɨʀ ɝɿɝɿɽɧɢ ɬɚ ɟɤɨɥɨɝɿʀ

(ɡɚɜ. – ɞ.ɦɟɞ.ɧ.,ɩɪɨɮ.ȱ.ȼ.ɋɟɪɝɟɬɚ) ɜɭɥ.ɉɢɪɨɝɨɜɚ, 56, ȼɿɧɧɢɰɹ, 21018, ɍɤɪɚʀɧɚ

Vinnytsya National Medical University named after Pirogov Department of General Hygiene and Ecology

Pirogov Str., 56, Vinnitsa, 21018, Ukraine e-mail: serheta@mail.ru

Ʉɥɸɱɨɜɿ ɫɥɨɜɚ:ɲɤɨɥɚ,ɭɱɧɿ 14-17 ɪɨɤɿɜ,ɜɥɚɫɬɢɜɨɫɬɿ ɯɚɪɚɤɬɟɪɭ,ɩɫɢɯɨɝɿɝɿɽɧɿɱɧɚ ɨɰɿɧɤɚ

Key words: school, pupils 14-17 years old, properties of character, psychohygienic estimation