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ISSN 0104-6632 Printed in Brazil

www.abeq.org.br/bjche

Vol. 33, No. 04, pp. 1083 - 1090, October - December, 2016 dx.doi.org/10.1590/0104-6632.20160334s20150374

*To whom correspondence should be addressed

Brazilian Journal

of Chemical

Engineering

TOWARD PREDICTIVE MODELS FOR

ESTIMATION OF BUBBLE-POINT PRESSURE AND

FORMATION VOLUME FACTOR OF CRUDE OIL

USING AN INTELLIGENT APPROACH

D. Abooali

1

and E. Khamehchi

2*

1

School of Chemical Engineering, Iran University of Science and Technology, (IUST), Postal Code, 16765-163, Tehran, Iran. 2

Faculty of Petroleum Engineering, Amirkabir University of Technology, Hafez Avenue, 15914, Tehran, Iran. Phone: + 98 (21) 64545154; Fax: + 98 (21) 64543528

E-mail: [email protected]

(Submitted: June 14, 2015 ; Revised: September 1, 2015 ; Accepted: September 2, 2015)

Abstract - Accurate estimation of reservoirs fluid properties, as vital tools of reservoir behavior simulation and reservoir economic investigations, seems to be necessary. In this study, two important properties of crude

oil, bubble point pressure (Pb) and formation volume factor (Bob), were modelled on the basis of a number of

basic oil properties: temperature, gas solubility, oil API gravity and gas specific gravity. Genetic programming, as a powerful method, was implemented on a set of 137 crude oil data and acceptable correlations were

achieved. In order to evaluate models, two test datasets (17 data for Pb and 12 data for Bob) were used. The

squared correlation coefficient (R2) and average absolute relative deviation (AARD %) over the total dataset

(training + test) are 0.9675 and 8.22% for Pb and 0.9436 and 2.004% for Bob, respectively. Simplicity and high

accuracy are the advantages of the obtained models.

Keywords: Crude oil; Bubble point pressure; Formation volume factor; Genetic programming.

INTRODUCTION

Thermodynamic quantities of crude oil are a set of important features in order to determine technical specifications of oil production process equipment. Designing plenty of systems such as upstream and underground devices, surface operation equipment, etc., requires adequate and accurate information about oil parameters which are achieved, in many cases, from experimental tests along with mathemati-cal correlations and formulas.

Laboratory tests are usually expensive and some-times difficult and time-consuming. However, the application of correlations is economically advanta-geous and increases the speed of works. Further-more, the other great use of the correlations is to

determine oil future specifications and changes taken into great consideration in reservoir simulators.

Various pressure-volume-temperature (PVT) prop-erties of crude oil can be estimated by means of equations of state or oil PVT analysis, if a complete set of variables of the oil including temperature, pressure and fluid composition are available. But in many cases, the composition of reservoir fluid is not predetermined, especially in the primary stages of recovery processes. Thus, some correlations are re-quired to be functions of a number of readily availa-ble reservoir parameters in order to be used by engi-neers and scientists in this area.

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volume factor (Bob) solely as functions of simple and quickly accessible live crudeoil parameters. The parameters are temperature (T), gas solubility (Rs), oil API gravity and gas specific gravity (γg).

In a hydrocarbon system at constant temperature, whether single-component or mixture, the bubble point pressure is the maximum pressure at which the first gas bubbles appear (Ahmed, 2010). The state of the system in this condition is called “saturated liquid”.

The oil formation volume factor (FVF) is the ra-tio of the specific volume of oil at its natural tem-perature and pressure to the specific volume of the oil at standard conditions (i.e. P = 1 atm and T = 60 ˚F). If Bo is measured in the bubble point condition, it will be the bubble point oil formation volume factor (Bob).

There are several correlations and methodologies developed and proposed so far for prediction of Pb and Bob. Methods of Standing (1947), Vasquez and Beggs (1980), Glaso (1980), Marhoun (1988) and Petrosky and Farshad (1993), as famous correlations, have been introduced in the literature (Ahmed, 2010). Elsharkawy and Alikhan (1997) presented a set of correlations for gas solubility, oil compressibil-ity (Co) and Bob. Their relation for Bob is as follows:

( )

( )

(

)

( )

(

)

(

)

5 5

ob s

5

s g o

B 1 40.428 10 R 63.802 10

T – 60 0.78 10

R T –60 /

− −

= + × +

× +

× γ γ

(1)

in which, γg is gas specific gravity. Khamehchi et al. (2009) also proposed three models for Pb, Rs and bubble point oil viscosity (μob). They called the achieved models “AUT”. Their Pb correlation is given below:

0.9129 0.666 0.2122 1.08

b s g

P = 107.93 R × γ − ×T ×API− (2)

Some presented correlations or algorithms are based on consistencies of a number of oil compo-nents or assays, which should be predetermined (El-sharkawy, 2003; AlQuraishi, 2009; Bandyopadhyay and Sharma, 2011; Farasat et al., 2013). However, the composition-based models have some limitations in their uses in preliminary reservoir investigations and simulations.

There are also several methods using the artificial neural network (ANN) technique to predict Pb and Bob (Rasouli et al., 2008; Asadisaghandi and Tah-masebi, 2011). Adaptive network-based fuzzy

infer-ence system (ANFIS) is another new approach that has been applied in this area (Shojaei et al., 2014).

Different procedures and methodologies can be used for model development. Artificial neural net-work (ANN), generalized regression neural netnet-works (GRN), imperialist competitive algorithm (ICA), particle swarm optimization (PSO), adaptive net-work-based fuzzy inference system (ANFIS), genetic programing (GP), etc. are applied as famous methods in various fields, especially for optimization and pre-diction purposes. In the present study, a genetic pro-gramming based multi-gene symbolic regression al-gorithm called “GPTIPS” (Searson, 2009) was ap-plied. This is an approved method used by the authors in some projects (Abooali and Khamehchi, 2014).

The application of genetic programming for de-veloping simple-to-use correlations for Pb and Bob seems novel. Moreover, applying natural ranges of bubble point pressure, bubble point formation volume factor, temperature, gas solubility, oil API gravity and gas specific gravity has increased the applicabil-ity and accuracy of the new developed models.

MATERIALS AND METHODS Data Set

The total dataset includes 137 training sets of data from 137 oil samples. Each set includes temperature, solution gas ratio, oil API gravity, gas specific grav-ity, oil bubble point pressure and formation volume factor. The data were collected from different geo-graphical zones.

In order to determine the predictive capability of the models and also to implement a comparison be-tween the new developed models and other correla-tions, two additional sets – one for Pb including 17 sets of data and the other for Bob which has 12 sets of data – were applied. The data of the additional sets known as “test sets” were gathered from several papers and reference books (Ahmed, 2010; McCain, 1990; Shojaei et al., 2014). The ranges of all parame-ters are presented in Table 1.

Table 1: The range of parameters in the dataset of present study.

Quantity Range

Temperature (˚F) 85 – 306

Solution gas oil ratio (SCF/STB) 83 – 2217

Oil API gravity 21.143 – 124.054

Gas specific gravity (air = 1) 0.216 – 1.872 Bubble point pressure (psia) 350 – 5152 Bubble point formation volume factor

(bbl/STB)

(3)

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valuation of For evaluati on statistical rrelation coe on (RMSD) a rcentage (AA ARD is prefe

n i 1 n 2 i 1 (y (y 1 = = = −

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exp. cal. 2 i i

exp. exp. 2 i

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cal. i

y , yexp. an d average of and Pb) and tively.

ULTS AND he genetic pr r bubble poi of crude oil

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(

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exp 0.945 − γ γ + dity veloped mod s were calcu ), root-mean absolute rela A low value o uld be near t

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nd n are the f experimen

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samples in th

ONS

approach, tw and formatio ined. They a

(5)

m B v v T m P

Toward Predic The statist models are gi Bob, respectiv alues predic ersus exper Table 3, Figu models are ca Pb and Bob. I

ntotal = RMSD R2total = AARD Subscripts “to

ntotal = RMSD R2total = AARD

Subscripts “to

F c

F R

ctive Models for

Brazilian J tical parame iven in Tabl vely. Figure cted by Equ rimental dat ure 4 and Fi apable of pr In Figure 6

Tab

154

Dtotal = 190.8408 = 0.9675 Dtotal = 8.2206%

tal”, “train”, and

Tabl

149

Dtotal = 0.0449 bb = 0.9436 Dtotal = 2.0040%

tal”, “train”, and

Figure 4: P correlation co

Figure 5: P R2train and R2t

Estimation of Bu

Journal of Chemic eters of the n le 2 and Tab

4 and Figu ation (7) an ta. Accordin

gure 5, the rediction and

and Figure

le 2: Statisti

8 psia

%

“test” are used to

le 3: Statisti

bl/STB

%

“test” are used to

Predicted ver oefficients o

redicted ver

test are correl

ubble-Point Pressu

cal Engineering V new develop ble 3 for Pb a ure 5 show nd Equation

ng to Table new develop d estimation

7, cumulat

ical parame

ntrain = RMSD R2train AARD o distinguish the r

cal paramet

ntrain = RMSD R2train AARD

o distinguish the r

rsus experim f training and

rsus experim ation coeffic

ure and Formatio

Vol. 33, No. 04, ped

and the (8) 2, ped n of tive

fre tiv da the for les ati tha

eters of the n

= 137

Dtrain = 169.112 n = 0.9695

Dtrain = 8.0395% results related to

ters of the n

= 137

Dtrain = 0.0456 b n = 0.9419

Dtrain = 2.0069% results related to

mental bubbl d test data, r

mental bubbl cients of train

on Volume Factor

pp. 1083 - 1090, equency per ve deviation ta set for Pb ese figures, t r 90.26% of ss than 20% ion percent f an 10%.

new develop

26 psia

%

total data set, trai

new develope

bbl/STB

%

total data set, trai

le point pres espectively.

e point oil ning and test

r of Crude Oil Us

October - Decem cent versus

percent are

b and Bob, r the absolute f all data esti . For Bob, th for 97.315%

ed model fo

ntest = RMS R2test AAR ining data set, and

ed model for

ntest = RMS R2test AAR

ining data set, and

ssure. R2train

formation v data, respec

sing an Intelligent

ember, 2016 maximum re shown ov respectively. relative dev imated by E he absolute of all the da

or Pb.

= 17

SDtest = 315.356 st = 0.9131 RDtest = 9.6795% nd test data set, re

r Bob.

= 12

SDtest = 0.0360 st = 0.9322 RDtest = 1.9700% nd test data set, re

and R2test ar

volume facto ctively.

t Approach 10 absolute rel ver the enti As shown viation perce Equation (7)

relative dev ataset is low

62 psia

% spectively.

bbl/STB

%

spectively.

re

or.

087 la-ire

(6)

w m

 

Figure 6: maximum developed m whole data absolute rel are less tha for 90.26%

In order t with other m mented over

Table 4: C

Method

Standing Glaso Marhoun Petrosky and AUT Present study

Figure 8: versus cum pressure of absolute re veloped mo correlations

Cumulative absolute rel model for bu a set (154 d lative deviat an 10% and

of all data a

to evaluate t models, a co

test dataset

Comparison

d Farshad

y

Maximum mulative num f the test set ( elative devia odel is lower s.

e frequency lative deviat ubble point p data). As ca tions for 73.3 absolute re are less than 2

the new cor omparison ha

ts and the r

between em

Pb

AARD % 16.951 21.740 11.190

- 35.199

9.680

absolute re mber of data (17 data). As ation curve r than that of

percent ve tion of the pressure over an be seen, 377% of all lative deviat 20%.

rrelations alo as been imp results are p

mpirical corr

(Number of d

R2 R

( 0.431 80 0.461 78 0.676 60

-

-0.944 14 0.913 31

elative devia for bubble p s can be seen

of the new f other empi

ersus new r the , the

data tions

Figu max velo fact seen the atio

ong ple-

pre-sen the els

relations and

data=17) RMSD

(psia) Max

AAR 07.127 59 85.440 50 08.592 43

-

491.11 94 15.356 29

ation point n, the w

de-irical

Figu vers poin data of t othe

ure 7: Cum ximum absol oped model or over all n, absolute re

data are less ns for 97.315

nted in Table e prediction s is higher th

d the new de

ximum RD%

AAR % .054 2.62 .763 2.1 .582 2.2 - 2.1 .462 -.317 1.9

ure 9: Max sus cumulati nt formation a). The avera the new dev er empirical

mulative fre ute relative d for bubble p the data set elative devia

than 5% an 5% of all the

e 4, Figure 8 capability of an that of pre

eveloped mo

Bob (Num

RD

% R

2

21 0.888 71 0.901 92 0.902 09 0.916 - 70 0.932

ximum abso ive number n volume fac age of the ab

eloped mode correlations.

equency per deviation of point format t (149 data). ations for 91. nd absolute re

e data are les

8 and Figure f the new de revious relati

odels over te

mber of data= RMSD (bbl/STB 8 0.0462 1 0.0435 2 0.0434 6 0.0402 - 2 0.0360

olute relativ of data for ctor for the bsolute relativ del is lower

.

rcent versus the new de-tion volume . As can be .275% of all elative

devi-s than 10%.

9. As a resu eveloped mo

ons.

est data set.

=12) D

B)

Maximum AARD% 2 5.773 5 6.484 4 6.774 2 7.074

- 0 4.788

ve deviation the bubble test set (12 ve deviation than that of

ult,

od-m %

(7)

Toward Predictive Models for Estimation of Bubble-Point Pressure and Formation Volume Factor of Crude Oil Using an Intelligent Approach 1089

Brazilian Journal of Chemical Engineering Vol. 33, No. 04, pp. 1083 - 1090, October - December, 2016 These comparisons demonstrate the superiority of

the correlations developed in the present project among proposed models.

The experimental values of all dataset along with predicted data have been provided in the supporting materials and information.

CONCLUSIONS

By application of genetic programing methodol-ogy, two new models have been achieved for estima-tion and predicestima-tion of bubble point pressure and bub-ble point formation volume factor, as functions of a number of rapidly measurable oil parameters. One of the useful applications of this kind of model is pre-diction of oil properties in the future during the reser-voir lifetime that is very important, especially for economic studies as well as effective uses in reser-voir simulators. A comparison between the new pro-posed models and some other correlations shows the greater accuracy of the proposed models over previ-ous works.

NOMENCLATURE

AARD% average absolute relative deviation percentage

ANN artificial neural network

API oil API gravity

ARD% absolute relative deviation percent bbl STB-1 barrel(s) per standard barrels Bo oil formation volume factor

Bob bubble point oil formation volume factor Co oil compressibility at constant

temperature

FVF formation volume factor GP genetic programing

GRN generalized regression neural networks ICA imperialist competitive algorithm n number of samples in the dataset Pb bubble point pressure

PSO particle swarm optimization PVT pressure – volume – temperature R2 squared correlation coefficient RMSD root-mean-square deviation

Rs gas solubility

SCF STB-1 standard cubic feet of solution gas per standard barrels of oil

T temperature

cal. i

y predicted dependent variable of component i

exp. i

y experimental dependent variable of component i

exp.

y average of experimental dependent variables

γg gas specific gravity

γo oil specific gravity

μob oil bubble point viscosity

REFERENCES

Abooali, D. and Khamehchi, E., Estimation of dy-namic viscosity of natural gas based on genetic pro-gramming methodology. J. Nat. Gas. Sci. Eng., 21, 1025 (2014).

Ahmed, T., Reservoir Engineering Handbook. Gulf Professional Publishing (2010).

AlQuraishi, A. A., Determination of crude oil satura-tion pressure using linear genetic programming. Energy Fuels, 23, 884 (2009).

Asadisaghandi, J. and Tahmasebi, P., Comparative evaluation of back-propagation neural network learning algorithms and empirical correlations for prediction of oil PVT properties in Iran oilfields. J. Pet. Sci. Eng., 78, 464 (2011).

Bandyopadhyay, P. and Sharma, A., Development of a new semi analytical model for prediction of bub-ble point pressure of crude oils. J. Pet. Sci. Eng., 78, 719 (2011).

Elsharkawy, A. M., An empirical model for estimat-ing the saturation pressures of crude oils. J. Pet. Sci. Eng., 38, 57 (2003).

Elsharkawy, A. M. and Alikhan, A. A., Correlations for predicting solution gas/oil ratio, OFVF and undersaturated oil compressibility. J. Pet. Sci. Eng., 17, 291 (1997).

Farasat, A., Shokrollahi, A., Arabloo, M., Ghara-gheizi, F. and Mohammadi, A. H., Toward an in-telligent approach for determination of saturation pressure of crude oil. Fuel Process Technol., 115, 201 (2013).

Glaso, O., Generalized pressure-volume-temperature correlations. J. Pet. Technol., 32, 785 (1980). Khamehchi, E., Rashidi, F., Rasouli, H. and

Ebrahim-ian, A., Novel empirical correlations for estima-tion of bubble point pressure, saturated viscosity and gas solubility of crude oils. J. Petrol Sci., 6, 86 (2009).

Koza, J., Genetic Programming. Massachusetts Insti-tute of Technology. New York (1992).

Marhoun, M. A., PVT Correlations for Middle East Crude Oils. J. Pet. Technol., 40, 650 (1988). McCain, W. D., The Properties of Petroleum Fluids.

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Petrosky, Jr. G. E. and Farshad, F., Pressure-volume-temperature correlations for Gulf of Mexico crude oils. SPE Res. Eval. Eng., 416-420 (1998). Rasouli, H., Rashidi, F. and Ebrahimian, A.,

Estimat-ing the bubble point pressure and formation vol-ume factor of oil using artificial neural networks. Chem. Eng. Technol., 31, 493 (2008).

Searson, D. P., GPTIPS: Genetic Programming & Symbolic Regression for MATLAB. http://gptips. sourceforge.net (2009).

Searson, D. P., Leahy, D. E. and Willis, M. J., GPTIPS: An open source genetic programming

toolbox for multigene symbolic regression. IMECS, March 17-19, Hong Kong (2010).

Shojaei, M-J., Bahrami, E., Barati, P. and Riahi, S., Adaptive neuro-fuzzy approach for reservoir oil bubble point pressure estimation. J. Nat. Gas. Sci. Eng., 20, 214 (2014).

Standing, M. B., A Pressure-volume-temperature correlation for mixtures of California oils and gases. API Drill Prod. Pract., 275-287 (1947). Vazquez, M. and Beggs, H. D., Correlations for fluid

Imagem

Table 1: The range of parameters in the dataset of  present study.

Referências

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Figure 5 shows the color removal efficiencies in reactors SAMBR-1 and SAMBR-2 during all opera- tional phases, thereby showing the influence of DF and HRT, as well as of PAC and

Given that one of the environmental problems is soil contamination with heavy metals and the use of earthworms is a suitable biological method for re- moval of the contamination

Keywords : Carbon dioxide emissions; Mitigation; Energy efficiency; Carbon Capture and Storage (CCS); Oil refinery; Marginal abatement